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Low-cost concrete antifreezing pumping aid and preparation method thereof

An antifreeze pump and concrete technology, applied in the field of concrete pumping agent, can solve the problems of darkening of the concrete surface, poor adaptability of the retarder, affecting the application promotion, etc. good effect

Active Publication Date: 2012-07-25
安徽海螺材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, many domestic colleges and universities and production companies have conducted a lot of research on the synthesis and application of polycarboxylate superplasticizers, and mass production. The application of polycarboxylate superplasticizers is the development of green concrete admixtures. An important direction, the main problem at present is that the price is high, and the adaptability to air-entraining agents, antifreeze agents, retarders, etc. commonly used in naphthalene-based water reducers is not good
[0005] The sulfonated acetone-formaldehyde condensate has a high water-reducing rate, which is very beneficial to the increase of the early strength of concrete, but the fluidity loss is relatively large when preparing high-fluidity concrete, and the addition of a large amount of sulfonated acetone-formaldehyde condensate will make the The color of the concrete surface becomes darker, thus affecting its application and promotion

Method used

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  • Low-cost concrete antifreezing pumping aid and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Put 380kg of deionized water and 180kg of methyl vinyl polyoxyethylene (TPEG) with a molecular weight of 2400 in the reactor, raise the temperature to 60°C, add 0.5kg of hydrogen peroxide and react for 8 minutes, then add 60kg of 50% acrylic acid aqueous solution dropwise And 5kg of 10% sodium thiosulfate aqueous solution. After 4 hours of dropping, keep warm for 2 hours, lower the temperature to below 40°C, neutralize with lye until the pH is 6~7, obtain the polycarboxylate water reducer, and adjust the solid content to 40%.

[0040] Add 506 kg of water, 200 kg of the obtained polycarboxylate superplasticizer, 4 kg of triterpene saponins, and 150 kg of 36% concentration of sulfonated acetone-formaldehyde condensate solution into the reaction kettle, and raise the temperature to 45-55°C. Add 100 kg of sodium lignosulfonate into the reaction kettle, stir thoroughly, and centrifuge at high speed to remove the precipitate after the dissolution is completed. The speed of ce...

Embodiment 2

[0042] Put 430kg of deionized water and 245kg of methyl vinyl polyoxyethylene (TPEG) with a molecular weight of 2400 in the reactor, raise the temperature to 70°C, add 0.8kg of hydrogen peroxide and react for 10 minutes, then add 80kg of 50% acrylic acid aqueous solution dropwise And 8kg of 10% sodium thiosulfate aqueous solution. After 5 hours of dropping, keep warm for 1 hour, lower the temperature to below 40°C, neutralize with lye until the pH is 6~7, and obtain the polycarboxylate water reducer, the molecular weight is between 5000~20000, and the solid content is adjusted to 40% .

[0043] Add 481 kg of water, 280 kg of the polycarboxylate superplasticizer obtained, 2 kg of fatty alcohol polyoxyethylene ether, 2 kg of triterpene saponin, and 110 kg of sulfonated acetone-formaldehyde condensate solution into the reactor, and raise the temperature to 45-55°C. Add 70 kg of sodium lignosulfonate into the reaction kettle, stir well, and centrifuge at high speed to remove the ...

Embodiment 3

[0045] Add 498 kg of water, 250 kg of polycarboxylate superplasticizer obtained in Example 2, 3 kg of triterpene saponins, and 130 kg of sulfonated acetone-formaldehyde condensate solution into the reactor, and raise the temperature to 45-55°C. Add 80 kg of sodium lignosulfonate into the reaction kettle, stir well, and centrifuge at high speed to remove the precipitate after the dissolution is completed. The speed of centrifugation is 950~1000r / min, and then transfer it into the reaction kettle. Put 15 kg of borax and 30 kg of ethylene glycol into the reaction kettle, stir evenly, and naturally cool to room temperature to obtain the finished product HY-3.

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Abstract

The invention relates to the concrete pumping aid field, in particular to a low-cost concrete antifreezing pumping aid and a preparation method thereof. The concrete pumping aid comprises the following raw materials by weight percent: 20-30% of polycarboxylic acid water reducing agent of which solid content is 40%, 0.3-0.4% of air entraining agent, 0.9-2% of retarder, 11-15% of sulfonated acetone-formaldehyde condensate of which solid content is 36%, 6-10% of sodium lignin sulfonate, 2-4% of antifreezing component and the balance of water. The preparation method comprises the following steps:adding water, air entraining agent, polycarboxylic acid water reducing agent and sulfonated acetone-formaldehyde condensate in a container to heat to 45-55 DEG C, and stirring evenly; adding sodium lignin sulfonate in the container to stir, centrifuging to remove precipitate; and adding retarder and antifreezing component to stir evenly. The low-cost concrete antifreezing pumping aid has good performance; the composite indicators such as the antifreezing property, the pumping property, the water reducing ratio and the ratio of compressive strength are better than that of the antifreezing pumping aid which uses polycarboxylic acid water reducing agent or sulfonated acetone-formaldehyde condensate alone; and the antifreezing pumping aid in the invention has higher adaptability and good costperformance.

Description

technical field [0001] The invention relates to the field of concrete pumping agent, in particular to a low-cost concrete antifreeze pumping agent and a preparation method of the pumping agent. Background technique [0002] Concrete pumping agent is an admixture used in concrete mixing and construction. It can increase the workability of concrete, so that the concrete mixture can pass through the pipeline smoothly, without blocking, without segregation, and with good viscoplasticity. Pumping agent is an admixture that must be used in modern concrete construction. For pumping construction in a normal temperature environment, only the pumping agent can be mixed, but in cold areas, the antifreeze performance of the concrete must also be considered when the construction is carried out at negative temperatures in winter. At this time, the antifreeze pumping agent is needed. It can give concrete good pumpability, and it can also make concrete have antifreeze performance. [0003...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/24
CPCC04B24/2647C04B24/165C04B40/0039
Inventor 冯恩娟傅秀新赵洪义朱化雨
Owner 安徽海螺材料科技股份有限公司
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