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Metal protecting coating and hot-dipped metal material

A technology of metal protective coatings and raw materials, which is applied in the field of metal protective coatings and hot-dip metal materials. It can solve the problems of protective film corrosion resistance, water resistance, heat resistance and fingerprint resistance, etc., and achieve excellent lubricating performance and heat resistance. Excellent performance, excellent anti-fingerprint effect

Inactive Publication Date: 2013-05-29
PANGANG GROUP RESEARCH INSTITUTE CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the defects of poor corrosion resistance, water resistance, heat resistance and fingerprint resistance of the protective film formed by the existing metal protective coating, and to provide a protective film capable of forming corrosion resistance, water resistance and heat resistance. Protective coating for metal with a protective film with good anti-fingerprint and anti-fingerprint

Method used

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  • Metal protecting coating and hot-dipped metal material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] 1 part by weight of water-soluble silicate (Na 2 SiO 3 ), 0.6 parts by weight of accelerator (the aqueous emulsion of polyethylene wax and the aqueous emulsion of oxidized polyethylene wax are obtained by mixing 1: 1 by weight, and the aqueous emulsion of polyethylene wax is purchased from Dongguan City Hongguang Plastic Raw Material Management Department, The solid content is 48% by weight, and the melting point of polyethylene wax is 110-115° C.; the aqueous emulsion of oxidized polyethylene wax is purchased from Beijing Zhongguan Special Wax Co., Ltd., and the solid content is 48% by weight, and the melting point of oxidized polyethylene wax is 105 -110°C, acid value 14-21mgKOH / g), 1.6 parts by weight of silane coupling agent (the first silane derivative (2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, purchased from Hubei Debang Fine Chemical Co., Ltd.) mixed with the second silane derivative (γ-aminopropyltriethoxysilane, purchased from Hubei Debang Fine Chemical Co...

Embodiment 2

[0044] With 1 weight part of water-soluble silicate (K 2 SiO 3 ), 0.5 parts by weight of accelerator (the aqueous emulsion of oxidized polyethylene wax, purchased from Beijing Zhongguan Special Wax Co., Ltd., the solid content is 48% by weight, the melting point of oxidized polyethylene wax is 100-105 ℃, and the acid value is 17 -26mgKOH / g), 1.4 parts by weight of silane coupling agent (the first silane derivative (2-(3,4-epoxycyclohexyl) ethyltriethoxysilane, purchased from Hubei Debang Fine Chemical Co., Ltd. ) and the second silane derivative (γ-glycidyl ether oxypropyltrimethoxysilane, purchased from Hubei Debang Fine Chemical Co., Ltd.) in a weight ratio of 1:0.4 to obtain), 0.6 parts by weight of silica filler (nano Silica, purchased from U.S. GE Company, RNS-E, average particle size 20nm), 2.1 parts by weight (in terms of solids) of water-soluble film-forming resin (water-soluble acrylic film-forming resin (purchased from the brand name of Guangzhou Oupeng Chemical Ind...

Embodiment 3

[0046] 1 part by weight of water-soluble silicate (Na 2 SiO 3 ), 0.7 parts by weight of accelerator (aqueous emulsion of polyethylene wax, purchased from Dongguan Hongguang Plastic Raw Material Management Department, solid content is 48% by weight, and the melting point of polyethylene wax is 105-110 ℃), 1.8 parts by weight of Silane coupling agent (the first silane derivative (2-(3,4-epoxycyclohexyl) propyltrimethoxysilane, purchased from Hubei Debang Fine Chemical Co., Ltd.) and the second silane derivative (γ-shrink Glyceryl ether oxypropyltrimethoxysilane, purchased from Hubei Debang Fine Chemical Co., Ltd.) obtained by mixing at a weight ratio of 1:0.1), 0.85 parts by weight of silica filler (30% by weight of silica sol, the usage amount is calculated as solid ), 2.7 parts by weight (in solid terms) of water-soluble film-forming resin (water-soluble polyurethane film-forming resin (purchased from Fujian Jinjiang Jianhua Company, polyurethane resin of brand 812)) and the ...

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Abstract

The invention provides a metal protecting coating. The metal protecting coating is obtained after mixing a raw material mixture uniformly, wherein the raw material mixture contains water soluble silicate, an accelerant, a silane coupling agent, a silicon oxide filler, water soluble film-forming resin and water; the accelerant is water-based emulsion of polyethylene wax and / or water-based emulsion of oxidized polyethylene wax; the silane coupling agent contains first silane derivatives shown in a formula (1) in the specification; and in the formula (1), R1, R2 and R3 are respectively methoxy or ethoxy, and n is an integer from 1 to 4. The invention also provides a hot-dipped metal material. The hot-dipped metal material comprises a hot-dipped metal substrate and a coating attached to the hot-dipped metal substrate, wherein the coating is a cured product of the metal protecting coating. Protective films formed by the metal protecting coating provided by the invention have excellent corrosion resistance, water resistance, heat resistance, fingerprint resistance and lubricating property.

Description

technical field [0001] The invention relates to the field of metal protection, in particular to a metal protection coating and a hot-dip metal material. Background technique [0002] Hot-dip metal materials, including hot-dip galvanized metal materials and hot-dip galvanized metal materials, in order to prevent corrosion, a layer of metal protective paint will be coated on the surface of the hot-dip metal materials to form a protective film. Therefore, the performance of metal protective coatings is very important for the anti-corrosion of hot-dip metal materials. [0003] For example, CN101608306A discloses a passivation solution, which also belongs to a metal protective coating, and is characterized in that the passivation solution is an aqueous solution containing a water-soluble molybdenum compound, boric acid, water-soluble organic matter and silica sol, wherein the water-soluble The organic compound is a mixture of alcohol and organic carboxylic acid. [0004] Howeve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/04C09D5/08C09D7/12C23C2/06C23C2/12
Inventor 许哲峰梅东生陈永徐权娄燕周一林
Owner PANGANG GROUP RESEARCH INSTITUTE CO LTD
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