Catalytic cracking process for producing vinyl chloride by using active carbon as accelerant
A catalytic cracking and activated carbon technology, applied in the direction of dehydrohalogenation preparation, etc., can solve the problems of high energy consumption, short production cycle, easy coking of furnace tubes, etc., and achieve the effects of good selectivity, reduced operating costs, and stable life
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Embodiment 1
[0027] After pretreatment, the coal-based activated carbon is dried in a constant temperature box at 100°C for 20 hours, and activated in a nitrogen atmosphere at 200°C for 20 hours to prepare a catalyst. The high-efficiency activated carbon catalyst is loaded into a fixed-bed reactor, and dichloroethane is introduced into a constant-flow pump with a space velocity of 670h-1 and an average reaction temperature of 250°C. After the reaction product is cooled to -15°C, the unreacted dichloroethane liquid in the liquid phase is separated first, and then the hydrogen chloride and liquid vinyl chloride liquid are mainly obtained through separation.
[0028] The single-pass conversion rate of dichloroethane is 7%, and the selectivity of vinyl chloride is over 99%.
[0029] The pretreatment method of coal-based activated carbon is as follows: Column-shaped activated carbon particles with a size of 40 mesh to 200 mesh are immersed in a nitric acid solution with a weight concentration of 10%...
Embodiment 2
[0031] After pretreatment, the coal-based activated carbon is dried in a constant temperature box at 90°C for 24 hours and activated in a nitrogen atmosphere at 250°C for 20 hours to prepare a catalyst. The high-efficiency activated carbon catalyst is loaded into the fixed-bed reactor, and dichloroethane is introduced into the constant flow pump, and the space velocity is 670h -1 , The average reaction temperature is 300°C, the reaction product is cooled to -20°C, and the unreacted dichloroethane liquid in the liquid phase is separated first, and then the hydrogen chloride and liquid vinyl chloride liquid are mainly obtained through separation.
[0032] The conversion rate of dichloroethane per pass is 22%, and the selectivity of vinyl chloride is over 97%.
[0033] The pretreatment method of coal-based activated carbon is as follows: Column-shaped activated carbon particles with a size of 40 mesh to 200 mesh are immersed in a nitric acid solution with a weight concentration of 30% ...
Embodiment 3
[0035] The coal-based activated carbon is pretreated and dried in a constant temperature box at 100°C for 24 hours and activated in a nitrogen atmosphere at 250°C for 20 hours to prepare a catalyst. The high-efficiency activated carbon catalyst is loaded into the fixed-bed reactor, and dichloroethane is introduced into the constant flow pump, and the space velocity is 670h -1 , The average reaction temperature is 350°C, and the reaction product is cooled to -20°C to separate the unreacted dichloroethane liquid in the liquid phase, and then mainly obtain hydrogen chloride and liquid vinyl chloride liquid through separation.
[0036] The conversion rate of dichloroethane per pass is 40%, and the selectivity of vinyl chloride is over 95%.
[0037] The method of coal-based activated carbon pretreatment is the same as in Example 1.
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