Anti-glare hard coat film and polarizing plate using the same
A hard coating, anti-glare technology, used in polarizing elements, coatings, instruments, etc., can solve the problems of reduced image clarity, poor visibility, and reduced black density, reducing fading or contrast. The effect of image clarity, appropriate anti-glare
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preparation example Construction
[0074] (Preparation of hard coat layer forming material)
[0075] The hard coat forming material used in the present invention is added to an appropriate solvent in a predetermined ratio according to the above-mentioned active energy line-sensitive composition of component (A), organic fine particles of component (B), and Prepared by dissolving or dispersing the photopolymerization initiator used and various additive components such as antioxidant, ultraviolet absorber, silane coupling agent, light stabilizer, leveling agent, defoamer, etc.
[0076] As the solvent used at this time, for example, aliphatic hydrocarbons such as hexane and heptane, aromatic hydrocarbons such as toluene and xylene, halogenated hydrocarbons such as dichloromethane and dichloroethane, methanol, ethanol, propanol, butanol, Alcohols such as propylene glycol monomethyl ether, ketones such as acetone, methyl ethyl ketone, 2-pentanone, isophorone, and cyclohexanone, esters such as ethyl acetate and butyl a...
preparation example 1
[0148] Preparation Example 1 Coating Agent 1 for Hard Coat
[0149] 50 parts by mass of (A) active energy ray-sensitive type composition containing antistatic agent (compound containing quaternary ammonium base) hard coating agent [manufactured by Nippon Chemical Industry Co., Ltd., trade name "L80313", solid content Concentration 70% by mass, propylene glycol monomethyl ether 30% by mass] and 35 mass parts of hard coat agent not containing antistatic agent [Dainichi Seika Industry (Co., Ltd.) manufacture, trade name " SEIKABI MU EXF-01L (NS )", solid content concentration 100% by mass, active energy ray-curable compound containing reactive monomer and multifunctional acrylate 95% by mass, photopolymerization initiator 5% by mass], as (B) 4 mass % of spherical organic microparticles Parts of polystyrene-polymethyl methacrylate (PSt-PMMA) microparticles [Sekisui Chemical Industry (KK), average particle size 2.5 μm, refractive index 1.555], uniformly mixed with 90 parts by mass ...
preparation example 2
[0150] Preparation Example 2 Coating Agent 2 for Hard Coat
[0151] In addition to adding 4 parts by mass of polymethyl methacrylate (PMMA) particles as (B) spherical organic particles [manufactured by Soken Chemical Co., Ltd., average particle diameter 3 μm, refractive index 1.49], 90 parts by mass as a dilution solvent Except for propylene glycol monomethyl ether, in the same manner as in Preparation Example 1, a coating agent 2 for a hard coat layer having a solid content of about 41% by mass was prepared.
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