High softening point bitumen used as lithium ion battery negative pole coating layer material and manufacture thereof
A technology of high softening point asphalt and lithium-ion batteries, which is applied in non-aqueous electrolyte battery electrodes, building insulation materials, active material electrodes, etc., can solve the problems of complex preparation methods, high requirements, cumbersome follow-up treatment, etc., and achieve simple process, The effect of high discharge capacity and easy industrialization
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Embodiment 1
[0017] Mix medium temperature coal tar pitch with 1% (weight) Si, at 250°C, N 2 Heat treatment under atmosphere protection for 48 hours, and pulverize the product to a size below 3 μm with a jet mill to obtain the high softening point asphalt coating material of the present invention. Recording its fixed carbon content is 83%, quinoline insoluble matter 17% (weight), toluene insoluble matter 83% (weight), softening point 280 ℃.
[0018] Among them, the above heat treatment equipment adopts circulating tunnel kiln, intermittent low temperature heat treatment furnace, high temperature oven and so on. During the heat treatment, a protective gas such as nitrogen, argon, helium, neon or carbon dioxide is filled, the gas flow rate is 1-10 liters / minute, and the final heat treatment temperature rise rate is 1-10° C. / minute. After heat treatment, cool down to room temperature, and use high-speed pulverizer, low-speed pulverizer, classifier to pulverize and classify respectively. The...
Embodiment 2
[0020] Mix medium temperature petroleum asphalt with 3% (weight) B 4 C mix, at 350°C, N 2 Heat treatment for 24 hours under the protection of the atmosphere, and pulverize the product to be less than 3 μm by using a jet mill to obtain the high softening point asphalt coating material of the present invention. It is measured that its fixed carbon content is 85%, quinoline insoluble matter 21% (weight), toluene insoluble matter 74 (weight) %, softening point 290 ℃.
Embodiment 3
[0022] Mix medium temperature petroleum asphalt with 10% (weight) H 3 PO 4 Mixed, at 500°C, CO 2 Heat treatment for 5 hours under the protection of the atmosphere, and pulverize the product to be less than 3 μm by using a jet mill to obtain the high softening point asphalt coating material of the present invention. Recording its fixed carbon content is 81%, quinoline insoluble matter 23% (weight), toluene insoluble matter 88% (weight), softening point 260 ℃.
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