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Rare earth polishing powder and preparation method thereof

A technology of rare earth polishing powder and rare earth carbonate, applied in the direction of chemical instruments and methods, other chemical processes, etc., can solve the problems of high polishing rate, environmental pollution, increased cost, etc., and achieve low cost, no environmental pollution, and the amount of erosion and high wear resistance

Active Publication Date: 2015-07-08
上海华明高纳稀土新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hard lumps of MIF particles cause scratches
In addition, if unreacted rare earth oxide particles remain, high polishing rates cannot be maintained over a long period of time
[0009] At the same time, in the current preparation process of rare earth polishing powder, due to the introduction of fluorine, whether it is the overflow of hydrogen fluoride in the preparation process or the sublimation of rare earth fluoride in the roasting process, it will cause great pollution to the environment. Processing adds a lot of cost

Method used

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  • Rare earth polishing powder and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0034] Under stirring conditions, 80g of lanthanum cerium carbonate (TREO is 45%, CeO 2 / TREO is 60%), 20g kaolin (weight loss on ignition is 15%) are added to 150g water, after ball milling until the D50 is 2.02μm, transfer to the reaction tank, add to 60°C, keep warm for 5h, and keep warm at 120°C for 20h . Then it was calcined at 960°C for 5.5h, and then pulverized by airflow until D50 was 1.51μm to obtain rare earth polishing powder. The mass content of rare earth oxide in the rare earth polishing powder is 68%, and the mass content of aluminum silicate is 32%. figure 1 The particle size distribution diagram of the polishing powder prepared in Example 1.

Embodiment 2

[0036] Under stirring conditions, 90g of lanthanum cerium carbonate (TREO is 45%, CeO 2 / TREO is 63%, Pr 6 o 11 / TREO is 3%), 10g bentonite (weight loss on ignition is 15%) is added to 67g water, after ball milling until D50 is 2.97μm, transfer to the reaction tank, add to 80°C, keep warm for 2h, and keep warm at 180°C for 10h . Then it was calcined at 1030°C for 3.5h, and then crushed by airflow until D50 was 2.98μm to obtain rare earth polishing powder. The mass content of rare earth oxides in the rare earth polishing powder is 82.6%, and the mass content of aluminum silicate is 17.4%.

Embodiment 3

[0038] Under stirring conditions, 85g of lanthanum cerium carbonate (TREO is 45%, CeO 2 / TREO is 70%, Pr 6 o 11 / TREO is 5%), 10g kaolin (weight loss on ignition is 15%), 5g magnesium aluminum silicate (weight loss on ignition is 17%) are added to 170g water, after ball milling until D50 is 2.53μm, transfer to the reaction tank , added to 70°C, kept for 4h, and kept at 160°C for 15h. Then it was calcined at 1000°C for 4.5h, and then pulverized by airflow until D50 was 2.32μm to obtain rare earth polishing powder. The mass content of rare earth oxide in the rare earth polishing powder is 75%, and the mass content of aluminum silicate is 25%.

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Abstract

The invention provides rare earth polishing powder and a preparation method thereof; the rare earth polishing powder is composed of rare earth oxide and aluminium silicate, wherein the rare earth oxide is lanthanum-cerium oxide or lanthanum-cerium-praseodymium oxide; the mass content of the rare earth oxide in the rare earth polishing powder is 66-85%; the rest is aluminium silicate. The rare earth polishing powder disclosed by the invention is prepared by proportioning, ball-milling, drying, roasting and crushing rare earth carbonate and aluminosilicate. Compared with the prior art, fluorine is not introduced into the rare earth polishing powder prepared by the invention; the operation condition in the reaction process is moderate; the rare earth polishing powder has the advantages of being high in polishing and corroding amount and abrasive resistance and the like; and the rare earth polishing powder prepared by the invention has the advantages of being simple in preparation process, free from environmental pollution, low in cost and the like in the production process.

Description

technical field [0001] The present invention relates to a kind of rare earth polishing powder and its preparation method, more precisely, it relates to a kind of cerium-based rare earth compound as raw material, which is prepared by chemical method and applied to the surface of glass substrates and optical glass components of displays and display screens. A fluorine-free cerium-based mixed rare earth polishing powder for polishing treatment and a preparation method thereof. Background technique [0002] Rare earth polishing powder is an important extended product of rare earth products, which has the advantages of fast polishing speed, high finish and long service life. High-precision rare earth polishing materials play a vital role in the liquid crystal display industry due to their advantages of uniform particle size, moderate hardness, high polishing efficiency, good polishing quality, long service life, and environmental protection. One of the key chemicals for developm...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K3/14
Inventor 赵月昌高玮陈曦倪萍赵秀娟王昕
Owner 上海华明高纳稀土新材料有限公司
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