Protective treating agent for silanizing surface of anti-corrosion stainless steel plate surface and preparation method thereof

A stainless steel plate, silanization technology, applied in the direction of anti-corrosion coatings, coatings, etc., can solve the problems of harmful environment, complicated process, inconvenient operation, etc., and achieve the effect of enhanced corrosion resistance and low polarization current density

Active Publication Date: 2013-04-24
FUJIAN MEIKE STAINLESS STEEL PROD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The phosphating treatment process uses phosphoric acid, zinc, manganese, and nickel as the main raw materials, causing serious environmental pollution such as heavy metals, phosphorus, and nitrite, and will more or less produce sediment and harmful gases during the treatment process, which affects production. If it is carried out normally, the discharged wastewater COD and heavy metals will endanger the environment if it is not treated in an environmentally friendly way; in addition, most of the phosphating treatment needs to be carried out under heating conditions, which consumes a lot of energy, the process is complicated, and the operation is inconvenient
Silane surface treatment technology has appeared, but the film formation of silane surface treatment agent on the metal surface is unstable, the anti-corrosion performance is unstable, and the effect is not good

Method used

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Embodiment Construction

[0018] A kind of anti-corrosion stainless steel plate surface silanization protective treatment agent, is made of following components, and the weight (gram) of each raw material component in every 500 grams of mixed liquids is:

[0019] Ammonium chloride 2, diethylamine 2, tetraisopropyl titanate 3, rosin 3, trihydroxyethyl isocyanurate 2, maleic anhydride 12, diethylene glycol butyl ether 6, polyethylene glycol Alcohol 12, oxalic acid 5, urea 2, aminopropyltriethoxysilane 12, and the balance is deionized water.

[0020] The preparation method of described metal surface silanization protective treatment agent comprises the following steps:

[0021] (1) Heat and melt the rosin to 110-115°C, add diethylene glycol butyl ether and aminopropyl triethoxysilane, and stir for 35-50 minutes;

[0022] (2) Heat up to 145-160°C, add trihydroxyethylisocyanurate and maleic anhydride, and stir for 40-50 minutes;

[0023] (3) Continue to heat up to 190-205°C, add ammonium chloride, diethyl...

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PUM

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Abstract

The invention discloses a protective treating agent for silanizing the surface of an anti-corrosion stainless steel plate surface. The protective treating agent is prepared from the following components by weight (g) in each 500 grams of mixed solution 1 to 2g of ammonium chloride, 1 to 2g of diethylamine, 2 to 3g of tetraisopropyl titanate, 3 to 5g of rosin, 1 to 2g of 1,3,5-tris(2-hydroxyethyl) cyanuric acid, 10 to 12g of maleic anhydride, 4 to 6g of diethylene glycol monobutyl ether, 10 to 12g of polyethylene glycol, 3 to 5g of oxalic acid, 1 to 2g of urea, 10 to 12g of aminopropyl triethoxy silane, and the balance of deionized water. According to the protective treating agent, the rosin is used as a reaction raw material and is polymerized with raw materials such as the maleic anhydride and silane, and a stronger protective film can be formed on the metal surfaces; and the corrosion resistance of metal matrixes is enhanced.

Description

technical field [0001] The invention relates to a silanization treatment agent on the metal surface and a process for silanization treatment on the metal surface. Background technique [0002] Phosphating treatment has been widely used in metal coating pretreatment, lubrication, antirust and other industries. Especially in the coating pretreatment industry, phosphating treatment is one of the most commonly used pretreatment methods. Phosphating treatment is the process of forming a phosphate protective film on the surface of a metal after reacting in an acidic phosphate solution. Phosphate film also has good lubricity, insulation and corrosion resistance, so it is widely used in the manufacturing fields of automobiles, machinery manufacturing, aerospace and household appliances. The phosphating treatment process uses phosphoric acid, zinc, manganese, and nickel as the main raw materials, causing serious environmental pollution such as heavy metals, phosphorus, and nitrite,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D4/06C09D7/12C09D5/08
Inventor 夏坤财
Owner FUJIAN MEIKE STAINLESS STEEL PROD
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