Vacuum drying method of carbon dioxide full base degradation plastic-polypropylidene carbonate and its device

A technology for polypropylene carbonate and degradable plastics, applied in the field of degradable plastic drying, can solve the problems of drying temperature not exceeding the material denaturation temperature, drying exhaust gas not being directly discharged, drying moisture not being able to be recovered, etc. High yield, not easy to dry

Active Publication Date: 2006-08-30
LANZHOU RUIDE DRYING TECH +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CO 2 All-based degradable plastic—polypropylene carbonate (PPC) is a polymer degradable plastic with good degradability. The wet material has strong photosensitivity and heat sensitivity. It is easy to decompose when exposed to light or heat before drying, and the water produced by the decomposition Parts will agglomerate the plastic particles, so CO 2 All-based degradable plastics must be dried immediately after filtration, and the drying temperature cannot exceed the material denaturation temperature; secondly, CO 2 The moisture that needs to be removed in the drying production process of all-based degradable plastics is methanol and propylene oxide, both of which are highly toxic substances, so the dryer must be airtight, and the drying tail gas cannot be discharged directly, and must be recycled by condensation; moreover , due to CO 2 All-based degradable plastic is a kind of material with high molecular weight, high viscosity, easy agglomeration, poor thermal conductivity or agglomeration degree, decomposition rate and moisture content of propylene oxide. So far, the new CO 2 Full-scale degradable plastics have not yet appeared in large-scale industrial production in China
The pilot plant jointly developed by Inner Mongolia Mengxi High-tech Materials Co., Ltd. and the Changchun Institute of Applied Chemistry, Chinese Academy of Sciences uses a vibrating fluidized bed for drying. The dried moisture cannot be recovered, and the drying requirements cannot be met, and there are even serious safety hazards and production defects.

Method used

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  • Vacuum drying method of carbon dioxide full base degradation plastic-polypropylidene carbonate and its device
  • Vacuum drying method of carbon dioxide full base degradation plastic-polypropylidene carbonate and its device
  • Vacuum drying method of carbon dioxide full base degradation plastic-polypropylidene carbonate and its device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The wet material comes from the upstream section, through the screw conveyor 1 and the rotary valve 2 with high air-locking performance, continuously and evenly enters the decompression delivery tank 3, and the decompression delivery tank 3 communicates with the decompression system through the valve 6. The decompressed material enters the disc dryer (manufactured by Lanzhou Ruide Drying Technology Co., Ltd., and its products are two types of normal pressure type and vacuum type) through the rotary valve 4 with high air-locking performance. The rakes 20 are driven by the main shaft 21 to stir and turn the materials, and the materials are dried by the indirect heat transfer heat medium during the flow from top to bottom along the hollow heating plate 22 . The heat source is circulating hot water. The drying temperature was 76°C. The steam and gas mixture with solid particles in the material enter the filter 5, the gas is filtered through the filter bag 18 fixed by the c...

Embodiment 2

[0029] The drying process is the same as continuous operation, but the operating procedure is different. During intermittent operation, the screw conveyor 1 transports the material from the upstream to the rotary valve 2 with high air-locking performance, and then the material enters the decompression delivery tank 3 continuously and evenly through the rotary valve 2, and the decompression delivery tank 3 passes through the valve 6 and The decompression system is connected. The decompressed material enters the vacuum paddle dryer (manufactured by Lanzhou Ruide Drying Technology Co., Ltd., the products are: W type and T type) through the rotary valve 4 with high air-locking performance. Both the hollow heat shaft 23 and the hollow jacket 24 are fed with steam, and the wet material is heated and dried through the wall of the vessel. The drying temperature is 90°C, and at the same time, the wet material gradually moves to the discharge port under the stirring of the hollow heat ...

Embodiment 3

[0031]The drying process is the same as in Example 1. The screw conveyor 1 transports the material from the upstream to the rotary valve 2 with high air-locking performance, and then the material enters the decompression conveying tank 3 continuously and evenly through the rotary valve 2, and the decompression conveying tank 3 passes through the valve 6 and the decompression system connected. The decompressed material enters the rake dryer (manufactured by Lanzhou Ruide Drying Technology Co., Ltd., the product is a vacuum type) through the rotary valve 4 with high air-locking performance. The heating medium required for drying—the steam of low-boiling substances passes through the cylinder jacket 25 and the stirring shaft 26 to indirectly heat and dry the wet materials, and the drying temperature is 90°C. The moisture in the wet material is heated and vaporized, and the vaporized moisture is removed in time. With the continuous rotation of the stirring shaft, the wet material...

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PUM

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Abstract

The present invention discloses a carbon-dioxide all-base degradable plastics-polypropylidene carbonate vacuum drying method and its equipment. Said equipment includes the following several portions: spiral conveyer, transfer rotary valve, decompression transfer tank, decompression system, rotary valves with high-blocking performance, heat source and drying machine and drying unit. Said invention also provides their connection mode and the concrete operation method and steps of said vacuum drying equipment.

Description

technical field [0001] The invention relates to the technical field of drying degradable plastics, and belongs to a vacuum drying method for carbon dioxide-based degradable plastics and a device for realizing the method. The method and device are also suitable for drying other heat-sensitive, moisture-recovering materials. Background technique [0002] The research on biodegradable polymer materials began in the 1970s. Since the 1980s, countries around the world have invested a lot of manpower and material resources in the research and development of degradable polymer materials, among which degradable plastics are the fastest growing category. CO 2 All-based degradable plastic—polypropylene carbonate (PPC) is a polymer degradable plastic with good degradability. The wet material has strong photosensitivity and heat sensitivity. It is easy to decompose when exposed to light or heat before drying, and the water produced by the decomposition parts will agglomerate the plasti...

Claims

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Application Information

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IPC IPC(8): C08L69/00C08K3/36B29B13/06
Inventor 赵旭岳永飞郭辉
Owner LANZHOU RUIDE DRYING TECH
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