Resin matching fluid used for metal foil laminated board

A technology of resin and epoxy resin, which is applied in the field of resin compounding solution in the field of preparing high-density interconnected multilayer boards or IC packaging, and can solve the problem of poor toughness and impact resistance, high crosslinking density, and poor heat resistance of cured products etc. to achieve low thermal expansion coefficient, high circuit processability, and improved compatibility

Inactive Publication Date: 2009-10-07
SHENGYI TECH SUZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cross-linking density is high, the cured product is brittle, and the toughness and impact resistance are poor, which affects the drilling processability of printed circuit boards.
[0006] In the traditional resin compounding solution, aluminum hydroxide, silicon dioxide and other inorganic fillers are generally added to improve the rigidity and thermal expansion properties of the sheet, and are used in the fields of high-density interconnection (HDI) and IC packaging, but metal foil and traditional Poor adhesion and heat resistance between resins affect product quality
[0007] Japanese patents with publication numbers Hei 11-207868, Hei 09-254313, 2001-316563 and 2001-316564 disclose a copper-clad laminate (re

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0036] Example one

[0037] (1) Preparation of epoxy resin solution: Weigh 100 parts by weight of bisphenol A Novrak type epoxy resin, 67 parts by weight of phenolic resin, 0.5 parts by weight of 2-ethyl-4-methylimidazole, and add to 100 parts by weight Part of the methyl ethyl ketone solvent is stirred and mixed to prepare a resin compounding liquid.

[0038] (2) Inorganic whisker surface treatment: weigh 72 parts by weight of magnesium borate whiskers (average diameter of 0.8μm, average length of 20μm, elastic modulus greater than 200GPa) and 29 parts by weight of borate coupling agent (borate positive Butanol-diethanolamine ester, n-BE4), and then add 30 parts by weight of methyl ethyl ketone solution, stir and mix well.

[0039] Then add the magnesium borate whisker solution to the resin compounding solution, continue to stir and mix evenly. An epoxy resin compound liquid containing magnesium borate whiskers with a solid content of 60% was obtained.

[0040] (3) 8 pieces of 76...

Example Embodiment

[0042] Experimental example two

[0043] (1) Preparation of epoxy resin solution: Weigh 100 parts by weight of bisphenol A Novrak type epoxy resin, 67 parts by weight of phenolic resin, 0.5 parts by weight of 2-ethyl-4-methylimidazole, and add to 100 parts by weight Part of the methyl ethyl ketone solvent is stirred and mixed to prepare a resin compounding liquid.

[0044] (2) Surface treatment of inorganic whiskers: Weigh 19 parts by weight of magnesium borate whiskers (average diameter of 0.8μm, average length of 20μm, elastic modulus greater than 200GPa) and 7.6 parts by weight of borate coupling agent (borate Butanol-diethanolamine ester, n-BE4), dissolve it with 16.4 parts by weight of solvent, stir and mix well.

[0045] Then add the magnesium borate whisker solution to the resin compounding solution, continue to stir and mix evenly. An epoxy resin compound liquid containing magnesium borate whiskers with a solid content of 60% was obtained.

[0046] Then, the bonding sheet ...

Example Embodiment

[0047] Experimental example three

[0048] (1) Preparation of epoxy resin solution: Weigh 100 parts by weight of bisphenol A Novrak type epoxy resin, 67 parts by weight of phenolic resin, 0.5 parts by weight of 2-ethyl-4-methylimidazole, and add to 100 parts by weight Part of the methyl ethyl ketone solvent is stirred and mixed to prepare a resin compounding liquid.

[0049] (2) Inorganic whisker surface treatment: weigh 251 parts by weight of magnesium borate whiskers (average diameter of 0.8μm, average length of 20μm, elastic modulus greater than 200GPa) and 100 parts by weight of borate coupling agent (borate positive Butanol-diethanolamine ester, n-BE4), dissolve with 79 parts by weight of solvent, stir and mix well.

[0050] Then add the magnesium borate whisker solution to the resin compounding solution, continue to stir and mix evenly. An epoxy resin compound liquid containing magnesium borate whiskers with a solid content of 60% was obtained.

[0051] Then, the bonding she...

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PUM

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Abstract

The invention discloses a resin matching fluid, comprising the following components: epoxy resin, a curing agent, a curing accelerator, a solvent, an inorganic crystal whisker and a surface coupling agent; the surface coupling agent is one or mixture of two or more than two selected form triethanolamine borate, diethanolamine n-butanol-borate, diethanolamine sec-butanol-borate or diethanolamine t-butanol-borate; due to the use of borate ester surface coupling agent, the resin matching fluid improves the compatibility of inorganic crystal whisker and thermosetting resin, thus obtaining the metal foil laminated board with high rigidity, low coefficient of thermal expansion and high cohesiveness; and a printed circuit board of the metal foil laminated board has high circuit processability in manufacture, thus being capable of meeting the requirements of thin multi-layer printed circuit boards and being applicable to HDI boards and IC package substrates.

Description

technical field [0001] The invention relates to a resin compounding solution required for the preparation of metal foil laminated boards, and is specifically designed and applied to the resin compounding liquid in the field of preparing high-density interconnect multilayer boards or IC packaging. Background technique [0002] In recent years, electronic products have been miniaturized and multi-functional, making printed circuit boards develop in the direction of fineness, thinness, and multi-layers. More and more high-end products use high-density interconnect (HDI) multi-layer boards; Due to the increasingly complex production and use processes, higher requirements are put forward for the performance of PCB substrate materials, requiring the board to have high thermal mechanical strength, low thermal expansion rate, and glass transition temperature; at the same time, because the substrate material for packaging is thinner, more Due to the pursuit of narrower spacing and mu...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08K13/04C08K5/55C08K5/16C08K7/04B32B15/092
Inventor 肖升高崔春梅罗鹏辉沙蕾计仙
Owner SHENGYI TECH SUZHOU
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