Modified dry oil alkyd resin for protective paint for metal coating on the back of the mirror and the curtain coating paint

A drying oil alkyd, metal coating technology, used in polyester coatings, coatings, instruments, etc., can solve the problems of easy penetration of chemical substances, difficulty, single performance, etc., to achieve excellent adhesion, high corrosion resistance, Moderately hard and brittle effect

Inactive Publication Date: 2005-06-01
徐金龙
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the prepared coating film has fast drying, high hardness and excellent water resistance, due to the high toxicity of TDI, it is easy to leak during feeding, which will pollute the environment and affect human health
Secondly, it is difficult to achieve large-scale production because of gelation if there is a slight carelessness in the production process of TDI modified alkyd resin.
Furthermore, TDI is more expensive, and the cost of use is higher
[0004] Mirror back protective paint such as CN1371409A discloses " based on the quick-drying type high solid content paint of modified alkyd resin ", is a kind of composition of acrylic modified alkyd resin normal temperature curing high solid, has good performance, because The coating structure is not dense enough, and chemical substances are easy to penetrate, which affects the durability of the mirror back reflection layer
[0005] To sum up, the current film-forming resins used in mirror back coatings all have the defect of single performance, especially when they are used in the curtain coating process, they are affected by factors such as glass temperature, drying time, and the continuous running line speed of the glass. It is more difficult to keep the thickness of the coating wet film uniform, adjustable and not bifurcated

Method used

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Embodiment Construction

[0039] Below in conjunction with embodiment the present invention is described in further detail.

[0040] 1. Prepare dry oil alkyd resin with medium oil degree by alcoholysis method, and each raw material in Table 1 is in % by weight.

[0041] Raw material name

[0042] All the above-mentioned raw materials are commercially available industrial products, polyols can also be selected from dibasic alcohols such as neopentyl glycol, tribasic alcohols such as trimethylolpropane, etc., and can also be other products of tetrabasic alcohols; Dibasic acid such as other products such as phthalic anhydride, also can select tribasic acid etc. for use, dry vegetable oleic acid can also select catalpa oleic acid, dehydrated ricinoleic acid etc. for use, dry vegetable oil can adopt tung oil and safflower seed oil etc., the present invention not only Limited to the specific materials mentioned above.

[0043] The preparation of medium-oil dry oil alkyd resin weighs each raw mater...

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Abstract

The modified drying alkyd resin for curtain coated paint protecting metal coating in the back of mirror includes medium oil content drying alkyd resin in 55-70 wt%, acrylate monomer in 20-30 wt% and epoxy resin as modifier in 10-15 wt%. The medium oil content drying alkyd resin and the acrylate monomer form copolymer resin, and the copolymer resin is reacted with epoxy resin to form the modified drying alkyd resin with final viscosity of 150-300 s, acid value lower than 5 mg KOH/g and solid powder content over 50 wt%. The modified drying alkyd resin, selected cross-linking resin, pigment and solvent constitute curtain coated paint capable of well attaching to the surface of smooth metal coating.

Description

technical field [0001] The invention relates to a modified dry oil alkyd resin and a curtain coating for a mirror back metal coating protection coating. Background technique [0002] There are two production methods for mirrors: one is to deposit a layer of aluminum on the glass surface as a reflective layer by vacuum aluminum plating. The second is to first coat a layer of metallic silver on the glass surface as a reflective layer by chemical methods, and then use chemical methods to coat a layer of copper on the silver film to increase the reflection effect and protective effect of the silver film. Since the metal layer of the mirror is easily eroded by atmospheric pollution, and the use environment is mostly in places with high humidity, large temperature difference, and strong corrosion, the metal layer is easily corroded and tarnished, resulting in loss of optical properties. In order to make the metal layer on the back of the mirror less susceptible to chemical corros...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/42C08G63/49C09D167/00G02B1/10
Inventor 包柏青何建生
Owner 徐金龙
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