Solution for nickel electroforming, electroforming method using solution and thin nickel plate manufactured by using method
An electroforming and solution technology, applied in the field of electroforming nickel sheets and thin-layer nickel sheets, can solve the problems of uneven opening size, curling or warping, insufficient thickness uniformity around micropore openings, etc., and achieve compressive stress. and/or effects of low tensile stress, balanced compressive and tensile stress, simple pattern transfer link
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preparation example Construction
[0057] The present invention has no particular limitation on the preparation method of the nickel electroforming solution. For example, a concentrated nickel sulfamate solution with a concentration such as 180g / L can be diluted with deionized water, and then other components can be added at the stated concentration Just prepare.
[0058] The amount of auxiliary brightener in the nickel electroforming solution can be calculated based on the product of the current and time required for electroforming each time. Preferably, the amount of the auxiliary brightener is 0.1g / L / (100A×h)~0.15g / L / (100A×h), for example, it can be 0.1g / L / (100A×h), 0.11g / L / (100A×h), 0.12g / L / (100A×h), 0.13g / L / (100A×h), 0.14g / L / (100A×h) or 0.15g / L / (100A× h)). For example, using 80A current for electroforming for 0.5 hours, the product of the required current and time is 40A×h, then the concentration of the auxiliary brightener in the nickel electroforming solution should be 0.04g / L~0.06g / L. If the concentrat...
preparation example 1~8 and comparative example 1~3
[0085] The solution for nickel electroforming was prepared with deionized water according to the concentration in Table 1 below, and the auxiliary brightener was added in the form of 100g / L aqueous solution.
[0086] Table 1 Concentrations of components used in nickel electroforming solution
[0087] Numbering
[0088] Comparative example 1
Embodiment 1
[0090] The thin-layer nickel sheet was prepared according to the following steps (see Table 3 for specific process parameters), in which the nickel electroforming solution prepared in Preparation Example 1 was used for electroforming, and a bidirectional pulse power supply was used as the electroforming power supply.
[0091] Activation: Place a bright surface stainless steel substrate (purchased from Changtai Buxiugang Technology Group, 1.5mm thick 304 mirror stainless steel) in an activation tank (the solution is industrial hydrochloric acid and deionized water in a volume ratio of 1:4) Medium activation for 30 minutes.
[0092] Film: Press and paste a layer of 50μm thick photosensitive film for electroforming (purchased from DuPont, 50μm thick, type HM1056) on the surface of the non-embroidered rigid substrate.
[0093] Graphic transfer: the high-precision chromium plate made of the micro-hole pattern to be produced in advance, and then use the chromium plate to expose the micro-h...
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