Method for producing potassium fertilizer and building bricks by using dry method or semi-dry method desulfurization ash
A semi-dry desulfurization and desulfurization ash technology, applied in potash fertilizers, applications, inorganic fertilizers, etc., can solve the problems of a large amount of desulfurization ash accumulation environment, pollution, etc., to reduce the content of sulfite and sulfate, and the process flow Simple, quality-enhancing effects
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[0024] Example 1
[0025] In the dry desulfurization ash of a coal-fired power plant, calcium sulfite (CaSO 3 ·1 / 2H 2 O) and calcium sulfate (CaSO 4 ·2H 2 O) The sum of weight accounts for 56.27%, and the molar ratio of the two is 1.43:1. Other calcium-based compounds include CaCO 3 ,Ca(OH) 2 And CaO, etc., the content accounts for 38.91% (weight), in addition, there is a small amount of fly ash in the material.
[0026] The above-mentioned desulfurized ash slag, together with potash ore and additives, is made into potash fertilizer and building materials building bricks according to the following steps and process conditions:
[0027] (1) Raw material configuration and roasting: blend desulfurization ash, potassium ore and calcium chloride additives with weights of 40.2kg, 55.4kg and 4.4kg respectively, add water accounting for 40% of the total weight of the three materials, ball mill 30 minutes to about 200 mesh (0.074mm), the material is dried to a moisture content o...
Example Embodiment
[0031] Example 2:
[0032] A coal-fired boiler plant adopts the semi-dry method for flue gas desulfurization. In the dry desulfurization ash, calcium sulfite (CaSO 3 ·1 / 2H 2 O) and calcium sulfate (CaSO 4 ·2H 2 O) The sum of weight accounts for 76.78%, and the molar ratio of the two is 8.23:1. Other calcium-based compounds include CaCO 3 ,Ca(OH) 2 And CaO, etc., the content accounts for 18.91% (weight), in addition, there is a small amount of fly ash in the material.
[0033] The above-mentioned desulfurized ash slag, together with potash ore and additives, is made into potash fertilizer and building material bricks according to the following steps and process conditions:
[0034] (1) Raw material configuration and roasting: blend desulfurization ash, potassium ore and calcium chloride additives weighing 55.4kg, 39.7kg and 4.9kg respectively, add water accounting for 41% of the total weight of the three materials, ball mill 25 Minute to about 300 orders, the material i...
Example Embodiment
[0038] Example 3
[0039] A 30-ton coal-fired boiler in a paper mill uses calcium-based semi-dry method for flue gas desulfurization. In the desulfurized ash produced, calcium sulfite CaSO 3 ·1 / 2H 2 O) and calcium sulfate (CaSO 4 ·2H 2 O) The sum of weight accounts for 68.89% by weight, and the molar ratio of the two is 4.68:1. Other calcium-based compounds include CaCO 3 ,Ca(OH) 2 And CaO, etc., its content accounts for 30.23% (weight), in addition, there is a small amount of fly ash in the material.
[0040] The above-mentioned desulfurized ash slag, together with potash ore and additives, is made into potash fertilizer and building material bricks according to the following steps and process conditions:
[0041] (1) Raw material configuration and roasting: blend desulfurization ash, potassium ore and calcium chloride additives with weights of 50.38kg, 48.57kg and 1.05kg respectively, add water that accounts for 37% of the total weight of the three materials, ball mil...
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