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Zr/MaN composited coating on surface of high-speed steel cutting tool and preparation method thereof

A cutting tool and composite coating technology, which is applied in coatings, chemical instruments and methods, metal material coating technology, etc., can solve the problems of coarse structure, low bonding force, poor wear resistance, etc. Good peeling, consistency and uniformity of thickness

Inactive Publication Date: 2014-12-10
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in actual preparation, no matter whether it is the TiAlN film of the Ti transition layer plated first or the TiAlN film of the Ti / TiN transition layer plated first, there are still defects such as low bonding force, coarse structure, easy peeling, and poor wear resistance. (The resulting coating see figure 1 , 2 , 4, 5)
Moreover, under the ordinary magnetron sputtering method, with the increase of film hardness (such as the increase of Al content), these defects will become more prominent

Method used

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  • Zr/MaN composited coating on surface of high-speed steel cutting tool and preparation method thereof
  • Zr/MaN composited coating on surface of high-speed steel cutting tool and preparation method thereof
  • Zr/MaN composited coating on surface of high-speed steel cutting tool and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] The high-speed steel hob is sandblasted and ultrasonically cleaned by conventional methods, and then put into the coating machine, and then the coating chamber is vacuumed to 5.0×10 -3 Pa, argon gas is introduced to make the total pressure in the coating machine 4.5×10 -1 Pa, and control the heating power of 10KW to heat the tool to be plated for 150min; at a pressure of 2.0×10 -1 Under the protection of Pa argon gas, the DC bias voltage of the control tool is -200V, the pulse bias voltage is -800V, and the tool to be plated is cleaned with a plasma power of 6KW for 30min; at a pressure of 2.0×10 -1 Under the protection of Pa argon gas, control the DC bias voltage to -200V, and clean the tool to be plated with a plasma with a power of 6KW for 30min; at a pressure of 1.0×10 -1 Under the protection of argon gas in Pa, heat the Zr metal evaporation source with a plasma enhanced source with a power of 10KW, control the DC bias voltage -200V, and plate at a pulse bias volta...

Embodiment 2

[0040] Put the high-speed steel drill bit into the coating machine after sandblasting and ultrasonic cleaning by conventional methods, and then vacuumize the coating chamber to 5.0×10 -3 Pa, argon gas is introduced to make the total pressure in the coating machine 4.0×10 -1 Pa, and control the heating power 9KW to heat the tool to be plated for 90min; at a pressure of 1.7×10 -1 Under the protection of Pa argon gas, the DC bias voltage of the control tool is -200V, the pulse bias voltage is -600V, and the tool to be plated is cleaned with a plasma power of 5KW for 20min; at a pressure of 1.7×10 -1 Under the protection of Pa argon gas, control the DC bias voltage to -200V, and clean the tool to be plated with a plasma with a power of 5KW for 20min; at a pressure of 1.3×10 -1 Under the protection of argon gas in Pa, heat the Zr metal evaporation source with a plasma enhanced source with a power of 9KW, control the DC bias voltage -200V, and plate at a pulse bias voltage -400V fo...

Embodiment 3

[0043] The high-speed steel end mills are sandblasted and ultrasonically cleaned by conventional methods, and then placed in the coating machine, and then the coating chamber is vacuumed to 5.0×10 -3 Pa, argon gas is introduced to make the total pressure in the coating machine 4.0×10 -1 Pa, and control the heating power of 8.5KW to heat the tool to be plated for 70min; at a pressure of 1.5×10 -1 Under the protection of Pa argon gas, the DC bias voltage of the control tool is -100V, the pulse bias voltage is -500V, and the tool to be plated is cleaned with a power of 4KW for 15min; at a pressure of 1.5×10 -1 Under the protection of Pa argon gas, control the DC bias voltage to -100V, and clean the tool to be plated with a plasma with a power of 4KW for 15min; at a pressure of 1.0×10 -1 Under the protection of argon gas in Pa, heat the Zr metal evaporation source with a plasma enhanced source with a power of 7.5KW, control the DC bias voltage -100V, and plate at a pulse bias vol...

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Abstract

The invention discloses a Zr / MaN composited coating on the surface of a high-speed steel cutting tool. The Zr / MaN composited coating comprises two layers which are a Zr transition layer and a MaN layer sequentially outwards from the surface of the tool, wherein the thicknesses of the Zr transition layer and the MaN layer are respectively 100-200 nanometers and 2-5 micrometers, the organization structure of the composited coating is a nanocrystalline structure, the diffraction strength of TiN (111) surface is 385 under X-ray diffraction, and the diffraction strength of AlN (111) surface is 0 under X-ray diffraction. The hardness of the surface of the composited coating is 22-44 GPa, and the indentation level is 1-2. The invention further discloses a preparation method of the Zr / MaN composited coating. Zr is used to form the transition layer, and a plasma enhanced medium frequency magnetron reactive sputtering technique is adopted to plate the composited layer, so that the sputtering evaporation of a reactant is facilitated, the coating is compact in organization, high in purity, flat in surface, strong in combination force with the cutting tool, and good in wear resistance, the segregation of a thin film component is inhibited to the greatest extent, the ionization rate and the deflection are greatly improved, the service life of the coating is prolonged by 30-100% in the cutting machining of stainless steel, the technology is simple and easy to master and control, and convenience is brought to the industrialized production of the coating for the cutting tool.

Description

technical field [0001] The invention belongs to the technical field of hard coatings on tool and mold surfaces and their preparation, and in particular relates to a Zr / MaN composite coating on the surface of a high-speed steel cutting tool and a preparation method thereof. Background technique [0002] Surface coating technology is one of the new application technologies of modern cutting tools. The micro-nano-scale film obtained on the surface of the tool through chemical or physical methods has the characteristics of high hardness, good lubricity, and excellent oxidation resistance. It can make the cutting tool obtain excellent comprehensive mechanical properties, effectively prolong the service life of the tool, improve the cutting performance of the tool, and improve the machining efficiency. TiN is the earliest film used to protect cutting tools. It has high hardness, lubricity and versatility. It is an ideal film material for low-speed cutting tools. [0003] However,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B15/04B32B9/04C23C14/35C23C14/06C23C14/16
Inventor 赵海波鲜广梁红樱梁雅庭杜昊王辉
Owner SICHUAN UNIV