Electrochemical method for preparing super-hydrophobic surface on copper substrate

A superhydrophobic surface, copper matrix technology, applied in the field of electrochemistry, to achieve the effect of simple method, good hydrophobic performance and high efficiency

Inactive Publication Date: 2012-07-04
XIAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, only by changing the surface energy on a smooth surface, the contact angle can usually only be incre

Method used

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  • Electrochemical method for preparing super-hydrophobic surface on copper substrate
  • Electrochemical method for preparing super-hydrophobic surface on copper substrate
  • Electrochemical method for preparing super-hydrophobic surface on copper substrate

Examples

Experimental program
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Example Embodiment

[0024] Example 1

[0025] Step 1. Polish two copper substrates with a size of 50mm×25mm×1.5mm with 800 grit and 1200 grit water sandpaper in order to remove the oxide layer on the surface of the copper substrate, and then apply distilled water and anhydrous to the polished copper substrate. Rinse it with ethanol, and then dry it with a hair dryer for later use;

[0026] Step 2. Add 7g potassium hydroxide and 1.78g potassium persulfate to absolute ethanol, dilute the volume to 150mL, stir evenly to obtain a solution with a potassium hydroxide concentration of 0.83mol / L and a potassium persulfate concentration of 0.044mol / L A;

[0027] Step 3: Add 0.5 mL of fluorosilane dropwise to 30 mL of absolute ethanol, and stir until the fluorosilane is completely dissolved to obtain solution B;

[0028] Step 4. Put the solution A described in step 2 in an electrolytic cell as an electrolyte, and connect the two copper substrates dried in step 1 as anode and cathode to the positive and negative e...

Example Embodiment

[0032] Example 2

[0033] This embodiment is the same as embodiment 1, except that the low surface energy material used is myristic acid, stearic acid or lauric acid.

Example Embodiment

[0034] Example 3

[0035] Step 1. Polish two copper substrates with a size of 50mm×25mm×1.5mm with 800 grit and 1200 grit water sandpaper in order to remove the oxide layer on the surface of the copper substrate, and then apply distilled water and anhydrous to the polished copper substrate. Rinse it with ethanol, and then dry it with a hair dryer for later use;

[0036] Step 2. Add 6.3g potassium hydroxide and 1.78g potassium persulfate to absolute ethanol, dilute to 150mL, stir evenly to obtain potassium hydroxide concentration of 0.75mol / L, potassium persulfate concentration of 0.044mol / L Solution A;

[0037] Step 3: Add 0.5 mL of stearic acid dropwise to 30 mL of absolute ethanol, and stir until the stearic acid is completely dissolved to obtain solution B;

[0038] Step 4. Put the solution A described in step 2 in an electrolytic cell as an electrolyte, and connect the two copper substrates dried in step 1 as anode and cathode to the positive and negative electrodes of the DC pow...

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Abstract

The invention discloses an electrochemical method for preparing a super-hydrophobic surface on a copper substrate. The electrochemical method comprises the following steps: 1) polishing copper substrates by using 800 particle-size and 1200 particle-size waterproof abrasive paper in turn, washing the copper substrates with distilled water and absolute ethyl alcohol in turn, drying the copper substrates by using an electric blower, and standing by; 2) adding potassium hydroxide and potassium peroxydisulfate into the absolute ethyl alcohol, thereby obtaining a solution A; 3) dropwise adding a material with low surface energy into the absolute ethyl alcohol, thereby obtaining a solution B; 4) placing the solution A as electrolyte into an electrolyzer, respectively taking the two dried copper substrates as an anode and a cathode, and electrolyzing; 5) washing the anode copper substrate after being electrolyzed with absolute ethyl alcohol and clean water in turn, and then placing the cleaned anode copper substrate into the distilled water and soaking for more than 2 hours; and 6) uniformly coating the solution B on the soaked anode copper substrate, and then drying in the air, thereby obtaining the copper substrate with the super-hydrophobic surface. A contact angle of the super-hydrophobic surface prepared according to the method provided by the invention is above 162 degrees.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to an electrochemical method for preparing a superhydrophobic surface on a copper substrate. Background technique [0002] The wettability of a solid surface is a very important indicator and mainly depends on the chemical composition and microstructure. Many plants in nature, such as lotus leaves, exhibit extraordinary superhydrophobic properties. The surfaces of these leaves usually have micro / nano-scale composite structures, so they have low rolling angles and contact angles as high as 150°. At present, the methods for preparing superhydrophobic materials mainly include anodic oxidation, electrodeposition, chemical corrosion, plasma etching, laser treatment, electrospinning, chemical vapor deposition, sol-gel, etc. However, these methods still have some shortcomings, such as Expensive materials, complex process control, and the need to use templates all seriously h...

Claims

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Application Information

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IPC IPC(8): C25D11/02
Inventor 郝丽梅赵省贵庞绍芳王瑞平
Owner XIAN UNIV OF SCI & TECH
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