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Preparation method for metal organic framework-derived tricobalt tetroxide-modified titanium dioxide nanotube array

The invention discloses a preparation method for a metal organic framework-derived tricobalt tetroxide-modified titanium dioxide nanotube array. The method comprises the following steps: firstly performing pretreatment on a titanium sheet substrate material; performing electrochemical treatment on the treated titanium substrate material by using an ethylene glycol solution containing ammonium fluoride and water as an electrolyte, and performing calcination by using a muffle furnace to change a titanium dioxide crystal form; secondly, performing cobalt hydroxide electrodeposition by means of athree-electrode electrochemical workstation and by using cobalt nitrate hexahydrate as an electrolyte, a titanium dioxide nanotube array as a working electrode, a platinum sheet as a negative electrode and silver/silver chloride as a reference electrode; performing hydrothermal treatment on the titanium dioxide nanotube array to form ZIF-67 in situ; and finally, performing secondary calcination byusing a muffle furnace to obtain the ZIF-67-derived porous tricobalt tetroxide-modified titanium dioxide nanotube array. The method disclosed by the invention can effectively improve absorption capacity of TiO2 on visible light, promote separation of electron hole pairs, and improve photocatalytic degradation efficiency of organic pollutants.
Owner:SUZHOU UNIV
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