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Production technology of PVC external lubricant

A production process and external lubricant technology, applied in the field of plastics, can solve the problems of high labor intensity, high processing temperature, low production efficiency, etc., and achieve the effects of improving product quality, reducing reaction temperature and saving production costs.

Active Publication Date: 2012-06-27
夏瑭
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Because of the inherent molecular structure and polymerization method of polyvinyl chloride, if it is directly used as the only raw material to produce plastic products, its chemical and physical properties have great defects: for example: polyvinyl chloride has poor stability to light and heat
[0007] 1. The purity requirement of adipic acid is high and the price is expensive, which makes the cost of the entire external lubricant higher;
[0008] 2. Adipic acid has poor non-stickiness and large precipitation. During the production process, the operator often needs to stop the machine to insert the roller, which is not only labor-intensive, but also greatly reduces the production efficiency. At the same time, the demoulding effect is poor, which seriously affects the economic benefits of the product;
[0009] 3. Except for a certain lubricating effect, there is no improvement in the comprehensive performance of PVC products such as strength and cold resistance
However, the applicant's previous application documents did not provide any further explanations about the entire technological process
[0011] Afterwards, the application also studied the U.S. invention patent with the publication number US5232967A. The applicant found that this patent was an older patent application, so there were still problems of high cost and low efficiency in terms of process and material selection.
Its specific performance is that the processing temperature adopted is relatively high, and at the same time, those skilled in the art can find through experiments that the final yield and quality of finished products are not as prominent as they claim, and such a technology cannot adapt to modern production

Method used

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  • Production technology of PVC external lubricant
  • Production technology of PVC external lubricant

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Fumaric acid is acid reflux obtained by recycling waste liquid produced by other chemical industries. The standard chemical name of fumaric acid is: fumaric acid; molecular formula is: C 4 h 4 o 4 ; It is a white crystalline powder with a fruity sour taste.

[0048] The process of recovering fumaric acid in the process of producing phthalic anhydride by ortho-method is as follows: the oxidation tail gas of phthalic anhydride produced by ortho-method is washed with water, contains 25%wt cisic acid, and is directly pumped to the fumaric acid production device. Under the action of a catalyst, the cis acid in the waste liquid is isomerized, the catalyst is selected from thiourea, the acid reflux is recovered, and fumaric acid (fumaric acid) is obtained by crystallization. Because the acid water is brown, the crude fumaric acid after cooling and crystallization is brown, decolorized with activated carbon, rinsed and dried to obtain refined fumaric acid.

[0049] During p...

Embodiment 2

[0057] The mass percent of each component is:

[0058] Stearic acid: 40%

[0059] Pentaerythritol: 30%

[0060] Fumaric Acid: 15%

[0061] Ethylene glycol 15%

[0062] Composition, in which fumaric acid is extracted from gutter oil after filtering. During processing, fumaric acid is selected as the mother liquor in proportion, and then ethylene glycol is added in proportion. Stearic acid is added for esterification, followed by high-temperature polymerization at 150°C. After polymerization, dealcoholization is carried out under high-temperature vacuum at 200°C, and sliced ​​after cooling. No catalyst is added during the entire process. The conversion of this reaction is around 94%.

[0063] The appearance of the obtained PVC external lubricant and its manufacturing process is white or light yellow flake or flake powder, with a freezing point of ≥ 56°C, a flash point of ≥ 240°C, and a viscosity of ≤ 90mpa·S at 80°C. When adding PVC raw materials, the general dosage is 0.3%-0...

Embodiment 3

[0065] The mass percent of each component is:

[0066] Stearic acid: 40%

[0067] Pentaerythritol: 20%

[0068] Fumaric Acid: 23%

[0069] Dipropylene Glycol 17%

[0070] Composition, in which fumaric acid is extracted from gutter oil after filtering, first select fumaric acid as the mother liquor in proportion during processing, then first add dipropylene glycol in proportion, after fully stirring, add pentaerythritol according to the above proportion, and finally add Stearic acid is esterified, then polymerized at a high temperature of 150°C, dealcoholized in a vacuum at a high temperature of 200°C after polymerization, sliced ​​after cooling, and no catalyst is added during the whole process. The conversion of this reaction is around 95%.

[0071] The appearance of the obtained PVC external lubricant and its manufacturing process is white or light yellow flake or flake powder, with a freezing point of ≥ 56°C, a flash point of ≥ 240°C, and a viscosity of ≤ 90mpa·S at 80°...

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Abstract

The invention aims at solving problems in prior arts, and provides a PVC external lubricant and a production method thereof. According to the invention, a reaction temperature in a processing process is reduced, and a product proportion is optimized. For reaching the purpose, the method comprises steps that: waste liquid produced from chemical industries is recovered and treated, such that fumaric acid is obtained; during processing, fumaric acid is selected as mother liquor according to a certain proportion; polyhydric alcohol is added according to a certain proportion, and the mixture is sufficiently stirred; pentaerythritol with a certain proportion is added; stearic acid is added for esterification; high temperature polymerization is carried out at a temperature of 150 DEG C to 160 DEG C; the polymerized material is delivered through a vacuum dealcoholizing process at a temperature of 200 DEG C; the obtained material is cooled and sliced. No catalyst is added during the whole processing process. The invention is advantaged in that: with the technical scheme, the reaction temperature is low, the polymerization effect is good, and a finished product conversion rate is high.

Description

【Technical field】 [0001] The invention relates to the field of plastics, in particular to a production process of a PVC external lubricant for PVC engineering additives. 【Background technique】 [0002] PVC (polyvinyl chloride) is a chlorinated polymer of PE (polyethylene). It is one of the most widely used plastics and is still used in large quantities. Its consumption is second only to polyethylene and polypropylene. There are many forms of PVC products, which can be divided into three categories: hard PVC, soft PVC, and PVC paste. Rigid polyvinyl chloride is mainly used in extruded products such as pipes, door and window profiles, sheets, etc., as well as injection molded parts such as pipe joints and electrical parts, and extrusion blown bottle products, which account for more than 65% of the consumption of polyvinyl chloride. Soft polyvinyl chloride is mainly used in calendered sheets, automotive interior accessories, handbags, films, labels, wires and cables, medical p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/52C08G63/676C08G63/78C08L27/06C08L67/06
Inventor 夏森林徐璐莎夏国斌
Owner 夏瑭
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