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Preparation method for special sizing agent for polycarboxylic acid hardboard

A technology of polycarboxylic acid and sizing agent, which is applied to the chemical industry, can solve the problems of poor chelating ability, poor fluidity and weak hydrophobicity of the surface sizing agent, and achieves improvement of surface flatness and smoothness, and good solubility. performance, to solve the effect of weak hydrophobicity

Inactive Publication Date: 2013-08-07
安徽百翼生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to improve the physical strength of cardboard, people choose thermosetting resin as the adhesive. For example, the Chinese patent "A Surface Sizing Agent for Improving the Crucibility of Paper and the Ring Crush Strength of Cardboard" (publication number CN 101050611A) discloses a water-soluble A mixture of thermosetting resin adhesives and curing agents. The surface sizing agent can improve the ink absorption of paper and improve the grade of paper products. However, the surface sizing agent has poor chelating ability and weak hydrophobicity when used. , poor liquidity and other defects

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A preparation method of a special sizing agent for polycarboxylate cardboard, the special sizing agent comprises a polycarboxylic acid-lignin water reducer and a modified rosin resin, and the polycarboxylate-lignin water reducer in the special sizing agent The weight percentage of agent is 25%, and the weight percentage of modified rosin resin is 75%, and preparation steps are as follows:

[0019] (1) Synthetic lignin water reducer: Pre-homogenize and sulfonate the black liquor of wood pulp and / or bagasse pulp (the sulfonation reagent is Na 2 SO 3 ), after the condensation reaction, the lignosulfonate superplasticizer was obtained by filtration.

[0020] (2) Copolymerization and grafting of lignin water reducer and JSJ polycarboxylate water reducer: use macromonomer synthesis method, add special dispersant for polymer carboxylation, use peroxide redox initiation system as initiator, Graft the C=C bond of the polycarboxylate superplasticizer to the sulfonate of lignin ...

Embodiment 2

[0025] A preparation method of a special sizing agent for polycarboxylate cardboard, the special sizing agent comprises a polycarboxylic acid-lignin water reducer and a modified rosin resin, and the polycarboxylate-lignin water reducer in the special sizing agent The percentage by weight of the agent is 30%, the percentage by weight of the modified rosin resin is 70%, and the paper pulp black liquor is one or more of the papermaking black liquor of straw pulp, bamboo pulp, reed pulp and cotton pulp, and the preparation steps are the same In Example 1. When the weight percentage of polycarboxylic acid-lignin superplasticizer is 70%, the fluidity and dispersion stability of the carton sizing agent not only increase the carboxyl bond in the sizing agent material, but also change the carboxyl bond in the sizing agent The distribution of various active groups improves the chelating ability and dispersion stability, and the structure is in a stable state. The sizing agent material h...

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PUM

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Abstract

The invention discloses a preparation method for a special sizing agent for a polycarboxylic acid hardboard. The special sizing agent comprises 25 to 30 wt% of a polycarboxylic acid-lignin water reducer and 70 to 75 wt% of a modified rosin resin. The preparation method comprises synthesis of a lignin water reducer, graft copolymerization of the lignin water reducer and a polycarboxylic water reducer, modification of a rosin resin and the like. According to the invention, lignosulfonate and the polycarboxylic water reducer undergo graft copolymerization to synthesize the special sizing agent for the polycarboxylic acid hardboard, so cost is saved, industrial waste is utilized, application performance and an application scope of the polycarboxylic water reducer are substantially improved, the problems of poor hydrophobicity, poor fluidity, high cost and the like of a sizing agent product for a common carton are effectively overcome, and fluidity, chelating capability and dispersion stability of a sizing agent for a carton are improved.

Description

technical field [0001] The invention belongs to the technical field of chemical industry and relates to a preparation method of a surface sizing agent, in particular to a preparation method of a special sizing agent for polycarboxylate cardboard. Background technique [0002] At present, the global paper product packaging industry is developing rapidly, and the market demand for various cardboard boxes is also increasing, and they are widely used in the outer packaging and transportation packaging of various products due to their high quality and environmental protection characteristics. In the case of increasingly fierce competition among carton companies and lower and lower profits, new technologies and methods that can improve production efficiency, product quality, save labor costs, and facilitate enterprise management are increasingly favored by carton companies. And attention, and constantly applied to the actual production. Cartons made of high-strength, moisture-res...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H21/16C08G81/02C08H7/00C09F1/04
Inventor 邵百成汪菊英吴诚
Owner 安徽百翼生物科技有限公司
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