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Seaweed oligosaccharide synergistic urea and preparation method thereof

A technology of seaweed oligosaccharides and urea, which is applied in the direction of urea compound fertilizer, nitrogen fertilizer, fertilizer mixture, etc., can solve the problems of polluting the living environment, increasing production costs, and having no fertilizer effect, so as to improve the soil environment, improve safety, and improve immunity effect of ability

Inactive Publication Date: 2012-11-28
青岛丰泰海洋生物科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are very prominent problems in my country's chemical fertilizers at present. The amount of chemical fertilizers used has doubled compared with 20 years ago, but the grain output has dropped from 28% to less than 5%. The utilization rate of chemical fertilizers has dropped sharply, and farmers have increased production without increasing income.
In the chemical fertilizer industry, nitrogen fertilizer plays a dominant role, but the average utilization rate of nitrogen fertilizer is only 30% to 35%. About 65-70% of nitrogen exists in the soil and is not used by plants. With the change of rain and snow weather, it is washed to In oceans, lakes and rivers, it not only increases the production cost and causes huge waste, but also pollutes the living environment. Compared with the nitrogen fertilizer utilization rate of about 50% in advanced countries in the world, there is a big difference
At present, the synergistic nitrogen fertilizer circulating in the domestic market is mainly polypeptide urea. Polypeptide urea is added polyaspartic acid in the process of urea synthesis. Polyaspartic acid is a single-component amino acid synthesized by American technology. synergist, no fertilizer effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Example 1 Preparation of algal oligosaccharide synergistic urea with alginic acid

[0015] Put alginic acid dry powder in a pressure vessel, add tap water to make the mass volume percentage of alginic acid reach 0.01-20.0%, stir, then add hydrogen peroxide with a mass volume percentage of 0.005-20.0%, stir, heat up to 121°C, and keep warm for 3 hours, then lower the temperature to 80°C, stir, adjust the pH to 6.5-9.0 with alkali, and concentrate to obtain a seaweed oligosaccharide solution. Then take a quantitative amount of seaweed oligosaccharide solution and add it to the urea aqueous solution in the conventional urea synthesis process, and then evaporate and granulate to obtain seaweed oligosaccharide synergistic urea.

[0016] The purpose of adding tap water is to allow the dry alginic acid powder to absorb water and expand, so that it can pass through the H of alginic acid (HALg) itself at high temperature. + Cut off the glycosidic bond, so that the seaweed polys...

Embodiment 2

[0018] Example 2 Preparation of seaweed oligosaccharide synergistic urea with potassium alginate

[0019] Put the dry powder of potassium alginate in a pressure vessel, add tap water to make the mass percentage of potassium alginate reach 0.01-20.0%, stir and dissolve, add hydrochloric acid or sulfuric acid with a mass percentage of 0.01-10.0%, and then add a mass percentage of 0.005- 20.0% hydrogen peroxide, stir, heat up to 121°C, keep warm for 3 hours, then cool down to 80°C, stir, adjust pH to 6.5-9.0 with alkali, and concentrate to obtain seaweed oligosaccharide solution. Then take a quantitative amount of seaweed oligosaccharide solution and add it to the urine in the conventional process of synthesizing urea, and then evaporate and granulate to obtain the seaweed oligosaccharide synergistic urea.

[0020] Weigh 10kg of potassium alginate dry powder, add 200kg of tap water, stir, add 2.0kg of sulfuric acid with a purity of 98%, then add 4.0kg of hydrogen peroxide with a ...

Embodiment 3

[0022] Example 3 Prepare seaweed oligosaccharide synergistic urea with kelp

[0023] Put the dried kelp into a pressure vessel, add tap water to make the seaweed polysaccharide in the kelp reach a mass percentage of 0.01-20.0%, stir, add hydrochloric acid or sulfuric acid with a mass percentage of 0.01-10.0%, and then add a mass percentage of 0.005- 20.0% hydrogen peroxide, stir, heat up to 121°C, keep warm for 3 hours, then cool down to 80°C, stir, filter, adjust the pH of the filtrate to 6.5-9.0 with alkali, and concentrate to obtain a seaweed oligosaccharide solution. Then take a quantitative amount of seaweed oligosaccharide solution and add it to the urine in the conventional process of synthesizing urea, and then evaporate and granulate to obtain the seaweed oligosaccharide synergistic urea.

[0024] Weigh 100kg of dried kelp and crush it, add 800kg of tap water, stir, add 9.0kg of sulfuric acid with a purity of 98%, then add 18.0kg of hydrogen peroxide with a purity of ...

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PUM

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Abstract

The invention relates to a seaweed oligosaccharide synergistic urea and a preparation method thereof. The preparation method comprises the following steps: mixing seaweed oligosaccharide and urea or raw materials or intermediate product in the urea synthesis step, and carrying out evaporation and granulation in the urea preparation technique to prepare the seaweed oligosaccharide synergistic urea. The special carboxy group with complexation, ion exchange and slow release properties in the oligosaccharide structure can be combined with the cationic group in the urea, so that active factors (ammonium ions and ammonia) in the urea nitrogen fertilizer can be slowly released in soil, thereby achieving the goal of providing nutrients for the plant for a long time. The seaweed oligosaccharide synergistic urea can enhance the utilization ratio of the nitrogen fertilizer to 45-55%, stimulate the plant to generate induced disease resistance, and enhance the autoimmunity of the plant. Besides, the seaweed oligosaccharide synergistic urea can prevent the plant from absorbing heavy metals around the root system, improve the soil environment and enhance the safety of the plant.

Description

technical field [0001] The invention belongs to the technical field of fertilizers, in particular to a seaweed oligosaccharide synergistic urea and a preparation method thereof technical background [0002] International research on seaweed oligosaccharides began in the middle and late 1950s, and my country began to do such research in the early 1980s. The early preparation of marine oligosaccharides was mainly for structural analysis, but now it is used for the study of structure-activity relationship and the development of applications of marine oligosaccharides in medicine, functional products, cosmetics, and agricultural technology. In agriculture, oligosaccharides are not only in demand in the development of pollution-free fertilizers, crop resistance and green pesticides, but also as plant growth regulators and seed treatment agents. Agriculture is the foundation of our country. Fertilizer plays a pivotal role in stabilizing the sustainable growth of our country's agr...

Claims

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Application Information

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IPC IPC(8): C05G3/00C05C9/00
Inventor 许加超盛泰刘存海刘作信刘晓林万梓龙杨海征郭亮李建林
Owner 青岛丰泰海洋生物科技有限公司
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