Unitary solid chlorine dioxide effervescent tablet and preparation method thereof

A technology of chlorine dioxide and effervescent tablets, which is applied in botany equipment and methods, chemicals for biological control, animal repellants, etc., and can solve inconvenience, chlorine dioxide gas escape, low generation, etc. problem, to achieve the effect of improving chemical yield, accelerating dissolution rate, and enhancing bactericidal activity

Inactive Publication Date: 2008-07-30
石家庄卫科生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Yet chlorine dioxide is gas at normal temperature, and very unstable, meets reducing substance and just reacts, and decomposes after encountering light, so chlorine dioxide must be produced on the spot, uses up as soon as possible, and this brings a negative impact on the popularization and use of chlorine dioxide Inconvenience
[0003] Chlorine dioxide generators are expensive, not suitable for small occasions such as civil use, and require professionals for operation and maintenance, so they can only be promoted in industrial occasions; for this reason, someone invented stable chlorine dioxide, and the two solutions were installed in two Chlorine dioxide can be produced by mixing the two solutions when in use
Chlorine dioxide powder has disadvantages during use: when dissolving, if a small amount of powder is placed in a relatively large amount of water, the amount of chlorine dioxide produced will be very low, the main reason being that the powder particles spread rapidly in the water , can not fully contact the reaction, in order to obtain a higher conversion rate, the powder must be dissolved in water less than 100 times its weight for activation. Due to the high reaction concentration, a large amount of chlorine dioxide gas escapes, resulting in the loss of active ingredients and the use inconvenient
However, this patent does not discuss the preparation process of the block composition and the treatment of raw materials, nor does it involve the storage stability of the block composition

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] Tablets weighing 10 grams were prepared using the following formulation.

[0073] raw material name

Raw material ratio

Sodium chlorite (content ≥ 80%), kg

34

Sodium dichloroisocyanurate, kg

13

Sodium bisulfate, kg

21

Sodium persulfate, kg

20

Magnesium sulfate, kg

5

Sodium alginate, kg

2.5

Sodium dodecylbenzenesulfonate, kg

0.5

Sodium carbonate, kg

1

Adipic acid, kg

3

[0074] First pour 2.5kg of sodium alginate into 60kg of water, heat up to about 80°C and stir until completely dissolved to obtain sodium alginate slurry; sieve sodium chlorite in a vibrating sieve, and take 34kg of sodium chlorite with a particle size of 40 mesh Put it into a coating machine, spray the above-mentioned prepared binder slurry for drying and coating. The drying temperature is controlled below 100°C. When the water content of the intermediate reaches belo...

Embodiment 2

[0081] Tablets weighing 1 gram were prepared using the following formulation.

[0082] raw material name

Raw material ratio

Sodium chlorite (content ≥ 80%), kg

30

Sodium dichloroisocyanurate, kg

10

Citric acid, kg

40

Sodium persulfate, kg

2

Magnesium sulfate, kg

10

Sodium alginate, kg

2.5

Sodium dodecylbenzenesulfonate, kg

0.5

Sodium bicarbonate, kg

2

Adipic acid, kg

3

[0083] First pour 2.5kg of sodium alginate into 60kg of water, heat up to about 80°C and stir until completely dissolved to obtain sodium alginate slurry; sieve sodium chlorite in a vibrating sieve, and take 30kg of sodium chlorite with a particle size of 40 mesh Put it into a coating machine, spray the above-mentioned prepared binder slurry for drying and coating. The drying temperature is controlled below 100°C. When the water content of the intermediate reaches below 1%,...

Embodiment 3

[0090] Tablets weighing 10 grams were prepared using the following formulation.

[0091] raw material name

Raw material ratio

Sodium chlorite (content ≥ 80%), kg

12

Sodium dichloroisocyanurate, kg

6

Sodium bisulfate, kg

40

Sodium persulfate, kg

2

Magnesium sulfate, kg

15

Polyvinylpyrrolidone, kg

1.5

Sodium lauryl sulfate, kg

0.5

Magnesium carbonate, kg

3

Sodium chloride, kg

20

[0092] The raw material of formula is processed according to the technological process described in embodiment 1, embodiment 2, after obtaining combined raw material, on tablet machine, press the tablet with the pressure of 50KN with the punch of diameter 25mm, be pressed into the tablet of weight 10 grams, Packed in aluminum-plastic composite bag.

[0093] 10 gram tablets are dropped into 20 liters of tap water, after 15 minutes, the concentration of sampling detect...

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PUM

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Abstract

The invention discloses a one-variable solid effervescent tablet and a preparation method for the tablet. The material system of the effervescent tablet comprises chlorite, solid acid source, free halogen source, activated Promoter, desiccant, bond, release agent, effervescent and surfactant. The preparation technique includes: after the coating processing with chlorite grains, drying and mixing well with other raw materials according to a specific proportion and technique requirements to prepare compound raw materials, and then pressing into tablets with different specification and shaping on the tablet machine to fit for application in various occasions. The effervescent tablet can quickly release chlorine dioxide and acquire pellucid water solution of chlorine dioxide while dissolving in the water, which is high in stability, rapid in dissolving rapid and strong in bactericidal ability.

Description

technical field [0001] The invention belongs to the field of chemical industry and pharmacy, and relates to an effervescent tablet capable of rapidly producing chlorine dioxide after being dissolved in water, in particular to a monobasic solid chlorine dioxide effervescent tablet and a preparation method thereof. Background technique [0002] Chlorine dioxide is an internationally recognized fourth-generation disinfectant. Its disinfection effect and environmental protection performance are superior to those commonly used disinfectants such as hypochlorite, chlorine gas, ethylene oxide, and glutaraldehyde. Compared with chlorine, it does not produce carcinogens such as halogenated alkanes when it is used for drinking water disinfection. Yet chlorine dioxide is gas at normal temperature, and very unstable, meets reducing substance and just reacts, and decomposes after encountering light, so chlorine dioxide must be produced on the spot, uses up as soon as possible, and this b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/08A01N59/00A01P1/00
Inventor 王奎涛张炳烛高金龙曹春峰谷娜张林霞李菁
Owner 石家庄卫科生物科技有限公司
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