High sealing flexible composite film material for cold punching molding and its manufacturing method

A composite film, high-sealing technology, applied in chemical instruments and methods, lamination devices, lamination auxiliary operations, etc., can solve the problems of failure of package contents, influence of barrier properties of packaging materials, improper molding, etc., and achieve easy stretching. Molding and mold release, stable interlayer peel strength, and the effect of reducing friction coefficient values

Inactive Publication Date: 2014-02-19
FSPG HI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, for some electronic components or pharmaceuticals, photographic medicines, etc. that have high requirements for cleanliness, barrier properties, and sealing properties, packaging materials that contain migratory lubricants such as fatty acid amide series may not be suitable, even for a small amount. The precipitation of the lubricant will also pollute the contents of the package. The precipitation of the lubricant will also affect the bonding performance of the composite surface of the material, increase the possibility of material separation, affect the barrier properties of the packaging material, and even cause Poor sealing performance caused by too smooth packaging surface, followed by the infiltration of water vapor and oxygen, resulting in the failure of the packaged content
[0009] At the same time, although the aluminum foil is oxidized with chromate, the treatment process is simple, the cost is low, the chemical conversion treatment layer has a certain corrosion resistance and has a good bonding force with the resin film, but the hexavalent chromium often contained in chromate is carcinogenic and harmful. Toxicity, the aerosol generated during the oxidation process and the waste water in the production have serious harm to organisms and the environment, and its application has been gradually restricted. The European Union has implemented the poisonous and harmful The Restriction of Substances Directive (RoSH) clearly limits the content of hexavalent chromium in products
[0010] The flexible packaging materials for electronic components in the prior art, especially the packaging materials for lithium-ion secondary batteries or capacitors, still have long-term interlayer separation in the molding production and assembly process, electrolyte leakage caused by poor sealing, and improper molding. The technical problems of shell damage and low processing yield

Method used

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  • High sealing flexible composite film material for cold punching molding and its manufacturing method
  • High sealing flexible composite film material for cold punching molding and its manufacturing method
  • High sealing flexible composite film material for cold punching molding and its manufacturing method

Examples

Experimental program
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Effect test

Embodiment 1

[0043] Such as figure 1 As shown, the flexible composite film material of this embodiment is sequentially from top to bottom: thermoplastic resin film inner layer 1, aluminum foil metal core layer 2 and heat-resistant film outer layer 3; wherein, thermoplastic resin film inner layer 1 is two A layer co-extrusion film, which includes a surface heat-sealing layer 101 and an inner composite layer 102. Aluminum foil made of aluminum-iron alloy (AA specification 8079) with a thickness of 45 μm is selected as the aluminum foil metal core layer 2, metallocene polyethylene (PE) with a thickness of 35 μm is used as the surface heat-sealing layer 101, and acid-modified aluminum foil with a thickness of 15 μm is selected. Polyethylene (MPE) is used as the inner layer composite layer 102, and polyamide (PA) with a thickness of 15 μm and polyester (PET) with a thickness of 12 μm are selected as the outer layer 3 of the heat-resistant film, which is made of PET(12) / ON( 15) / AL(45) / PE(15) / MP...

Embodiment 2

[0050] This embodiment and embodiment 1 have the same material composition, and its preparation process is as follows (such as figure 2 shown):

[0051] A, adopt chrome-free surface treatment agent to carry out double-sided chemical oxidation treatment to the surface of aluminum foil metal core layer 2, obtain double-sided pretreated aluminum foil metal core layer 2';

[0052] B. The inner layer 1 of the thermoplastic resin film is prepared through the casting and co-extrusion process, wherein 5% diatomaceous earth is added to the surface heat-sealing layer (101); The composite layer 102 is directly in contact with one side of the double-sided pretreated aluminum foil metal core layer 2'.

[0053] C. The heat-resistant film outer layer 3 is contacted with the other side of the uncoated aluminum foil metal core layer 2' in step B by dry compounding to prepare the multilayer aluminum-plastic composite film material.

[0054] Carry out the same experimental test as embodiment ...

Embodiment 3

[0056] This embodiment and embodiment 1 have the same material composition, and its preparation process is as follows (such as figure 2 shown):

[0057] A, adopt silane coupling agent to carry out double-sided primer treatment to the surface of aluminum foil metal core layer 2, obtain double-sided pretreated aluminum foil metal core layer 2';

[0058] B. The inner layer 1 of the thermoplastic resin film is prepared by casting and co-extrusion process, wherein the surface heat-sealing layer 101 is added with 5% precipitation-type smooth agent erucamide, and the inner composite layer 102 is added with 5% modified phenolic aldehyde Resin; while casting and co-extruding, the inner layer composite layer 102 is directly contacted and composited with one side of the double-sided pretreated aluminum foil metal core layer 2' by adopting a hot-compression composite process.

[0059] C. The heat-resistant film outer layer 3 is contacted and compounded with the other side of the uncoate...

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Abstract

The invention provides a high sealing flexible composite film material for cold punching molding. The composite film material comprises: a thermoplastic resin film inner layer, an aluminum foil metal core layer, and a heat resistant film outer layer. Specifically, the aluminum foil metal core layer is positioned between the thermoplastic resin film inner layer and the heat resistant film outer layer. The thermoplastic resin film inner layer is a multi-layer coextrusion layer containing at least two resin layers. The multi-layer coextrusion layer at least includes a surface heat seal layer and an inner composite layer, and the inner composite layer contacts the aluminum foil metal core layer. The surface heat seal layer contains a non-migrating inorganic additive with lubrication. The upper and lower surfaces of the aluminum foil metal core layer both undergo surface pretreatment. By adding the non-migrating inorganic additive with lubrication to the surface heat seal layer, the bonding problem caused by clinging of a composite material surface and a die can be prevented, and at the same time, air can permeate into the space between the composite material and the die along the gaps between tiny protuberances, so that the whole composite material is easy to undergo cold punching molding and die release. The invention also provides a preparation method of the flexible composite film material.

Description

technical field [0001] The invention relates to a high-seal flexible composite film material for cold stamping and its corresponding manufacturing method, in particular to a film suitable for electronics with high formability, sealing performance, barrier performance and chemical corrosion resistance in post-processing applications. A flexible composite film material for packaging parts or medical supplies, photographic medicines, and other items containing strong corrosive organic solvents. Background technique [0002] Since the industrialization of lithium-ion batteries in the early 1990s, they have been widely used in civilian fields, such as small-capacity lithium-ion secondary batteries used in mobile phones, handheld computers, notebook computers, video cameras, and digital cameras. With the development of lithium-ion battery technology, its application fields have gradually expanded to large-capacity lithium-ion batteries in the fields of electric vehicles, aerospace...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B15/082B32B15/20B32B7/12B32B38/18B32B37/12B32B37/15
Inventor 徐冰吴耀根李永鸿
Owner FSPG HI TECH
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