Double-sided laminated polyester film
A laminated polyester film, double-sided technology, applied in the direction of coating, layered products, synthetic resin layered products, etc., can solve problems such as the reduction of film surface slipperiness, and achieve high-value effects
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[0056] As a specific production example of the polyurethane resin, for example, a method utilizing a reaction between a hydroxyl group and an isocyanate can be mentioned. As the hydroxyl group used as a raw material, polyols are preferably used, and examples thereof include polyether polyols, polyester polyols, polycarbonate polyols, polyolefin polyols, and acrylic polyols. These compounds may be used alone or in combination.
[0057] Examples of polyether polyols include polyethylene glycol, polypropylene glycol, polyethylene glycol, polytetramethylene ether glycol, polyhexamethylene ether glycol, and the like.
[0058] Examples of polyester polyols include polycarboxylic acids (malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, sebacic acid, fumaric acid, maleic acid, p- phthalic acid, isophthalic acid, etc.) or their anhydrides and polyols (ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripro...
Embodiment 1
[0139] Mix polyesters (I) and (II) at a ratio of 90% and 10% respectively, use the mixed raw materials obtained by mixing as raw materials for the outermost layer (surface layer), and use polyester (I) as a raw material for the middle layer, and supply to 2 sets of extruders, each melted at 285°C, co-extruded with 2 types of 2-layer (surface layer / middle layer / surface layer) layer structure on the cooling roll set at 40°C, allowed to cool and solidify, and obtained Unstretched sheet. Next, after stretching 3.4 times in the longitudinal direction at a film temperature of 85°C by using the difference in roll rotation speed, each coating layer composed of the following coating agents is coated on both sides of the film so that the coating amount (after drying) is a predetermined amount. (With respect to the film moving direction, the upper surface is called A side, and the lower surface is called B side), then it is introduced into a tenter, stretched 4.3 times at 120°C in the tr...
Embodiment 2~ Embodiment 8
[0165] In Example 1, the composition of the coating agent coated on the A side and the B side was changed to the composition shown in the following Tables 1 and 2 (units in the table are weight %), and the same as in Example 1 1 was produced in the same manner to obtain a double-sided laminated polyester film. The properties of the obtained double-sided laminated polyester film are shown in Table 3 below.
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