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A kind of preparation method of dispersed oxide nickel aluminum alloy

A nickel-aluminum alloy, oxide technology, applied in solid diffusion coating, metal material coating process, coating and other directions, can solve problems such as poor effect, and achieve the effect of simple process, good coating quality and low cost

Inactive Publication Date: 2016-02-24
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this method works well for flat surfaces and is less effective for irregularly shaped components

Method used

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  • A kind of preparation method of dispersed oxide nickel aluminum alloy
  • A kind of preparation method of dispersed oxide nickel aluminum alloy
  • A kind of preparation method of dispersed oxide nickel aluminum alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach 1

[0026] Embodiment 1: The preparation method of the dispersed oxide nickel-aluminum alloy of this embodiment is:

[0027] (1) Mix pure aluminum powder (particle size 60 microns, purity 99.8wt%) and yttrium oxide (powder particle size 50 nanometers) at a ratio of 99wt%: 1wt%, then ball mill the mixture (360 rpm, The processing time is 2 hours, and the mixture ball ink adopts the dry method. The mixture is put into a ball mill tank with a diameter of 50mm and a height of 80mm, and filled with ceramic balls with a diameter of 2mm, and the ball mill tank is installed on a planetary ball mill. Carry out ball milling, and after the ball milling, the ultrafine metal oxides are dispersed in the aluminum powder particles; figure 1 shown.

[0028] (2) Ball mill the mixture in step (1) as aluminum donor, NH 4 Cl is used as a penetration aid, and varnish is used as a binder. According to the ratio of aluminum donor: penetration aid: binder is 49wt%: 1wt%: 50wt%, mixed with polyvinyl alco...

Embodiment approach 2

[0031] Embodiment 2: The preparation method of the dispersed oxide nickel-aluminum alloy of this embodiment is:

[0032] (1) Pure aluminum powder (with a particle size of 40 microns and a purity of more than 99.5wt%) and yttrium oxide (Y 2 o 3), the powder particle size is 45 nanometers) mixed according to the ratio of 99.5wt%: 0.5wt%, and then the mixture is ball milled (rotating speed 300 rpm, processing time is 1 hour. The ball ink of the mixture is ball milled by wet method, and the wet method is to use pure Alcohol is completely submerged in the powder for ball milling, and then dried), and the ultrafine metal oxides are dispersed in the aluminum powder particles;

[0033] (2) Ball mill the mixture in step (1) as aluminum donor, NH 4 Cl is used as a penetration aid, and varnish is used as a binder. According to the ratio of aluminum donor: penetration aid: binder is 45wt%: 5wt%: 50wt%, mixed with polyvinyl alcohol solution with a concentration of 15wt% after fully grind...

Embodiment approach 3

[0035] Embodiment 3: The preparation method of the dispersed oxide nickel-aluminum alloy of this embodiment is:

[0036] (1) Pure aluminum powder (with a particle size of 10 microns and a purity of more than 99.5wt%) and hafnium oxide (HfO 2 ) (powder particle size is 100 nanometers) mixed according to the ratio of 95wt%: 5wt%, and then the mixture is ball milled (rotating speed 600 rpm, processing time is 6 hours. The ball ink of the mixture is ball milled by wet method, and the wet method is to use pure ethanol to completely submerge the powder for ball milling, and then dry), and the ultrafine metal oxides are dispersed in the aluminum powder particles;

[0037] (2) Ball mill the mixture in step (1) as aluminum donor, NH 4 Cl is used as a penetration aid, and varnish is used as a binder. According to the ratio of aluminum donor: penetration aid: binder is 30wt%: 4wt%: 66wt%, mixed with polyvinyl alcohol solution with a concentration of 14wt% after fully grinding Mix accor...

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Abstract

The invention relates to a dispersed nickel-aluminum alloy preparation method, and belongs to the technical field of the preparation and performances of a high temperature resistant oxidation coat. The method comprises the following steps: mixing pure aluminum powder with ultrafine rare earth oxide powder, carrying out ball milling treatment, dispersing a rare earth oxide in aluminum powder particles, adding a polyvinyl alcohol solution to prepare an aluminized slurry with the processed aluminum powder as an aluminum supply agent, NH4Cl as a permeation promoter and a varnish as a binder; and coating the surface of a matrix which is a nickel based alloy with the aluminized slurry through dip coating or brush coating, drying, heating to a high temperature to obtain a dispersed nickel-aluminum alloy coat by utilizing the outward diffusion characteristic of the matrix nickel.

Description

technical field [0001] The invention relates to a method for preparing a dispersed oxide nickel-aluminum alloy, and belongs to the technical field of high-temperature oxidation-resistant coating preparation and performance. Background technique [0002] Nickel-based superalloys are one of the main materials for aviation and aerospace engines. With the rapid development of the modern aviation industry, higher requirements are put forward for the alloy's ability to resist oxygen and high temperature oxidation. Add a small amount of rare earth and rare earth oxides to the alloy to form a dispersed strengthening phase and form a dispersed oxide strengthened alloy, which can significantly improve the anti-stripping ability of the oxide film, reduce the constant temperature and cycle oxidation rate, and improve the high temperature oxidation resistance of the alloy. performance. [0003] Dispersed oxide coating first appeared in 1986, Luthra adopted the plasma spraying method, a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C10/48
Inventor 詹肇麟刘忠王虎吴云霞刘建雄
Owner KUNMING UNIV OF SCI & TECH