Preparation method for high-strength high-toughness flame-retardant polyamide

A technology of flame-retardant polyamide and high toughness, which is applied in the field of preparation of flame-retardant polyamide, which can solve the problems of affecting the surface finish of products, affecting the mechanical properties of substrates, and improving product density, so as to improve production capacity and product appearance quality and Smoothness, improve processing fluidity, slow down the effect of heat aging

A technology of flame-retardant polyamide and high toughness, which is applied in the field of preparation of flame-retardant polyamide, which can solve the problems of affecting the surface finish of products, affecting the mechanical properties of substrates, and improving product density, so as to improve production capacity and product appearance quality and Smoothness, improve processing fluidity, slow down the effect of heat aging

CN102492290AInactive Publication Date: 2012-06-13上海华谊集团华原化工有限公司

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method for high-strength high-toughness flame-retardant polyamide
  • Preparation method for high-strength high-toughness flame-retardant polyamide

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] In terms of parts by mass, 100 parts of nylon 6 with a viscosity of 2.5 was dried with a vacuum rotary drier and mixed with 18 parts of decabromodiphenylethane, 5 parts of antimony trioxide, 3 parts of polyvinyl carbon black, 0.5 parts of light Calcium stearate and 1 part of antioxidant 1098 are mixed evenly and added to the twin-screw extruder from the feeder. The temperature is 240°C, the temperature in the fourth zone is 235°C, the temperature in the fifth zone is 230°C, the temperature in the sixth zone is 230°C, the temperature in the seventh zone is 235°C, the temperature in the eighth zone is 240°C, the temperature of the head is 240°C, and the speed of the main engine is 240r / min. Extrude, cool, dry, and pelletize through the head of the machine to obtain a flame-retardant polyamide composition product. The prepared composite product is injection-molded into a standard sample bar for testing according to a standard size, and the physical properties are tested ac...

Embodiment 2

[0022] In terms of parts by mass, 100 parts of nylon 6 with a viscosity of 2.8 was dried with a vacuum rotary drier and mixed with 16 parts of decabromodiphenylethane, 4 parts of antimony trioxide, 0.5 parts of light calcium stearate, 0.8 parts of antimony Oxygen 1098 is mixed evenly and fed into the twin-screw extruder from the feeder. The temperature of the first zone of the extruder from the feeding port to the die head is 220°C, the temperature of the second zone is 260°C, the temperature of the third zone is 250°C, and the temperature of the fourth zone is 240°C ℃, the temperature in the fifth zone is 235°C, the temperature in the sixth zone is 235°C, the temperature in the seventh zone is 240°C, the temperature in the eighth zone is 245°C, the temperature of the head is 245°C, the speed of the main engine is 240r / min, extrusion from the head of the extruder, cooling, Dried and pelletized to obtain a flame-retardant polyamide composition product. The prepared composite pr...

Embodiment 3

[0024] In terms of parts by mass, 100 parts of nylon 66 with a viscosity of 2.7 was dried with a vacuum rotary drier and mixed with 18 parts of decabromodiphenylethane, 5 parts of antimony trioxide, 3 parts of polyvinyl carbon black, 0.5 parts of light Calcium stearate and 1 part of antioxidant 1098 are mixed evenly and added to the twin-screw extruder from the feeder. The temperature is 260°C, the temperature in the fourth zone is 250°C, the temperature in the fifth zone is 240°C, the temperature in the sixth zone is 240°C, the temperature in the seventh zone is 245°C, the temperature in the eighth zone is 250°C, the temperature of the head is 255°C, and the speed of the main engine is 300r / min. Extrude, cool, dry, and pelletize through the head of the machine to obtain a flame-retardant polyamide composition product. The prepared composite product is injection-molded into a standard sample bar for testing according to a standard size, and the physical properties are tested a...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
tensile strengthaaaaaaaaaa
impact strengthaaaaaaaaaa
tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention relates to a preparation method for high-strength high-toughness flame-retardant polyamide. According to the method, based on 100 parts by weight of polyamide with a relative viscosity of 2.4 to 3.3, 15 to 30 parts by weight of a decabromodiphenylethane fire retardant, 3 to 10 parts by weight of an antimony oxide fire retardant, 0 to 5 parts by weight of a light stabilizer, 0.2 to 1part by weight of a heat stabilizer and 0.5 to 1 part by weight of an anti-oxidant are added so as to obtain a mixture, and the mixture is subjected to melt mixing and extrusion in virtue of a double-screw extruder and then undergoes cooling, drying and pelletizing so as to obtain the high-strength high-toughness flame-retardant polyamide. The method provided in the invention enables nylon to have improved flame retardation and aging resistance and good mechanical properties and allows a product of nylon to have good surface appearance; combined utilization of decabromodiphenylethane and antimony oxide for modification of polyamide enables purposes of the invention to be achieved.

Description

1. Technical field [0001] The present invention relates to a preparation method of high-strength and high-toughness flame-retardant polyamide, more precisely to a kind of electrical and electronic equipment and home appliances used for injection molding that meet the requirements of environmental protection and flame-retardant, especially for the mechanics of photovoltaic cell components. A method for preparing flame-retardant polyamide with excellent performance. 2. Background technology [0002] It is well known that polyamide has many advantages, such as: excellent impact resistance, low temperature resistance, excellent electrical properties and chemical resistance, good processing fluidity, easy extrusion, injection molding, etc. However, the general flame retardant grade of polyamide is UL94V-2, which is still combustible and has the risk of causing fire. Therefore, it is necessary to improve its flame retardant performance and expand its use (electrical equipment par...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
13 Jun 2012
Publication
CN102492290A
IPC
C08L77/00; C08L77/02; C08L77/06; C08K13/02; C08K5/03; C08K3/22; B29B9/06; B29C47/92; B29C48/92
CPC
B29C48/04; B29C48/40; B29C48/911
Inventors
石磊; 冯宁