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High-efficiency low-phosphorus corrosion and scale inhibiting dispersant and its preparation method

A scale and dispersant agent, corrosion and scale inhibition technology, applied in chemical instruments and methods, descaling and water softening, water/sludge/sewage treatment, etc. Oxygen and other problems, to achieve the effect of convenient online automatic dosing, high scale inhibition rate and wide application range

Inactive Publication Date: 2012-10-24
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, organophosphate chemicals are most commonly used because of their high efficiency and dual functions of corrosion inhibition and scale inhibition. However, due to their high phosphorus content, a large amount of phosphate will flow into the environment when discharged, which will easily cause phosphorus-rich water systems to form "Red tide" makes the water lack of oxygen and affects the survival of aquatic organisms

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1: High-efficiency, low-phosphorus, corrosion and scale inhibitor dispersant suitable for 5 times the concentration of the source water of the Yangtze River system and its preparation and application

[0032] Formula 1 of the present invention

[0033] The preparation of circulating water high-efficiency low-phosphorus corrosion and scale inhibitor dispersant suitable for a petrochemical enterprise with a water quality of more than five times the concentration multiple, according to the orthogonal test to determine the following formula (mass percentage): 1% dimethylformamide, 10% AA / AMPS copolymer, 10% polyphosphonocarboxylate (PCM), 10% sodium benzoate, 4% sodium molybdate, 1% methiazole, 3% anhydrous zinc chloride and 3% fluorescent tracer compounding agent.

[0034] Product Quality Index

[0035] Appearance Pale yellow liquid, no precipitation

[0036] Density (20 o C), g / cm 3 1.199

[0037] Total phosphate content (as PO 4 3- c...

Embodiment 2

[0048] Example 2: High-efficiency, low-phosphorus, corrosion and scale inhibitor dispersant suitable for 8-fold concentration, low hardness, and low alkalinity water source water quality, and its preparation and application

[0049] Formula 2 of the present invention

[0050] The preparation of high-efficiency low-phosphorus corrosion and scale inhibitor dispersant for circulating water suitable for the water source water quality of an enterprise's circulating water system with low hardness and low alkalinity of more than eight times the concentration multiple, according to the orthogonal test to determine the following formula (mass percentage): 5% two Methylformamide, 15% AA / AMPS copolymer, 18% polyphosphonocarboxylate (PCM), 12% sodium benzoate, 1% sodium molybdate, 1% methiazole, 3% anhydrous chlorine Zinc chloride and 2% fluorescent tracer compound.

[0051] Product Quality Index

[0052] Appearance brown liquid, no precipitation

[0053] Density (20 o C), g / cm 3...

Embodiment 3

[0065] Example 3: High-efficiency and low-phosphorus corrosion and scale inhibition dispersant suitable for high-chloride water source water quality and its preparation and application

[0066] Formula 3 of the present invention

[0067] The preparation of high-efficiency, low-phosphorus, corrosion and scale inhibitor dispersant for circulating water, which is suitable for a petrochemical enterprise to recycle high-chloride sewage water with a concentration factor of more than 5 times, is determined according to the orthogonal test. The following formula (mass percentage): 3% dimethyl formazan Amide, 10% AA / AMPS copolymer, 15% polyphosphonocarboxylate (PCM), 12% sodium benzoate, 5% sodium tungstate, 2% methiazole, 3% anhydrous zinc chloride and 2% fluorescent tracer compound.

[0068] Product Quality Index

[0069] Appearance brown liquid, no precipitation

[0070] Density (20 o C), g / cm 3 1.188

[0071] Total phosphate content (as PO 4 3- count)...

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Abstract

The invention discloses a high-efficiency low-phosphorus corrosion and scale inhibiting dispersant and its preparation method. The high-efficiency low-phosphorus corrosion and scale inhibiting dispersant comprises: 2%-12% of sodium benzoate, 1%-5% of molybdate (or tungstate), 1%-2% of thiazole, 3%-6% of anhydrous zinc chloride, 8%-18% of polyphosphonocarboxylate, 5%-15% of acrylic acid-2-methyl-2-acrylamido propane sulfonic acid copolymer, 3%-6% of a stabilizer, 3%-6% of a tracer, and the balance deionized water. The dispersant of the invention can be widely applicable to water quality treatment of circulating water with a sum of hardness and alkalinity of less than 1100mg / L, a chloride ion concentration of less than 1000mg / L, pH of 6.8-9.5, and turbidity of less than 20NTYU. The dispersant provided in the invention has scale and corrosion inhibiting performances able to meet the requirements of industrial circulating water design specifications and a wide source water quality application range, and has the advantages of low phosphorus, environmental protection, strong chlorine resistance, applicability for auto-medicating control, as well as convenient use, etc.

Description

technical field [0001] The invention belongs to the technical field of environmental protection, and relates to a water treatment agent and a preparation method thereof, in particular to a high-efficiency low-phosphorus scale inhibitor dispersant for treating circulating cooling water and a preparation method thereof. Background technique [0002] The reuse rate of industrial water has reached 80%-90% in developed countries, and the concentration ratio of water has reached 6-8 times. However, the average water utilization rate in my country is less than 50%, and the concentration ratio of circulating cooling water is mostly at the level of 2-3 times. From the perspective of energy saving and water saving, it is undoubtedly a huge waste of resources. [0003] In order to save water resources, it is necessary to increase the reuse rate of water. In the process of water reuse, problems such as scaling, corrosion, bacteria and algae and slime reproduction will occur. A certain a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14
Inventor 童志武褚才全樊恩亚沙志强
Owner CHINA PETROLEUM & CHEM CORP
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