Pouring slag for continuously casting cast steel plate (CSP) sheet billet high-carbon steel

A technology of high carbon steel and slag pouring, applied in the field of steelmaking accessories, can solve the problems of poor lubrication effect of control heat transfer capacity, high carbon steel, slow slag formation speed, low basicity, melting point viscosity, etc., to ensure stability And the effect of uniformity, uniform and stable slag formation and suitable viscosity

Active Publication Date: 2011-06-22
XIXIA LONGCHENG METALLURGICAL MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In general, the general-purpose pouring slag has a faster slag formation speed, and the formed liquid slag has a moderate alkalinity of about 0.8, which can meet the pouring requirements of most models and most steel types, including CSP with high pouring temperature. It is not a big problem when using low carbon and medium carbon, but CSP high carbon steel continuous casting is special, its casting speed is high, the amount of liquid slag required per unit time is large, and the liquidus temperature of high carbon steel is relatively low 1. When the general general pouring slag is used, due to the low temperature of molten steel, the slag is slow to melt, and it is easy to fail to break out when the demand is large and the supply of liquid slag is small;
[0008] 2. The characteristics of high-carbon steel (with a carbon content of 0.26-1%) lead to the failure of CSP continuous casting
First of all, the liquidus temperature of high-carbon steel is usually much lower than that of medium-carbon steel and low-carbon steel. Insufficient heating and calorific value can easily cause molten steel to freeze steel, which will make it difficult to judge on-site operation and cause casting failure; Compared with the former, the casting slag should have lower basicity, melting point and proper viscosity
The lower basicity and melting point are to ensure the good lubrica

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The CSP thin slab high carbon steel continuous casting slag provided in this embodiment is shown in the ingredient table 1:

[0023] raw material

Proportion

chemical composition

index(%)

sodium fluoride

3

silica

13.52

glass powder

12

Calcium Oxide

21.89

Fluorine powder

12

magnesium oxide

0.75

cement clinker

20

Ferric oxide

6.59

white alkali

13

Aluminum oxide

3.21

Scorched powder

5

sodium oxide

13.72

Ferrosilicon

17

Fluoride ion

10.95

Iron Oxide Red

6

fixed carbon

4.25

sodium nitrate

4

sodium nitrate

3.96

cryolite

8

moisture

0.23

iron

2.55

silicon

12.75

[0024]

carbon dioxide

5.3

other impurities

0.33

total

100

total

100

[0025]...

Embodiment 2

[0029] The CSP thin slab high carbon steel continuous casting slag provided in this embodiment is shown in the ingredient table 2:

[0030] raw material

Proportion

chemical composition

index(%)

sodium fluoride

3

silica

13.75

glass powder

12.5

Calcium Oxide

21.6

Fluorine powder

12

magnesium oxide

0.75

cement clinker

19.5

Ferric oxide

6.58

white alkali

13

Aluminum oxide

3.20

Scorched powder

5

sodium oxide

13.78

Ferrosilicon

17

Fluoride ion

10.95

Iron Oxide Red

6

fixed carbon

4.25

sodium nitrate

4

sodium nitrate

3.96

cryolite

8

moisture

0.23

iron

2.55

silicon

12.75

carbon dioxide

5.3

other impurities

0.35

[0031] total

100

total

100

[00...

Embodiment 3

[0036] The CSP thin slab high carbon steel continuous casting slag provided in this embodiment is shown in the ingredient table 2:

[0037] raw material

Proportion

chemical composition

index(%)

sodium fluoride

2

silica

14.25

glass powder

13

Calcium Oxide

20.65

Fluorine powder

15

magnesium oxide

1.25

cement clinker

16

Ferric oxide

7.9

white alkali

13

Aluminum oxide

3.0

Scorched powder

4

sodium oxide

10.5

Ferrosilicon

19

Fluoride ion

9.5

Iron Oxide Red

6

fixed carbon

5.55

sodium nitrate

3

sodium nitrate

4.45

cryolite

9

moisture

0.25

iron

4.55

silicon

13.5

carbon dioxide

4.5

other impurities

0.15

total

100

total

100

[0038] SiO 2 : 9%~19%, MgO: 0....

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PUM

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Abstract

The invention discloses pouring slag for continuously casting cast steel plate (CSP) sheet billet high-carbon steel. During the continuous casting of the CSP sheet billet high-carbon steel, phenomena of binding cold steel, clotting pouring slag and slagging badly do not occur basically when silicon iron is used; the pouring slag has low alkalinity and proper viscosity; after the silicon iron is oxidized quickly, the silicon iron and other components of the pouring slag form acidic slag with alkalinity of 0.5 to 0.7 quickly; and under an acidic slag system, a network limiting body, namely silicon dioxide has high content, so that the viscosity of liquid slag formed by the pouring slag which uses a large number of fusing agent materials such as sodium fluoride, flousper powder, white alkali, cryolite and the like is not ultralow, the liquid slag forms uniform slag membranes between a primary solidification billet shell and the wall of a crystallizer and has long viscous time, and stable, continuous and good lubricating effect is provided during pouring of the CSP high-carbon steel.

Description

technical field [0001] The invention belongs to the technical field of steelmaking auxiliary materials, and in particular relates to a casting slag for continuous casting of CSP thin slab high-carbon steel. technical background [0002] CSP thin slab continuous casting is characterized by its high efficiency and short process, and represents the most advanced strip steel production technology. And other steel mills have introduced multiple sets of CSP continuous casting production lines. [0003] In CSP thin slab continuous casting, casting failure is a relatively common type of vicious accident, which has a huge impact on the continuous casting production line: it directly causes unplanned shutdown of casting, seriously affects the production rhythm, and brings great waste of manpower and material resources and economy to the steel plant. benefit loss. Therefore, solving the failure of casting is an important problem that all CSP continuous casting manufacturers need to s...

Claims

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Application Information

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IPC IPC(8): B22D11/111
Inventor 李晓阳秦教武赵博汪国敏赵春宝
Owner XIXIA LONGCHENG METALLURGICAL MATERIALS CO LTD
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