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Kapok fiber composite super absorbent resin as well as preparation method thereof

A technology of super absorbent resin and kapok fiber, which is applied in the field of super absorbent resin to achieve the effects of fast water absorption rate, high reaction efficiency and simple synthesis process

Active Publication Date: 2014-01-22
LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But do not adopt the report of kapok fiber to prepare superabsorbent resin so far

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Crush the kapok fiber to about 1cm first, add it to an aqueous solution containing 1% sodium chlorite, and heat it up to 70°C for 1 hour. After the reaction, the fibers were washed with distilled water until neutral, and the fibers were dried at 70°C to constant weight for later use. Add 10 parts of activated kapok fiber into the reactor, add a certain amount of distilled water to stir and wet it, and pass N 2 , add 0.1 part of ammonium persulfate solution, heat up to 60 o C for 15 min, then add 100 parts of acrylic acid (neutralized to 70% with NaOH in advance), 15 parts of acrylamide and 0.2 parts N,N '-methylenebisacrylamide, heated to 70 o C reacted for 3 h. After the reaction, the product was at 70 o C, dried to constant weight, crushed, and passed through a 40-80 mesh sieve. The distilled water absorption rate of the product in this embodiment is 580g / g, and the absorption rate of physiological saline is 70g / g.

Embodiment 2

[0026] Crush the kapok fiber to about 1cm first, add it to an aqueous solution containing 1% sodium chlorite, and heat it up to 70°C for 1 hour. After the reaction, the fibers were washed with distilled water until neutral, and the fibers were dried at 70°C to constant weight for later use. Add 10 parts of activated kapok fiber into the reactor, add a certain amount of distilled water to stir and wet it, and pass N 2 , add 0.1 part of potassium persulfate, heat up to 60 o C was initiated for 15 min, and then 100 parts of acrylic acid (neutralized to 80% with NaOH in advance), 20 parts of acrylamide and 0.1 parts of N,N '-methylenebisacrylamide, heated to 80 o C reacted for 2h. After the reaction, the product was at 70 o C, dried to constant weight, crushed, and passed through a 40-80 mesh sieve. The distilled water absorption rate of the product in this embodiment is 675g / g, and the absorption rate of physiological saline is 78g / g.

Embodiment 3

[0028] Crush the kapok fiber to about 1cm first, add it to an aqueous solution containing 1% sodium chlorite, and heat it up to 70°C for 1 hour. After the reaction, the fibers were washed with distilled water until neutral, and the fibers were dried at 70°C to constant weight for later use. Put 20 parts of activated kapok fiber into the reactor, add a certain amount of distilled water to stir and wet it, and pass N 2 , add 0.2 parts of V50, heat up to 60 o C for 15 min, then add 100 parts of acrylic acid (neutralized to 90% with NaOH in advance), 20 parts of acrylamide and 0.1 parts N,N '-methylenebisacrylamide, heated to 80 o C reacted for 3 h. After the reaction, the product was at 70 o C, dried to constant weight, crushed, and passed through a 40-80 mesh sieve. The distilled water absorption rate of the product in this embodiment is 850g / g, and the absorption rate of physiological saline is 88g / g.

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Abstract

The invention discloses kapok fiber composite super absorbent resin as well as a preparation method thereof. The preparation method comprises the following steps: by taking acrylic acid, acrylamide and kapok fiber as main raw materials, adding an initiator and a crosslinking agent; carrying out graft polymerization, crosslinking, drying and crushing in an aqueous liquid to prepare the kapok fiber composite super absorbent resin. Per gram of the super absorbent resin absorbs 500-860g of distilled water and 65-90g of normal saline; the super absorbent resin has high water absorption rate and excellent recycling performance, and can be widely applied to the fields such as agriculture and forestry, gardening, desert modification, industry and construction industry.

Description

technical field [0001] The invention relates to a preparation method of a superabsorbent resin, in particular to a superabsorbent resin prepared by grafting, copolymerizing and crosslinking kapok fibers, acrylic acid and acrylamide in an aqueous solution. Background technique [0002] Superabsorbent resin is a functional polymer material with a unique three-dimensional network structure formed by moderate chemical and physical crosslinking of hydrophilic monomers, which can swell but not dissolve in water. Due to its excellent hydrophilicity, water retention and biocompatibility, it has been widely used in medical and health, agriculture, forestry and gardening, food processing, environmental protection, beauty and makeup, civil engineering, oil exploration and other fields. [0003] According to the different sources of raw materials for preparing superabsorbent resins, superabsorbent resins can be roughly divided into starch-based, cellulose-based and synthetic resin-based...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/02C08F220/06C08F220/56C08B15/02
Inventor 王爱勤施小宁郑易安
Owner LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI