Modified natural polymer medical adjuvant, its preparation method and use
A technology of natural polymers and pharmaceutical excipients, applied in the field of modified natural polymer pharmaceutical excipients and their preparation and application, to achieve the effects of increasing swelling, increasing disintegration ability, and accelerating moisture absorption speed
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Embodiment 1
[0035] Embodiment 1: add the distilled water of 2 times of the quality of the polysaccharide in 20g of the polysaccharide, after stirring evenly, add the sodium hydroxide of 5% of the quality of the polysaccharide, stir at room temperature, basify for 40 minutes, add 20% of the quality of the polysaccharide Chloroacetic acid, etherification reaction at 75°C for 8 hours, then use 1mol / L dilute sulfuric acid to neutralize the reaction product to a pH value of 5-6, filter, wash 3 times with 80% (mass fraction) ethanol, Drying at 50°C yielded an average molecular weight of 20.2×10 4 、-CH 2 Carboxymethylpachyran 1 with a COOH substitution degree of 0.162.
Embodiment 2
[0036] Embodiment 2: add the distilled water of 3 times of the quality of the polysaccharide in 20g pachymansin, after stirring evenly, add the swelling inhibitor sodium sulfate of 0.5% of the quality of the polysaccharide as the quality of the polysaccharide as the polysaccharide, add the quality of the polysaccharide as the distilled water 3% sodium hydroxide, stirred at room temperature, basified for 60 minutes, added 15% chloroacetic acid of the quality of polysaccharides, etherified at 50°C for 10 hours, and then used 1mol / L dilute sulfuric acid to dilute the reaction product and to a pH value of 5 to 7, filtered, washed 3 times with 80% (mass fraction) ethanol, dried at 50°C to obtain an average molecular weight of 22.2×10 4 、-CH 2 Carboxymethylpachyran 2 with a COOH substitution degree of 0.179.
Embodiment 3
[0037] Embodiment 3: add the distilled water of 5 times of the quality of the polysaccharide in 20g polysaccharide, after stirring evenly, add the sodium hydroxide of 3% of the quality of the polysaccharide, stir at room temperature, basify for 60 minutes, add 15% of the quality of the polysaccharide Chloroacetic acid was etherified at 50°C for 10 hours, and then the reaction product was neutralized to a pH of 5 to 7 with 1 mol / L dilute sulfuric acid, filtered, and washed 3 times with 80% (mass fraction) ethanol, Drying at 50°C yielded an average molecular weight of 22.2×10 4 、-CH 2 Carboxymethylpachyran 3 with a COOH substitution degree of 0.216.
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Abstract
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