Solution for nickel electroforming, electroforming method using solution and thin nickel plate manufactured by using method

An electroforming and solution technology, applied in the field of electroforming nickel sheets and thin-layer nickel sheets, can solve the problems of uneven opening size, curling or warping, insufficient thickness uniformity around micropore openings, etc., and achieve compressive stress. and/or effects of low tensile stress, balanced compressive and tensile stress, simple pattern transfer link

Inactive Publication Date: 2013-02-13
KUN SHAN POWER STENCIL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The current printing stencil is usually made by fine etching technology, but this technology cannot meet the requirements of chip-scale packaging stencil pit printing, and its main defects are as follows:
[0005] (2) There is a problem of lateral corrosion;
[0006] (3) The etching technology is based on chemical dissolution, the surface of the formed opening is rough, and the hole wall is not smooth enough, which is not conducive to the printing of conductive materials;
[0007] (4) The hole size tolerance of the etching printing template is about 20 μm, resulting in uneven hole size;
[0008] (5) The uniformity of the hole size after etching is poor, and there will be a deviation of about 20 μm
In the case of using sodium chloride or nickel chloride, the compressive stress and tensile stress of the thin-layer nickel sheet cannot be balanced, and the prepared thin-layer nickel sheet has high stress, curling or warping.
[0020] Therefore, although the existing electroforming process can overcome the inherent shortcomings of the fine etching process to a certain extent, it is still difficult to overcome (especially difficult to overcome at the same time) the thin nickel sheet produced by electroforming also has problems such as thin Defects such as insufficient thickness uniformity of the layer nickel sheet, insufficient thickness uniformity around the micropore opening, and insufficient flatness after separation from the original mold

Method used

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  • Solution for nickel electroforming, electroforming method using solution and thin nickel plate manufactured by using method
  • Solution for nickel electroforming, electroforming method using solution and thin nickel plate manufactured by using method

Examples

Experimental program
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preparation example Construction

[0057] The present invention has no particular limitation on the preparation method of the nickel electroforming solution. For example, a concentrated nickel sulfamate solution with a concentration such as 180g / L can be diluted with deionized water, and then other components can be added at the stated concentration Just prepare.

[0058] The amount of auxiliary brightener in the nickel electroforming solution can be calculated based on the product of the current and time required for electroforming each time. Preferably, the amount of the auxiliary brightener is 0.1g / L / (100A×h)~0.15g / L / (100A×h), for example, it can be 0.1g / L / (100A×h), 0.11g / L / (100A×h), 0.12g / L / (100A×h), 0.13g / L / (100A×h), 0.14g / L / (100A×h) or 0.15g / L / (100A× h)). For example, using 80A current for electroforming for 0.5 hours, the product of the required current and time is 40A×h, then the concentration of the auxiliary brightener in the nickel electroforming solution should be 0.04g / L~0.06g / L. If the concentrat...

preparation example 1~8 and comparative example 1~3

[0085] The solution for nickel electroforming was prepared with deionized water according to the concentration in Table 1 below, and the auxiliary brightener was added in the form of 100g / L aqueous solution.

[0086] Table 1 Concentrations of components used in nickel electroforming solution

[0087] Numbering

[0088] Comparative example 1

Embodiment 1

[0090] The thin-layer nickel sheet was prepared according to the following steps (see Table 3 for specific process parameters), in which the nickel electroforming solution prepared in Preparation Example 1 was used for electroforming, and a bidirectional pulse power supply was used as the electroforming power supply.

[0091] Activation: Place a bright surface stainless steel substrate (purchased from Changtai Buxiugang Technology Group, 1.5mm thick 304 mirror stainless steel) in an activation tank (the solution is industrial hydrochloric acid and deionized water in a volume ratio of 1:4) Medium activation for 30 minutes.

[0092] Film: Press and paste a layer of 50μm thick photosensitive film for electroforming (purchased from DuPont, 50μm thick, type HM1056) on the surface of the non-embroidered rigid substrate.

[0093] Graphic transfer: the high-precision chromium plate made of the micro-hole pattern to be produced in advance, and then use the chromium plate to expose the micro-h...

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Abstract

The invention provides a solution for nickel electroforming, an electroforming method using the solution and a thin nickel plate manufactured by using the method. The solution for nickel electroforming contains nickel aminosulfonate and nickel sulfate, and preferably also contains nickel bromide. The solution for nickel electroforming is adopted for electroforming in the method, and preferably a bidirectional pulse power supply is adopted as an electroforming power supply. The thin nickel plate has good thickness uniformity, low stress (pressure stress or tensile stress), smooth inner walls of micropores and no micro burrs or pin holes, and can be used for manufacturing an encapsulation template for transferring soldering paste during flip chip encapsulation.

Description

Technical field [0001] The invention belongs to the technical field of material preparation technology, and relates to an electroforming solution, an electroforming method and a thin-layer nickel sheet prepared by the method, in particular to a transfer soldering tin used for making flip-chip packaging. Electroformed nickel sheet for packaging template for paste. Background technique [0002] Integrated circuit flip chip packaging is an advanced chip interconnection technology and an ideal chip bonding technology. It has the advantages of small package area, high I / O density, good heat dissipation, high reliability and improved testability of bare chips. The key process of integrated circuit flip chip packaging is to form bumps on the pads of the chip. Bump molding techniques include evaporation, sputtering, electroplating and stencil printing. Among them, stencil printing has low cost, high efficiency and can be used without Lead solder and other advantages. Although stencil ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D1/00C25D3/12
Inventor 谭建雄胡鹏程赵录军
Owner KUN SHAN POWER STENCIL
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