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Water-purifying porous ceramic

A porous ceramic and water purification technology, applied in the field of water treatment, can solve the problems of extremely large primary battery treatment surface area, small functional area, and high cost, and achieve the effects of large market potential, large specific surface area, and low production cost

Inactive Publication Date: 2014-02-12
广东慧信环保有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing technology generally uses waste metal scraps, and also uses powder metallurgy to weld different metals to obtain primary battery devices. These methods either obtain very small functional areas or are expensive
To obtain a better treatment effect on organic matter in sewage, a large primary battery treatment surface area is required, so the primary battery process is still subject to cost

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0022] A kind of water-purifying porous ceramics, its preparation method comprises the following steps:

[0023] 1) Grind and mix copper oxide and iron oxide with a molar ratio of (6~14):(8~17), put them into water to make a suspension;

[0024] 2) Add sodium silicate, polyaluminum chloride and porogen respectively to the suspension, stir and mix well; then let stand to react and generate precipitate; wherein the molar ratio of sodium silicate and polyaluminum chloride is (5~ 13): (6~21), polyaluminum chloride is calculated according to the moles of alumina contained in it;

[0025] 3) After the reaction is over, discard the supernatant, make the precipitate into a sphere, and obtain a ball after drying;

[0026] 4) Send the pellets into the kiln, and fire them in a reducing atmosphere to obtain water-purifying porous ceramics.

[0027] Preferably, the molar ratio of copper oxide, iron oxide, sodium silicate and polyaluminum chloride used is (6-14):(8-17):(5-13):(6-21).

[...

Embodiment 1

[0038] 1) Grind copper oxide and iron oxide in equimolar ratio to 500 mesh and mix well, put into water and stir to disperse to make suspension;

[0039] 2) Put sodium silicate, polyaluminum chloride, and polyacrylamide into the suspension respectively, stir and mix well; then let it stand for 2 hours, and react to form a precipitate; among them, copper oxide, iron oxide, sodium silicate, polychloride The feed molar ratio of aluminum is 1:1:1:1, the molar value of polyaluminum chloride is calculated according to the moles of alumina contained in it, and the polyacrylamide is calculated according to copper oxide, iron oxide, sodium silicate and polychloride 0.1% throwing in of the total weight of aluminum;

[0040] 3) After the reaction is over, filter the supernatant, take out the precipitated sludge and make a sphere with a particle size of 5 cm, leave it to dry, and obtain a pellet;

[0041] 4) Send the pellets into the kiln, and sinter at 1200°C for 20 minutes in a reducin...

Embodiment 2

[0043] 1) Grind copper oxide and iron oxide with a molar ratio of 6:8 to 400 mesh and mix well, put into water and stir to disperse to form a suspension;

[0044] 2) Put sodium silicate, polyaluminum chloride, and ammonium bicarbonate into the suspension respectively, stir and mix well; The feed molar ratio of aluminum is 6:8:5:6, the molar value of polyaluminum chloride is calculated according to the moles of alumina contained in it, and the ammonium bicarbonate is calculated according to copper oxide, iron oxide, sodium silicate and polyaluminum chloride 0.5% throwing in of the total weight of aluminum;

[0045] 3) After the reaction is finished, filter the supernatant, take out the precipitated sludge and make a sphere with a particle size of 4 cm, leave it to dry, and obtain a pellet;

[0046] 4) Send the pellets into the kiln, and sinter at 1250°C for 20 minutes under a reducing atmosphere to obtain a nanoscale water-purifying porous ceramic.

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Abstract

The invention discloses a water-purifying porous ceramic. The novel water-purifying porous ceramic is prepared by a reduction sintering process, simple in process, low in production cost, and can be industrially produced on a large scale. The primary battery activity functional zone of the water-purifying porous ceramic has huge specific surface area, so that the water-purifying porous ceramic can effectively remove organic matters in sewage, is short in hydraulic retention time, good in water treatment effect and has larger market potential.

Description

technical field [0001] The invention belongs to the technical field of water treatment, in particular to a water-purifying porous ceramic. Background technique [0002] With the rapid development of industry, many such as printing and dyeing wastewater, medical wastewater, solid waste, landfill leachate, etc., have the characteristics of large discharge, wide pollution area, and difficult biodegradation. It is removed by coagulation and sedimentation. Therefore, methods such as electrolysis, Fenton oxidation, and biological fermentation are generally used to remove this type of sewage, but the high cost has become the bottleneck of the application of this type of method. [0003] The primary battery electrolysis process is effective in water treatment, especially in the treatment of biodegradable organic wastewater, and the cost of use is low. In recent years, the primary battery electrolysis process has become more and more popular in environmental pollution control as an e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/26C04B35/45C04B35/622C04B38/06C02F1/461B01D39/06
Inventor 谭铭卓龙德顺
Owner 广东慧信环保有限公司