Recipe and preparation method of high-voltage gradient zinc oxide resistance card

A technology of zinc oxide resistance sheet and high voltage, which is applied in the field of resistance materials for lightning arresters, can solve the problems of electrical performance degradation, resistance sheet performance degradation, and large energy demand, and achieve the effect of easy crushing process and high efficiency

Active Publication Date: 2010-11-10
NINGBO ZHENHAI GUOCHUANG HIGH VOLTAGE ELECTRIC APP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, although these methods achieve the purpose of reducing the grain size and increasing the voltage gradient of the resistor, on the other hand, they lead to the nonlinear performance of the resistor and the reduction of electrical performance (such as 4/10μs large current flow capacity and 2ms Reduced square wave flow capacity, etc.)
Japanese Patent Application No. 49-064897 and Japanese Patent Application No. 53-044900 use the addition of a large amount of SiO 2 way to increase the voltage gradient, however, a large amount of SiO 2 Adding too much Zn 2 SiO 4 Second phase, causing other electrical properties to decrease, such as increas...

Method used

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  • Recipe and preparation method of high-voltage gradient zinc oxide resistance card
  • Recipe and preparation method of high-voltage gradient zinc oxide resistance card
  • Recipe and preparation method of high-voltage gradient zinc oxide resistance card

Examples

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Effect test

Embodiment 1

[0064] Formula: Composed of zinc oxide, subcomponents and trace components, the subcomponents are oxides of subelements, and the trace components are nitrates of trace elements or glass powder containing trace elements.

[0065] Accessory elements: bismuth, antimony, cobalt, manganese, chromium, silicon and nickel;

[0066] Trace elements: aluminum, boron and silver;

[0067] Each auxiliary element is added in the form of its oxide, the aluminum element in the trace elements is added in the form of aluminum nitrate, and the boron and silver elements are added in the form of glass powder corresponding to the two elements.

[0068] In terms of mass percentage, the contents of zinc, bismuth, antimony, cobalt, manganese, chromium, silicon, nickel, aluminum, boron and silver are as follows:

[0069] Bismuth: 4.0%, Antimony: 3.6%, Cobalt: 0.6%, Manganese: 0.46%, Chromium: 0.2%, Silicon: 0.6%, Nickel: 0.45%, Aluminum 0.03%, Boron 0.002 %, silver element: 0.02%, and the balance is z...

Embodiment 2

[0075] Formula: Composed of zinc oxide, subcomponents and trace components, the subcomponents are oxides of subelements, and the trace components are nitrates of trace elements or glass powder containing trace elements.

[0076]Accessory elements: bismuth, antimony, cobalt, manganese, nickel, silicon and magnesium

[0077] Trace elements: aluminum, boron and silver;

[0078] Each auxiliary element is added in the form of its oxide, the aluminum element in the trace elements is added in the form of aluminum nitrate, and the boron and silver elements are added in the form of glass powder corresponding to the two elements.

[0079] In terms of mass percentage, the contents of zinc, bismuth, antimony, cobalt, manganese, nickel, silicon and magnesium, aluminum, boron and silver are as follows:

[0080] Bismuth: 4.5%, Antimony: 4.0%, Cobalt: 1.2%, Manganese: 0.3%, Nickel: 0.47, Silicon: 0.22%, Magnesium: 0.08%, Aluminum: 0.012%, Boron: 0.008%, silver element: 0.004%, and the balan...

Embodiment 3

[0086] Formula: Composed of zinc oxide, subcomponents and trace components, the subcomponents are oxides of subelements, and the trace components are nitrates of trace elements or glass powder containing trace elements.

[0087] Accessory elements: bismuth, antimony, cobalt, manganese, nickel, tin and yttrium;

[0088] Trace elements: aluminum, boron and silver;

[0089] Each auxiliary element is added in the form of its oxide, the aluminum element in the trace elements is added in the form of aluminum nitrate, and the boron and silver elements are added in the form of glass powder corresponding to the two elements.

[0090] In terms of mass percentage, the contents of zinc, bismuth, antimony, cobalt, manganese, nickel, tin, yttrium, aluminum, boron and silver are as follows:

[0091] Bismuth: 5.1%, Antimony: 4.1%, Cobalt: 1.9%, Manganese: 0.64%, Nickel: 0.66%, Tin: 0.38%, Yttrium: 0.15%, Aluminum: 0.01%, Boron : 0.005%, silver element: 0.015%, and the balance is zinc elemen...

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Abstract

The invention discloses a recipe and a preparation method of a high-voltage gradient zinc oxide resistance card. The recipe of the zinc oxide resistance card of the invention reasonably and preferably adopts the ingredients and the contents of the zinc oxide resistance card, the zinc oxide resistance card prepared by the recipe has the high-voltage gradient as high as 350 to 600v/mm, and at the same time, under the high-voltage gradient, the zinc oxide resistance card can maintain good nonlinear characteristic, electrical property and ageing-resistant characteristic to meet the miniaturization requirement of electronic components such as lightning protectors in practical application. In the preparation method of the zinc oxide resistance card of the invention, the accessory ingredients and trace ingredients in the zinc oxide resistance card have fine granularity, are matched, and are uniformly mixed, the impurity mixing quantity is reduced, at the same time, because the low-temperature heat-insulation process is added in the sintering process, the zinc oxide resistance card forms a stable crystal boundary structure which is favorable for improving the stability of the zinc oxide resistance card and the phase change of the bismuth oxide in the secondary heat treatment process, so the electrical property of the zinc oxide bismuth oxide can be improved.

Description

technical field [0001] The invention relates to the field of resistance materials for lightning arresters, in particular to a formula and a preparation method of a high-voltage gradient zinc oxide resistance sheet. Background technique [0002] Zinc oxide resistors have very superior nonlinear characteristics, and are widely used in power systems as the core components of lightning arresters to protect electrical equipment from overvoltage damage such as lightning. [0003] In recent years, with the development of the economy, the requirements for the transmission capacitance and voltage in the power system have been continuously improved. New requirements were put forward. At present, the miniaturization of power transmission and transformation equipment has become a major problem that needs to be solved urgently. [0004] The voltage gradient of existing zinc oxide resistors is low, generally 180-220V / mm. When zinc oxide resistors are used in transmission lines with high...

Claims

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Application Information

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IPC IPC(8): C04B35/453C04B35/622
Inventor 段雷许高杰陈越高奇峰李向军严斌杰王海英蒋烨汤建江崔平
Owner NINGBO ZHENHAI GUOCHUANG HIGH VOLTAGE ELECTRIC APP
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