Polymer latex and application thereof

A technology of polymer emulsion and substance, applied in the direction of detergent composition, soap detergent composition, alkali soap/ammonium soap composition, etc.

Inactive Publication Date: 2013-01-09
JIANGSU FEIXIANG CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] While the above rheological thickeners can be used to stabilize composition

Method used

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  • Polymer latex and application thereof
  • Polymer latex and application thereof
  • Polymer latex and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0115] 1) Pre-emulsification: Put 16.8g of ammonium lauryl / tetradecyl alcohol polyoxyethylene ether sulfate (30-60wt%) and 208g of water in a four-necked flask, stir and pass through N for 15min 2 , then add 84.8g methacrylic acid, 130.8g ethyl acrylate, 0.23g pentaerythritol triallyl ether, 8g cetearyl alcohol polyoxyethylene ether methacrylate (60-80Wt.%), high-speed stirring Emulsification to prepare monomer pre-emulsion;

[0116] 2) Seed stage: Put 1g of ammonium lauryl / tetradecyl alcohol polyoxyethylene ether sulfate (30-60Wt.%) and 248g of water in a four-necked flask, stir and pass N 2 , heating up to 75°C, dissolving 0.32g of ammonium persulfate in 32g of water to make an aqueous initiator solution, adding 2Wt.% monomer pre-emulsion and 20wt% ammonium persulfate aqueous solution, and incubating at 75°C-85°C for 15min;

[0117] 3) Polymerization stage: after the light blue color appears in step 2), add the remaining monomer pre-emulsion and ammonium persulfate aqueous ...

Embodiment 2

[0120] 1) Pre-emulsification: Put 12.8g of ammonium lauryl / tetradecyl alcohol polyoxyethylene ether sulfate (30-60wt%) and 208g of water in a four-necked flask, and pass through it for 15min under stirring N 2 , after adding 80.8g methacrylic acid, 4g acrylic acid, 40g methyl acrylate, 90.8g ethyl acrylate, 0.65g triallylamine, 8g cetearyl alcohol polyoxyethylene ether methacrylate (60-80Wt .%), high-speed stirring for emulsification to prepare monomer pre-emulsion;

[0121] 2) Seed stage: Put 1g ammonium lauryl / tetradecyl alcohol polyoxyethylene ether sulfate (30-60Wt.%) and 248g water in a four-necked flask, pass N 2 And stir, after heating up to 80°C, dissolve 0.32g of ammonium persulfate in 32g of water to make an aqueous initiator solution, add 2Wt.% monomer pre-emulsion and 20Wt.% of ammonium persulfate aqueous solution, at 80°C-90°C Keep warm for 15 minutes;

[0122] 3) Polymerization stage: After the light blue color appears in step 2), add the remaining monomer pre-...

Embodiment 3

[0125] 1) Pre-emulsification: Put 16.8g of ammonium lauryl alcohol polyoxyethylene ether sulfate (30-60wt%) and 208g of water in a four-necked flask, and pass N for 15min under stirring. 2 , after adding 64.8g methacrylic acid, 20g fumaric acid, 50g methyl methacrylate, 80.8g ethyl acrylate, 1.74g tetraallyl ammonium chloride (45Wt.%), 8g cetearyl alcohol poly Oxyethylene ether methacrylate (60-80Wt.%), 8g methanol polyoxyethylene ether methacrylate (60-80Wt.%), high-speed stirring for emulsification to prepare monomer pre-emulsion;

[0126] 2) Seed stage: Put 1g ammonium lauryl / tetradecyl alcohol polyoxyethylene ether sulfate (30-60Wt.%) and 248g water in a four-necked flask, pass N 2 And stir, after heating up to 75°C, dissolve 0.32g ammonium persulfate in 32g water to make aqueous initiator solution, add 2Wt.% monomer pre-emulsion and 20wt% ammonium persulfate aqueous solution, keep warm at 75°C-85°C 15min;

[0127] 3) Polymerization stage: After the light blue color appe...

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PUM

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Abstract

The invention discloses a polymer latex which can be obtained by the reaction among alpha, beta-vinyl unsaturated carboxylic acid monomer (I) and or acid monomer with sulfonic acid, phosphoric acid or hypophosphorous acid, alpha, beta-vinyl unsaturated monomer (II), hydrophilic unsaturated crosslinking monomer or bifunctional and multifunctional vinyl unsaturated crosslinking monomer (III-VI), nonionic vinyl or acryl surface active agent (VII), anionic emulsifier, initiator, and chain transfer agent, wherein the polymer latex can be used for forming into a binary system in a surface active agent composition. Due to the unique crosslinking nodes in the polymer latex, the polymer latex can be used in various fields even under the low-pH and high-salt content severe environment such as the cosmetics, the medicines, the emulsion paint, and the effective and high-efficiency thickening agent and suspending agent in cleaning composition.

Description

technical field [0001] The invention relates to a polymer emulsion, in particular to an alkali-swellable polymer emulsion prepared by polymerization of one or more charged or hydrophilic monomers, which can be formed with a surface-active composition Binary system, the binary system can be used as a thickener and stabilizer for emulsions and dispersions in cosmetics, industry, and pharmaceutical compositions. Background technique [0002] Formulations based on water and solvents, such as solutions, emulsions, suspensions and suspoemulsions used in cosmetic, pharmaceutical, agricultural and industrial compositions, require thickening due to the need to improve their stability and economy. Likewise, for various aqueous detergent compositions containing silicone oil additives, abrasive or pearlescent materials, the shelf life can be significantly extended before the system components separate. At the same time, increasing the viscosity can also improve the uniform spreading of...

Claims

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Application Information

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IPC IPC(8): C08F290/06C08F220/18C08F220/06C08F216/12C08F220/14C08F226/02C08F222/02C08F2/30C08F2/26C11D9/02C11D9/32C11D10/04B01F17/52C09K23/52
CPCC08F290/06C08F2/06C08F220/1802C08F220/06C08F220/14C08F220/282C08F226/02C08F216/125C08F222/02C08F220/286C08F218/06C08F220/1804C08F220/34
Inventor 陶鑫刘昭清庄东青张萍
Owner JIANGSU FEIXIANG CHEM
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