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Liquid nanometer simple substance silver antibacterial agent and preparation method thereof

A nano-element, antibacterial agent technology, applied in the field of antibacterial agents, can solve the problems of prolonged production cycle, application limitation, large product particle size, etc., and achieves the effects of high content of active ingredients, reduced production cost, and increased contact area.

Inactive Publication Date: 2007-02-07
RESEARCH INSTITUTE OF TSINGHUA UNIVERSITY IN SHENZHEN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This kind of antibacterial agent has good safety and is a kind of antibacterial agent that is widely used at present, but its stability is poor, easy to change color, and it is a powder material, which needs to be dispersed again before application
[0009] The heat resistance of the second type of inorganic antibacterial agent is higher than that of the first type of inorganic antibacterial agent, but it must have ultraviolet radiation, oxygen or water to play a bactericidal effect, and there is also the problem of re-dispersion, so the application is limited
Like this, can increase production cost greatly, have increased a process again simultaneously, prolong production cycle; The 2nd, the product particle diameter that obtains in the two patent application methods is larger, and the range is wider (1-50nm)
And the smaller and narrower the distribution of nanometer particle size, the higher its activity, the better the antibacterial effect and workability; the third, the silver salts used in the two patented methods are only silver nitrate, and the cost is high (in nano silver In the preparation process of the silver salt, the cost of the silver salt is one of the most critical factors affecting the cost of the whole product)
In the current technical field of nano-silver preparation, although silver nitrate is expensive, it is widely used because it can be well dissolved in distilled water or pure water; silver chloride is very expensive and insoluble in water, so it is generally not used. Potassium silver cyanide is used because the product contains potassium cyanide, which is toxic and generally not used; silver sulfate is much lower in price than silver nitrate, and its safety is also very good, but because it is slightly soluble in water, it has not been used at present. Applied to the preparation of nano silver

Method used

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  • Liquid nanometer simple substance silver antibacterial agent and preparation method thereof
  • Liquid nanometer simple substance silver antibacterial agent and preparation method thereof
  • Liquid nanometer simple substance silver antibacterial agent and preparation method thereof

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preparation example Construction

[0032] In the preparation process of nano-silver, the requirements for water are very strict. Generally adopt distilled water, pure water in the prior art, although tap water is cheap and good-looking, but seldom adopts, this is because tap water contains more Cl - , will react with silver ions to form white AgCl precipitates, on the one hand, it will reduce Ag + At the same time, the AgCl particles generated are equivalent to adding a nucleating agent to make the generated nano-silver particles larger. Therefore, in the prior art, in the process of preparing nano-silver, distilled water or pure water must be used to exclude Cl - interference. After repeated studies, the applicant has tested again, although the silver nitrate or silver sulfate solution prepared by tap water is due to some Ag + It turns into AgCl and becomes white and turbid, but after mixing with silver complexing agent and stirring for a period of time, the white precipitate will disappear and become a col...

Embodiment 1

[0040] (1) 0.5% betaine type polymer and 47% tap water are mixed to be betaine type polymer aqueous solution; Then 0.5% hydrogen peroxide and 50% tap water are mixed into hydrogen peroxide solution;

[0041] (2) Add the betaine type polymer aqueous solution in the reaction kettle, add 2% silver nitrate at the stirring speed of 800r / min in the high-speed disperser, and stir for about 1.5 hours to make the silver ion and the betaine type polymer The solution fully undergoes a complexation reaction;

[0042] (3) Finally, the aqueous hydrogen peroxide solution is sprayed in the solution obtained in step (2) through the sprayer and under the flow control of 1000ml per minute. After the spraying ends, continue to stir the reaction and stir for 1 hour, and then The liquid nanometer elemental silver antibacterial agent is obtained.

Embodiment 2

[0044] (1) 5% polymaleic acid is mixed with 44% distilled water to be polypolymaleic acid aqueous solution; Then 3% sodium borohydride and 45% distilled water are mixed into sodium borohydride aqueous solution;

[0045] (2) Add the polymaleic acid aqueous solution in the reaction kettle, add 3% silver sulfate under the stirring speed of 700r / min in the high-speed disperser, stir for 1 hour to make the silver ion and the polymaleic acid solution fully intertwine Combined reaction;

[0046] (3) Finally, the aqueous solution of sodium borohydride is sprayed into the solution obtained in step (2) through the sprayer and under the flow control of 800ml per minute. After the spraying ends, continue to stir the reaction and stir for 1 hour, and then The liquid nanometer elemental silver antibacterial agent is obtained.

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PUM

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Abstract

Disclosed is a liquid state nano antimicrobial agent of Argentine simple substance, which comprises the following constituents (by weight percent): argentic salt 2-5%, nano Argentine generating agent 0.5-5%, Argentine complexing agent 0.5-8%, and water 82-97%. In the preparation, ionic type high molecular polymer is used as the Argentine complexing agent.

Description

technical field [0001] The invention relates to an antibacterial agent, in particular to a liquid nanometer elemental silver antibacterial agent and a preparation method of the antibacterial agent. Background technique [0002] There are various harmful microorganisms in people's living environment, which have adverse effects on human life. According to the survey of the British Scottish Telephone Company, there are more than a dozen infectious diseases such as colds, pharyngitis, meningitis, hepatitis, pink eye, skin diseases, and tuberculosis. The disease can be spread through the use of the telephone. It has been discovered that a "refrigerator syndrome" syndrome of gastroenteritis, sore throat, nausea, and dizziness caused by eating food contaminated by bacteria in the refrigerator. Therefore, research on various antibacterial materials closely related to people's lives has become a hot topic today. [0003] Antibacterial materials refer to endowing materials with good...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A01N59/16A01N25/02A01P3/00
Inventor 陈丽琼李荣先
Owner RESEARCH INSTITUTE OF TSINGHUA UNIVERSITY IN SHENZHEN
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