Glass ceramics made from high silicon iron tailings and manufacturing method thereof
A technology of high-silicon iron tailings and glass-ceramics, applied in the direction of solid waste removal, etc., can solve the problems of high raw material cost, increased fuel consumption, high melting temperature of glass, etc., achieve good social and economic benefits, and improve melting Speed, the effect of lowering the melting temperature
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Embodiment 1
[0025] The glass batch is made by weighing and mixing, and its composition by weight is: 70 parts of iron tailings, 15 parts of quartz, 6 parts of limestone, 3.5 parts of alumina, 9.5 parts of soda ash, 4 parts of zinc oxide, carbonic acid Barium 3 parts.
[0026] Put the above-mentioned glass batch material in a mullite crucible and melt it in a box-type electric furnace at a temperature of 1450°C for 4 hours. After the melting is completed, the glass liquid flows directly into the water to become glass pellets. Spread 700 grams of glass granules in a refractory mold with a size of 120×120 mm, and conduct crystallization in a box-type electric furnace. The crystallization temperature is 1070° C., and the crystallization time is 30 hours. Thereby, a black glass-ceramic sample of 120×120×18 mm was obtained.
Embodiment 2
[0028] The glass batch is made by weighing and mixing, and its composition by weight is: 40 parts of iron tailings, 32 parts of quartz, 17.7 parts of limestone, 6.5 parts of alumina, 8.5 parts of soda ash, 5 parts of zinc oxide, carbonic acid 6 parts of barium, 3 parts of borax, 0.3 parts of copper oxide, 0.15 parts of carbon powder.
[0029] The above-mentioned glass batch materials are melted in a glass tank kiln at a temperature of 1450° C. for 4 hours. After the melting is completed, the glass liquid flows directly into the water to become glass pellets. Spread 26 kg of glass pellets in a refractory mold with a size of 6000×9000mm, and carry out crystallization in a shuttle kiln fueled by liquefied petroleum gas. The crystallization temperature is 1050°C and the crystallization time is 30 hours. Thus, a red glass-ceramic sample of 600×900×18 mm can be obtained.
Embodiment 3
[0031] The glass batch is made by weighing and mixing, and its composition by weight is: 30 parts of iron tailings, 40 parts of quartz, 19.2 parts of calcium carbonate, 6 parts of alumina, 8.5 parts of soda ash, 5 parts of zinc oxide, 6 parts of barium carbonate, 2 parts of borax, 0.2 part of chromium trioxide.
[0032] Put the above-mentioned glass batch material in a mullite crucible and melt it in a box-type electric furnace at a temperature of 1500°C for 4 hours. After the melting is completed, the glass liquid flows directly into the water to become glass pellets. Spread 700 grams of glass granules in a refractory mold with a size of 120×120 mm, and conduct crystallization in a box-type electric furnace. The crystallization temperature is 1070° C., and the crystallization time is 30 hours. A green glass-ceramic sample of 120×120×18 mm can thus be obtained.
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