Composite bactericidal microemulsion containing triadimefon and ethylicin and preparation method thereof

A technology of acetoallin and triadimefon, which is applied in the field of pesticides, can solve problems such as unfavorable safety production, transportation and storage, influence of wettable powder drug efficacy, and environmental hazards of organic solvents, so as to reduce product toxicity and production costs, and improve The safety of production and storage, and the effect of improving drug efficacy

Inactive Publication Date: 2010-02-10
ZHENGZHOU UNIVERSITY OF LIGHT INDUSTRY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the main dosage forms of triadimefon and acetocilin preparations are emulsifiable concentrates and wettable powders. The production process of emulsifiable concentrates needs to consume a large amount of toxic and flammable organic solvents, which is not conducive to safe production, transportation and storage; Volatilization can be harmful to the environment
The disadvantages of wettable powder in the process of use are that it is easy to cause the powder to fly when preparing the spray liquid, causing harm to the operator, and the remaining powder in the packaging bag pollutes the environment
In addition, during the spraying process of the emulsifiable pesticide with oil as the medium, the pesticide is dispersed in the aqueous solution in the form of small emulsifiable droplets. After spraying on the leaves of crops, it is not conducive to the wetting of the leaves, thus affecting the efficacy. , the efficacy of wettable powder is also affected by the fineness of the powder

Method used

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  • Composite bactericidal microemulsion containing triadimefon and ethylicin and preparation method thereof
  • Composite bactericidal microemulsion containing triadimefon and ethylicin and preparation method thereof
  • Composite bactericidal microemulsion containing triadimefon and ethylicin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] Select the following formula: triadimefon 5%; acetoallin 2%; cyclohexanone 7%; nonylphenol polyoxyethylene ether 12%; calcium alkylbenzenesulfonate 3%; n-butanol 9%; water 64% .

[0028] Preparation method: at room temperature, dissolve 5kg triadimefon and 2kg acetoallin in 7kg cyclohexanone, and at the same time dissolve 9kg n-butanol, 3kg alkylbenzenesulfonate calcium (ABS-Ca) and 12kg nonylphenol polyoxygen Vinyl ether (Tx-10) was formulated as an emulsifier. After the two were mixed evenly under stirring conditions, 64kg of water was slowly added under stirring, and fully stirred for 30 minutes to obtain a homogeneous clear liquid, which was 5% triadimefon+2 % Acetoallicin microemulsion.

Embodiment 2

[0030] Select the following formula: triadimefon 8%; 3% ethyl allicin; cyclohexanone 10%; isoamyl alcohol 7%; polyoxyethylene sorbitan monofatty acid ester (Tween-20) 17%; Calcium acid (ABS-Ca) 7%; water 48%.

[0031] Prepared according to the method of Example 1, that is, 8% triadimefon + 3% acetoallin microemulsion.

Embodiment 3

[0033] Choose the following formula: triadimefon 10%; 2.5% acetoallin; cyclohexanone 12.5%; ethanol 7.5%; nonylphenol polyoxyethylene ether (Tx-10) 16%; g calcium alkylbenzene sulfonate (ABS -Ca) 7.5%; water 44%.

[0034] Prepared according to the method of Example 1, namely 15% triadimefon+3% acetoallin microemulsion.

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Abstract

The invention discloses composite bactericidal microemulsion containing triadimefon and ethylicin, which consists of the following components in percentage by weight: 5 to 15 percent of triadimefon, 1to 5 percent of ethylicin, 5 to 25 percent of organic solvent, 15 to 25 percent of primary surfactant, 3 to 10 percent of cosurfactant, and the balance of water. The invention also discloses a methodfor preparing the microemulsion. The microemulsion is apparently transparent or almost transparent uniform liquid, has no sediments and floating oil after being diluted, has excellent cold / hot storage stability and ageing stability, high transfer efficiency, high flash point, safe production, transportation, storage and usage, less environmental pollution, low production and use cost, and high bactericidal effect.

Description

technical field [0001] The invention belongs to the technical field of pesticides, and in particular relates to a compound bactericidal microemulsion containing triadimefon and acetoallicin and a preparation method thereof. Background technique [0002] Triadimefon (triadimefon), also known as Fenxiu Ning, triazole dimethyl ketone, chlorothalone, Bailitong and so on. The pure product is colorless crystal with special smell, melting point 82.3℃, slightly soluble in water at 20℃, soluble in most organic solvents. The original powder is a white to light yellow solid with a melting point greater than 70°C and is relatively stable under acidic and alkaline conditions. It has the characteristics of high efficiency, broad spectrum, low residue, long residual period and strong systemic absorption. It is easily absorbed by plants and conducted in the body. It has the functions of protection, treatment, eradication and fumigation. It is a low toxicity fungicide. Rat Acute Oral LD...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/04A01N43/653A01N41/00A01P3/00
Inventor 王军杨许召李刚森
Owner ZHENGZHOU UNIVERSITY OF LIGHT INDUSTRY
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