Liquid nanometer simple substance silver antibacterial agent and preparation method thereof
A nano-element, antibacterial agent technology, applied in the field of antibacterial agents, can solve the problems of prolonged production cycle, large product particle size, application limitations, etc., and achieves the effects of high content of active ingredients, increased contact area, and reduced production costs.
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[0032] In the preparation process of nano silver, the requirements for water are very strict. In the prior art, distilled water and pure water are generally used. Although tap water is cheap and good, it is rarely used. This is because tap water contains more Cl - , It will react with silver ions to form a white AgCl precipitate. On the one hand, it will reduce Ag + The effective concentration of AgCl particles generated at the same time is equivalent to adding a nucleating agent to make the generated nano silver particles larger. Therefore, in the process of preparing nano-silver in the prior art, distilled water or pure water must be used to eliminate Cl - Interference. The applicant went through tests after repeated studies, although the silver nitrate or silver sulfate solution prepared by tap water was partially Ag + It turns into AgCl and shows white turbidity, but after mixing with silver complexing agent and stirring for a period of time, the white precipitate will disappe...
Embodiment 1
[0040] (1) Mix 0.5% betaine polymer and 47% tap water into a betaine polymer aqueous solution; then mix 0.5% hydrogen peroxide and 50% tap water to form a hydrogen peroxide aqueous solution;
[0041] (2) Put the betaine polymer aqueous solution into the reaction kettle, add 2% silver nitrate in a high-speed disperser at a stirring speed of 800r / min, and stir for about 1.5 hours to make the silver ion and the betaine polymer The solution fully undergoes complexation reaction;
[0042] (3) Finally, the hydrogen peroxide aqueous solution is sprayed into the solution obtained in step (2) through the sprayer and under the flow control of 1000ml per minute. After the spraying is completed, continue to stir the reaction and stir for 1 hour. The liquid nano-silver antibacterial agent is obtained.
Embodiment 2
[0044] (1) Mix 5% of polymaleic acid and 44% of distilled water to form an aqueous solution of polymaleic acid; then mix 3% of sodium borohydride and 45% of distilled water to form an aqueous solution of sodium borohydride;
[0045] (2) Add the polymaleic acid aqueous solution into the reaction kettle, add 3% silver sulfate in a high-speed disperser at a stirring speed of 700r / min, and stir for 1 hour to make the silver ion and the polymaleic acid solution fully complex. Combined reaction
[0046] (3) Finally, the sodium borohydride aqueous solution is sprayed into the solution obtained in step (2) through the sprayer and under the flow control of 800ml per minute. After the spraying is completed, continue to stir the reaction and stir for 1 hour. The liquid nano-silver antibacterial agent is obtained.
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