A kind of preparation method of antibacterial composite film material
A composite film and composite film technology, applied in the field of plastic film manufacturing, can solve the problems of softness, extensibility and transparency of low-density composite film, corona discharge between winding turns, uneven distribution of pulse voltage, etc., to achieve production Good process stability, time saving, and remarkable effect of corona resistance
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Embodiment 1
[0016] (1) Mixing of raw materials: Heat 3g of 4,4’-diaminodiphenyl ether and 54mL of N,N-dimethylacetamide in a three-necked flask at room temperature, stir until completely dissolved by ultrasonic, then add 5.72g of Sol, continue ultrasonic stirring for 28min;
[0017] (2) Polyamic acid / Preparation of the precursor: under the condition of an ice-water bath, 3.27g of pyromellitic dianhydride was added to the three-necked flask in 6 times on average to obtain polyamic acid / Precursor, continue to stir for 6h, mix well With polyamic acid; Add 3g antibacterial complex again; The preparation method of described antibacterial complex is:
[0018] Mix hops, airplane grass, pentagon, thyme, galangal, garlic, mugwort leaves, and water at 15-20: 10-15: 10-15: 12-15: 8-10: 8-10: 5-7: 15 The mass parts of -20 are mixed in proportion, and cellulase is added (8 parts of activity unit is 100U) for enzymolysis, the enzymolysis reaction temperature is 25°C, the enzymolysis reaction t...
Embodiment 2
[0022] Example 2: The rest are the same as in Example 1, except that in the step (1), the stirring time is controlled to be 32 min; in the step (3), the holding time is controlled to be 0.6 h, and the oven temperature is 85°C. In 4), the soaking time is controlled to be 3.0 h; in the step (5), the oven temperature is controlled to be 328° C., and the drying time is controlled to be 10 min.
Embodiment 3
[0023] Example 3: The rest are the same as in Example 1, except that in the step (1), the stirring time is controlled to be 38 min; in the step (3), the holding time is controlled to be 0.6 h, and the oven temperature is 90°C. In 4), the soaking time is controlled to be 3.2 hours; in the step (5), the oven temperature is controlled to be 335° C., and the drying time is controlled to be 11 minutes.
[0024] After the above process steps, the composite film sample is taken out to be tested:
[0025] serial number thermal stability Permittivity change rate / % Corona Resistance Tensile strength / MPa Elongation at break / % Example 1 excellent 2.4 excellent 96.06 13.48 Example 2 excellent 2.3 excellent 95.20 12.98 Example 3 excellent 2.5 excellent 96.13 13.05
[0026] From the above data, it can be seen that the prepared composite film has excellent thermal stability and corona resistance, a small change rate of dielectric c...
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