High-toughness Fe-Al-Cr coating and preparation method thereof

A fe-al-cr, high-toughness technology, applied in the coating, metal material coating process, ion implantation plating, etc., can solve the health and safety problems of operators, strong light radiation, poor material toughness and other problems, Achieve excellent high temperature oxidation resistance, good transition bonding, and good surface quality

Active Publication Date: 2013-06-12
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantages of using this technique to prepare the resulting coatings are: During the spraying process, the powder is in contact with oxygen, which makes the coating There are large particles such as Cr2O3 and Al2O3, resulting in poor toughness of the material; It also results in porosity in the coating that must be sealed and mechanically finished to obtain a smooth surface finish; Using this technique to prepare coatings During the layering process, a large amount of dust, odor, noise and strong light radiation will be generated, which will cause serious health and safety problems for operators

Method used

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  • High-toughness Fe-Al-Cr coating and preparation method thereof
  • High-toughness Fe-Al-Cr coating and preparation method thereof
  • High-toughness Fe-Al-Cr coating and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0052] The present invention is described in further detail below in conjunction with embodiment. However, for those skilled in the art, reasonable generalization and derivation can be made on the basis of the numerical values ​​listed in the specific embodiments.

[0053] (1) Treat the surface of 20 steel with metallographic sandpaper, ultrasonically clean it, and dry it;

[0054] (2) Put the above-mentioned 20 steel and iron-aluminum-chromium alloy wire into the double-glow plasma surface alloying device, use 20 steel as the workpiece electrode, and use the disc-shaped mesh-shaped iron-aluminum-chromium alloy wire as the source electrode. The ratio of the source components is: Al: 4%, Cr: 25%, the balance is Fe, the diameter of the wire is 1.5mm, and the aperture of the mesh is 14 mesh. Adjust the distance between the two poles to 15mm.

[0055] (3) Vacuumize to 0.5Pa, send in argon, start the glow, and adjust the process parameters. The follow-up experiment was divided i...

Embodiment 2

[0071] (1) Treat the surface of 45 steel with metallographic sandpaper, ultrasonically clean it, and dry it;

[0072] (2) Put the 45 steel and iron-aluminum-chromium alloy wire treated above into the double-glow plasma surface alloying device, use 45 steel as the workpiece electrode, and use the mesh structure made of iron-aluminum-chromium alloy wire as the source electrode. The distribution ratio of the source electrode is: Al: 6%, Cr: 15%, the balance is Fe, the wire diameter is 1.0mm, and the mesh aperture is 10 mesh. Adjust the distance between the two poles to 25mm.

[0073] (3) Vacuumize to 0.5Pa, send in argon gas, start glow, and adjust the process parameters to . The follow-up experiment was divided into three phases.

[0074] The time of stage one is 1.5h, and the debugging process parameters are:

[0075] Source voltage: 950V;

[0076] Workpiece voltage: 650V;

[0077] Argon pressure: 38 Pa;

[0078] The time of stage two is 2.0h, and the debugging process pa...

Embodiment 3

[0089] (1) Treat the surface of Q235 steel with metallographic sandpaper, ultrasonically clean it, and dry it;

[0090] (2) Put the above-treated Q235 steel and Fe-Al-Cr alloy wire into the double-glow plasma surface alloying device, use Q235 steel as the workpiece pole, and use the mesh structure made of Fe-Al-Cr alloy wire as the source. The distribution ratio of the source electrode is: Al: 5%, Cr: 20%, the balance is Fe, the diameter of the wire is 1.2mm, and the aperture of the mesh is 12 mesh. Adjust the distance between the two poles to 20mm.

[0091] (3) Vacuumize to 1.0Pa, send in argon gas, start glow, and adjust the process parameters to . The follow-up experiment was divided into three phases.

[0092] The time of stage 1 is 1.0h, and the debugging process parameters are:

[0093] Source voltage: 900V;

[0094] Workpiece voltage: 600V;

[0095] Argon pressure: 35 Pa;

[0096] The time of stage two is 1.5h, and the debugging process parameters are:

[0097] S...

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Abstract

The invention relates to a high-toughness Fe-Al-Cr coating and a preparation method thereof, belonging to the field of preparation of an Fe-Al intermetallic compound. The coating thickness is 20-30 mu m, and the coating and the matrix are bonded metallurgically. The Fe content is 60-65 wt% in the coating surface, and increases to 90-95 wt% in a gradient way in the surface depth direction; the Al content is 0-5 wt% in the coating surface, increases to 20-30 wt% in a gradient way in the surface depth direction, and decreases to 0-5 wt% in a gradient way as the depth increases; and the Cr content is 30-40 wt% in the coating surface, and decreases to 0-10 wt% in a gradient way in the surface depth direction. The coating is prepared by an ion sputtering deposition technique, and uses an iron-aluminum-chromium alloy wire as a target. The target is in a net disk structure of which the diameter is 10 cm, and is composed of 4-6 wt% of Al, 15-25 wt% of Cr and the balance of Fe; the diameter of the wire is 1.0-1.5 mm; and the pore size of the net material is 10-14 meshes. The coating provided by the invention has high toughness, and the toughness decreases in a continuous gradient in the surface depth direction without any abrupt point in the period.

Description

technical field [0001] The invention belongs to the field of preparation of Fe-Al intermetallic compounds, and in particular relates to a high-toughness Fe-Al-Cr coating and a preparation method thereof. Background technique [0002] Fe-Al intermetallic compounds have excellent properties of high temperature oxidation resistance, corrosion resistance and wear resistance. At the same time, it has the advantages of low cost and low density. However, due to its unique long-range ordered structure, dislocation movement and atomic diffusion are difficult, and it is affected by environmental hydrogen embrittlement, resulting in poor room temperature plasticity and brittle fracture during use, which limits its application in the engineering field. Applications. Studies have shown that Cr is the most effective element to improve the toughness of Fe-Al intermetallic compounds. The reason is: Cr can not only improve the strength and hardness of the material, but also improve the pl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/16C23C14/38
Inventor 姚正军罗西希魏东博张平则周金堂陈煜朱俊谋周文斌杨红勤吴小凤
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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