Preparation method of magnetism remotely-controlled drive microstructure
A microstructure and magnetic technology, which is applied in the field of preparation of magnetic remote control driven microstructures, can solve problems such as difficult biocompatible remote operation methods
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Embodiment 1
[0044] (1) Preparation of magnetic nanomaterials. Preparation of Fe by Chemical Co-precipitation 3 o 4 - Oleic acid magnetic nanomaterials. 5.38g FeCl 3 .6H 2 O was dissolved in 200ml deionized water, and 1.98g FeCl was added under nitrogen protection 2 .4H 2 O. Under electric stirring, 7 ml of ammonia water with a concentration of 8% was quickly added. After stirring for 3 hours, the temperature of the oil bath was raised to 80° C., 1.22 g of oleic acid was added dropwise, and the reaction was completed for 30 minutes after the dropwise addition. Utilize magnet adsorption, wash three times with deionized water, dry, obtain 2.54g product, the X-ray diffraction data shown in Fig. 2, infrared transmission spectrum prove that product is Fe 3 o 4 - Oleic acid magnetic nanomaterials, transmission electron microscope pictures show that the particle size of the nanoparticles is about 15nm.
[0045] (2) Preparation of magnetic photoresist. Will Fe 3 o 4 - Oleic acid magnet...
Embodiment 2
[0052] (1) Preparation of magnetic nanomaterials. Preparation of Fe by High Temperature Pyrolysis 3 o 4 Magnetic nanomaterials as core, oleic acid and oleylamine as surface modification materials. 2mmol precursor iron triacetylacetonate Fe(acac) in the there-necked flask 3 Dissolve 10mmol reducing agent 1,2-hexadecanediol in 20ml phenetole ether solvent, add 6mmol oleic acid and 6mmol oleylamine at the same time, pass nitrogen gas for 30 minutes under magnetic stirring, heat to 200°C for 30 minutes, then heat to 250°C ℃ for another 30 minutes, centrifuged and washed to obtain the product. The X-ray diffraction data and infrared transmission spectrum shown in Figure 4 prove that the product is Fe 3 o 4 - Oleic acid and oleylamine magnetic nanomaterials, the transmission electron microscope pictures show that the particle size of the nanoparticles is about 6nm.
[0053] (2) Fe 3 o 4 -Oleic acid, oleylamine magnetic nanomaterial with photoinitiator L369 and BPO, MA, resin...
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