Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Copper-zinc-tin-sulfur quaternary compound, thin film solar cell formed by same, and preparation method thereof

A technology of thin-film solar cells and quaternary compounds, which is applied in the manufacture of circuits, electrical components, and final products, can solve problems such as hindering the photovoltaic performance of thin-film solar cells, difficult to control product stoichiometry, and difficult to remove organic solvents, and achieve stoichiometric The effect of easy control, adjustable, strong adhesion and low cost

Inactive Publication Date: 2010-08-04
HEFEI UNIV OF TECH
View PDF4 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Common methods for preparing copper-zinc-tin-sulfur quaternary compound semiconductor films mainly include vapor deposition of metal precursors followed by vulcanization and magnetron sputtering. Japanese patent JP2009135316A uses vapor deposition of metal precursors followed by vulcanization to prepare copper-zinc Tin-sulfur quaternary compound thin films and corresponding n-cadmium sulfide / p-copper zinc tin-sulfur quaternary compound thin-film solar cells have a photoelectric conversion efficiency of 6.9%; Hironori Katagiri et al. (Thin Solid Films, 2007, 515: 5997-5999 ) prepared copper-zinc-tin-sulfur quaternary compound films and thin-film solar cells in the same way, and obtained a photoelectric conversion efficiency of 5.74%; Russian patent RU2347299C1 prepared copper-zinc Tin-sulfur quaternary compound film; Chinese patents CN101026198A and CN101101939A have prepared copper-zinc-tin-sulfur quaternary compound film by melting alloys and magnetron sputtering. The vulcanization process of these preparation methods is complicated and the stoichiometric ratio of the product is difficult to control , The preparation process requires vacuum or gas protection, etc.
Recently, Journal of the American Chemical Society (J.AM.CHEM.SOC.2009, 131, 11672-11673; J.AM.CHEM.SOC.2009, 131, 12554-12555; J.AM.CHEM.SOC.2009, 131 , 12054-12055) reported the use of metal-organic compounds of copper, zinc, and tin in organic solvent oleylamine solution to synthesize copper-zinc-tin-sulfur quaternary compound nanomaterials at 225-300 ° C. These preparation methods are expensive and difficult to obtain in organic solvents. Removal, residual organic matter hinders the improvement of photovoltaic performance of thin-film solar cells

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] (1), preparation of copper-zinc-tin-sulfur quaternary compound powder:

[0018] Mix copper sulfide, zinc sulfide, and stannous sulfide in a molar ratio of 1:0.2:0.2, then add them to an appropriate amount of water, and mill them in a ball mill for more than one hour; ℃ treatment for more than two hours, that is, copper zinc tin sulfur quaternary compound powder;

[0019] (2), preparation of copper-zinc-tin-sulfur quaternary compound film:

[0020] Use the aluminum dihydrogen phosphate solution or the mixed solution of aluminum oxide and aluminum dihydrogen phosphate or the mixed solution of copper oxide and aluminum dihydrogen phosphate as the adhesive, mix the copper-zinc-tin-sulfur quaternary compound powder with the adhesive, and then coat the film , dried at 40°C, and then dried and cured at 400°C for more than one hour to obtain a copper-zinc-tin-sulfur quaternary compound film.

[0021] (3) Assembly of p-copper zinc tin sulfur quaternary compound / n-tin disulfide...

Embodiment 2

[0024] Mix copper sulfide, zinc sulfide, and stannous sulfide in a molar ratio of 1:0.8:0.8, then add them to an appropriate amount of water, and ball mill them in a ball mill for more than one hour; ℃ treatment for more than two hours to obtain copper-zinc-tin-sulfur quaternary compound powder; others are the same as in Example 1.

Embodiment 3

[0026] Mix copper sulfide, zinc sulfide, and stannous sulfide in a molar ratio of 1:0.5:0.5, then add them to an appropriate amount of water, and ball mill them in a ball mill for more than one hour; ℃ treatment for more than two hours to obtain copper-zinc-tin-sulfur quaternary compound powder; others are the same as in Example 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a copper-zinc-tin-sulfur quaternary compound, a thin film solar cell formed by the same, and a preparation method thereof. The thin film solar cell comprises a conductive glass / metal gate electrode and a metal backing electrode, and is characterized in that: a p-copper-zinc-tin-sulfur quaternary compound thin film and an n-stannic sulfide thin film which form a p-n structure are arranged between the conductive glass / metal gate electrode and the metal backing electrode. The preparation method for the copper-zinc-tin-sulfur quaternary compound comprises the following steps: mixing copper sulfide, zinc sulfide and stannous sulfide in a mole ratio of 1:0.2-0.8:0.2-0.8; adding the mixture into an appropriate amount of water and performing ball grinding for more than 1 hour; transferring the obtained mixed liquid to a high-pressure autoclave; and performing hydro-thermal treatment for more than 2 hours at the temperature of between 120 and 280 DEG C to obtain copper-zinc-tin-sulfur quaternary compound powder. The thin film solar cell prepared by the invention has the advantages of strong adhesive force, low resistance and rich raw material sources; and the preparation method has the advantages of simple preparation process, low cost and environmental friendliness.

Description

technical field [0001] The invention relates to the field of thin-film solar cells, in particular to a thin-film solar cell and a method for preparing a thin-film solar cell and a copper-zinc-tin-sulfur quaternary compound film constituting the thin-film solar cell, and a method for preparing a p-n junction structure thin-film solar cell. Background technique [0002] Copper-zinc-tin-sulfur quaternary compounds do not contain low-abundance elements Ga, In, Se, and toxic elements Cd, etc., and the band gap is about 1.5eV, which matches the solar spectrum, and the absorption coefficient is as high as 10 4 cm -1 . According to relevant theoretical calculations, single-junction copper-zinc-tin-sulfur quaternary compound thin-film solar cells operate at AM 1.5 and 100mW / cm 2 Under bright light, the photovoltaic performance parameters are: open circuit voltage 1.23V, short circuit current density 29.0mA / cm 2 , fill factor 90.0%, photoelectric conversion efficiency up to 32.2%, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): H01L31/032H01L31/18
CPCY02P70/50
Inventor 史成武刘清安史高杨陈柱
Owner HEFEI UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products