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Adhesive gum special for sheet metal and preparation thereof

A metal sheet and adhesive technology, applied in the field of adhesives, can solve the problems of insufficient bonding between the colloid and the metal plate, weak peeling resistance, and unenvironmental protection, so as to achieve outstanding shock absorption and sound absorption effects, and reduce adhesive bonding. Destruction, performance-enhancing effects

Inactive Publication Date: 2009-01-14
RUIYANG AUTOMOTIVE MATERIALS XIANTAO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention mainly solves the technical problems such as weak colloidal shear resistance, weak peeling resistance, insufficient combination of colloid and metal plate, and non-environmental protection when traditional adhesives are used for mutual adhesion of metal plates.

Method used

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  • Adhesive gum special for sheet metal and preparation thereof
  • Adhesive gum special for sheet metal and preparation thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Example 1: Dissolve 2 parts (each weight is 50g, the same below) of γ-aminopropyltriethoxysilane in ethyl acetate at a ratio of 1:5, and mix 5 parts of nanometer Silica powder and 5 parts of nano-alumina powder were added to the above-mentioned silane coupling agent solution, treated with ultrasonic waves for 30 minutes, then distilled under reduced pressure to remove ethyl acetate, and dried to obtain active filler powder; the temperature was controlled at At 90°C, pour the active filler powder and 50 parts of epoxy resin into the reaction kettle of the vacuum disperser, and stir at a high speed of 1350rpm for 20 minutes to obtain a mixture of epoxy resin-active filler; then mix 100 parts of epoxy resin according to the proportion Pour one part of amino-terminated liquid nitrile rubber (with acrylonitrile content of 18) and 50 parts of ethyl acetate into the reaction kettle of the vacuum disperser, stir at a low speed of 350 rpm for 35 minutes, then control the temperat...

Embodiment 2

[0022] Example 2: Dissolve 1 part (each weight is 50g, the same below) of γ-aminopropyltriethoxysilane in ethyl acetate at a ratio of 1:5, and mix 7 parts of nanometer Silica powder and 6 parts of nano-alumina powder are added to the above-mentioned silane coupling agent solution, treated with ultrasonic waves for 30 minutes, then the ethyl acetate is removed by distillation under reduced pressure, and dried to obtain the active filler powder; the temperature is controlled at At 90°C, pour the active filler powder and 40 parts of epoxy resin into the reaction kettle of the vacuum disperser, and stir at a high speed of 1350rpm for 20 minutes to form the mixture of epoxy resin-active filler; then mix 90 parts of epoxy resin according to the proportion Pour amino-terminated liquid nitrile rubber (acrylonitrile content: 26%) and 55 parts of ethyl acetate into the reaction kettle of the vacuum disperser, stir at a low speed of 350 rpm for 35 minutes, then control the temperature at ...

Embodiment 3

[0023] Example 3: Dissolve 2 parts (each weight is 50g, the same below) of γ-aminopropyltriethoxysilane in ethyl acetate at a ratio of 1:5, and mix 6 parts of nanometer Silicon oxide powder and 7 parts of nano-alumina powder were added to the above-mentioned silane coupling agent solution, treated with ultrasonic waves for 30 minutes, then distilled under reduced pressure to remove ethyl acetate, and dried to obtain active filler powder; the temperature was controlled at At 90°C, pour the active filler powder and 45 parts of epoxy resin into the reaction kettle of the vacuum disperser, and stir at a high speed of 1350rpm for 20 minutes to obtain a mixture of epoxy resin-active filler; then mix 95 parts of epoxy resin according to the proportion Pour 60 parts of amino-terminated liquid nitrile rubber (acrylonitrile content is 18) and 60 parts of ethyl acetate into the reaction kettle of the vacuum disperser, stir at a low speed for 35 minutes at a speed of 350 rpm, then control ...

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Abstract

The invention relates to an adhesive agent specially used for a metal plate and the preparation method. The formulation is mainly made by the components according to the weight parts: 86 parts to 100 parts of amine terminated liquid nitrile rubber, 40 parts to 50 parts of bisphenol A epoxy resin, 5 parts to 7 parts of nanometer silica, 5 parts to 7 parts of nanometer alumina, 1 part to 2 parts of silane coupling agent, 2.5 parts to 4 parts of dicumyl peroxide, 1 part to 2 parts of triallyl cyanurate, 30 parts to 40 parts of methyl hexahydro phthalic anhydride, 0.5 part to 1 part of benzyl triethyl ammonium chloride and 50 parts to 60 parts of acetic ether. The adhesive agent is used for compounding two layers of the metal plates, and when compared with the traditional adhesive agent, both the shear strength and the peel strength are greatly enhanced. The compounded metal plate bonded by the adhesive agent is particularly suitable for manufacturing a damping and deadening disc, because the damping coefficient of which is high. In addition, the raw material adopted in the adhesive agent belongs to the environmental protection product, and during the large-scale industry application, the problem of the environmental pollution can not be generated.

Description

technical field [0001] The invention relates to an adhesive, in particular to a special adhesive for metal plates and a preparation method thereof. Background technique [0002] The shock-absorbing and noise-absorbing pad is an important part of the brake pad. When the brake pad is braking, the shock-absorbing and noise-absorbing pad can damp the vibration and noise caused by the friction block in the brake pad. At present, there is a shock-absorbing and sound-absorbing sheet of a composite structure, which is formed by bonding two layers of metal sheets. Compared with the ordinary shock-absorbing and sound-absorbing sheet using a single-layer metal plate, the shock-absorbing sheet with a composite structure has better strength, excellent shock-absorbing and sound-absorbing properties. In this shock absorber, the glue that bonds the two metal sheets is the key factor. Since glue and metal are two different materials, their chemical structure and mechanical properties are v...

Claims

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Application Information

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IPC IPC(8): C09J109/02C09J11/00B32B15/01B32B37/12C09J163/02
Inventor 张泽伟
Owner RUIYANG AUTOMOTIVE MATERIALS XIANTAO
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