Carbon nanotube / polymer composite membrane array type flexible force sensor and manufacturing method thereof

A carbon nanotube, polymer technology, applied in the field of nanotechnology and sensing, which can solve the problems of instability, irreversibility, hysteresis, and high carbon black concentration

Inactive Publication Date: 2012-03-14
TSINGHUA UNIV
View PDF3 Cites 54 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although after years of improvement, the piezoresistive coefficient of the carbon black / silicone rubber composite system has been significantly improved, but due to the high concentration of carbon black required, the flexibility of the matrix material is reduced, and the conductive path formed by carbon black particles is affected. Instability and non-recoverability when stressed
In addition, sensitive elements made of this sensitive material often show problems such as poor flexibility, obvious hysteresis, and poor stability. These shortcomings limit the application of pressure-sensitive conductive rubber in high-performance flexible force-sensitive sensors.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Carbon nanotube / polymer composite membrane array type flexible force sensor and manufacturing method thereof
  • Carbon nanotube / polymer composite membrane array type flexible force sensor and manufacturing method thereof
  • Carbon nanotube / polymer composite membrane array type flexible force sensor and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] The parallel metal row electrodes 2 and parallel metal column electrodes 4 and their first insulating protective layer 1 and second insulating protective layer 5 are processed by standard flexible circuit board technology, and the surfaces of the two electrodes are plated with gold to improve the composite with carbon nanotubes / polymers For the contact characteristics of material 3, the thickness of the two electrodes can be within the range of 20-60 μm.

[0055] The multi-walled carbon nanotube A modified by hydroxyl group is used as the conductive filling material, and SBS is selected as the polymer matrix material B; the solvent C is a toluene / acetone mixed solution with a volume ratio of 1:1;

[0056] At room temperature and normal pressure, add carbon nanotube A to solvent C and ultrasonically disperse for 40 minutes. The ratio of carbon nanotube to solvent is 1mg: 40ml, and the ultrasonic power is 300W; then add a polymer 10 times the mass of carbon nanotube A For...

Embodiment 2

[0060] The difference between this embodiment and embodiment 1 is that PDMS with a smaller modulus is used as the polymer matrix material, and ethyl acetate is used as the solvent. The preparation process is the same as in Example 1.

Embodiment 3

[0062] The difference between this embodiment and Embodiments 1 and 2 is that single-armed carbon nanotubes are used as the conductive filling material, and the preparation process is the same as that of Embodiments 1 and 2.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to view more

Abstract

The invention relates to a carbon nanotube / polymer composite membrane array type flexible force sensor and a manufacturing method thereof. The carbon nanotube / polymer composite membrane array type flexible force sensor comprises a parallel metal row electrode and a parallel metal column electrode which are respectively and graphically arranged on the upper and lower surfaces of a carbon nanotube / polymer composite membrane, an upper insulation protecting layer adhered onto the row electrode, and a lower insulation protecting layer adhered onto the column electrode, wherein the row electrode and the column electrode are distributed in a spatial intersection way, and a spatial intersection part and the carbon nanotube / polymer composite membrane contained in the spatial intersection part form a force sensing unit of the array type flexible force sensor; and the carbon nanotube / polymer composite membrane is made by a composite material that carbon nanotubes are uniformly dispersed in a polymer matrix material, and the mass ratio of the carbon nanotubes to the polymer matrix material is (0.1-15): 100. The carbon nanotube / polymer composite membrane in the array type flexible force sensor has the characteristics of excellent flexibility, good repeatability, stable performances, good consistency and the like.

Description

technical field [0001] The invention belongs to the field of nanotechnology and sensing technology, and in particular relates to a carbon nanotube / polymer composite film array type flexible force sensitive sensor and a manufacturing method. Background technique [0002] Because of its good flexibility, the flexible sensor is not limited by the shape of the object to be measured, and can be attached to various regular or irregular surfaces to realize the sensing function. The flexible force sensor is mainly used in the measurement of extrusion force and shear force, and can be used as a tactile sensor. The discovery of carbon nanotubes has injected new vitality into the research of functional materials. Dispersing a very small amount of carbon nanotubes into a polymer will make the entire composite exhibit a certain degree of electrical conductivity. Recent studies have shown that the electrical conductivity of carbon nanotube / polymer composites changes significantly with th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): G01L1/18B81C1/00
Inventor 叶雄英王志峰杨继敏楼思远谢续明
Owner TSINGHUA UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products