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Alkali-free glass and manufacturing technique thereof

A technology of alkali-free glass and production process, applied in the field of inorganic non-metallic materials, can solve the problems of secondary pollution of solid waste, waste gas pollutants, increase of production cost, etc., and achieve the effect of sustainable development

Active Publication Date: 2008-01-30
JUSHI GRP CO
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Problems solved by technology

However, boron and fluorine are volatile components in the glass melting process, and are the main part of the volatiles in the glass melting operation, forming a large amount of exhaust gas pollutants
Therefore, it is necessary to build high-efficiency waste gas treatment facilities to ensure that the discharged waste gas meets the environmental protection requirements stipulated by the state, thereby increasing production costs and easily causing secondary pollution of solid waste

Method used

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  • Alkali-free glass and manufacturing technique thereof

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Embodiment Construction

[0009] The present invention is specifically described below through examples, but the content of the present invention is not subject to any restriction of the following examples.

[0010] The raw materials for the production of alkali-free glass usually use quartz sand, calcined limestone, pyrophyllite, and calcined dolomite. The calcined limestone can be replaced by ordinary limestone or a mixture of the two, pyrophyllite can be replaced by kaolin or a mixture of the two, and calcined dolomite can be replaced by lightly calcined dolomite. Stone or ordinary dolomite is used instead or mixed. Generally speaking, the processing procedure of the embodiment of the present invention is as follows: each component of the embodiment of the present invention can be obtained from suitable batch material or raw material (for example: the silicon dioxide in the quartz sand, the calcium oxide in the limestone, the calcium oxide in the dolomite magnesium oxide) and may contain traces of o...

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Abstract

The invention relates to alkali-free glass for the production of continuous glass fiber product and production process thereof, pertaining to inorganic non-metallic material field. The main production raw materials of the alkali-free glass comprise quartz sand, limestone, pyrophyllite and dolomite; wherein, the production processes comprise proportioning, melting, fiber forming, fiber drawing and product processing; the temperature for fiber forming is 1160-1360 DEG C, the viscosity is 1000 poises and liquid phase temperature is at least 97 DEG C lower than that of the fiber forming; the weight proportions of compositions to the product are respectively that: silicon dioxide is 58-62 percent, calcium oxide 20-24 percent, aluminum oxide 12-14 percent, magnesium oxide 2-4 percent, fluorine 0-0.6 percent, potassium oxide and sodium oxide 0-2 percent in total, titanium oxide 0-2 percent, iron trioxide 0-0.6%, sulfur trioxide 0-0.6% and micro impurity 1%. By adjusting the variety and proportion thereof of glass raw materials, the invention removes fluoride materials such as fluorite and boride such as borocalcite from raw materials of glass, thereby controlling the origin of the waster gas pollutants.

Description

Technical field: [0001] The invention relates to an alkali-free glass used for producing continuous glass fiber products and a production process thereof, belonging to the field of inorganic non-metallic materials. Background technique: [0002] A common glass composition used to produce continuous glass fibers is alkali-free glass, which is the most common glass used to produce electronic-grade and reinforced glass fibers. The main advantage of alkali-free glass is that it uses fluoride and boride as flux, which can be melted and clarified at a relatively low temperature. However, boron and fluorine are volatile components in the glass melting process, and are the main part of the volatiles in the glass melting operation, forming a relatively large amount of exhaust gas pollutants. Therefore, it is necessary to build high-efficiency waste gas treatment facilities to ensure that the discharged waste gas meets the environmental protection requirements stipulated by the state...

Claims

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Application Information

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IPC IPC(8): C03C3/112C03C6/04
Inventor 张毓强
Owner JUSHI GRP CO
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