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Abrasive and polishing composition

A technology of grinding materials and compositions, which is applied in the direction of abrasive materials, grinding devices, grinding machine tools, etc., and can solve problems such as insufficient satisfaction

Inactive Publication Date: 2014-02-19
FUJIMI INCORPORATED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, when the polishing composition described in Patent Document 2 is used for polishing hard and brittle materials such as glass substrates, it cannot fully satisfy all the above requirements.

Method used

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  • Abrasive and polishing composition
  • Abrasive and polishing composition
  • Abrasive and polishing composition

Examples

Experimental program
Comparison scheme
Effect test

no. 1 Embodiment approach

[0022] A first embodiment of the present invention will be described below.

[0023] The polishing composition of this embodiment contains an abrasive and water. The abrasive material contains zirconia particles. The polishing composition is suitably used for polishing hard and brittle materials such as sapphire, silicon nitride, silicon carbide, silicon oxide, glass, gallium nitride, gallium arsenide, indium arsenide, and indium phosphide.

[0024] The zirconia particles contained in the abrasive may contain crystalline zirconia such as cubic system, tetragonal system, and monoclinic system, or may contain amorphous zirconia. As the abrasive, tetragonal or monoclinic zirconia is preferable. Zirconia particles may also contain calcium, magnesium, hafnium, yttrium, silicon, and the like. Among them, the purity of the zirconia particles is preferably as high as possible, specifically, preferably 98% by mass or more, more preferably 99% by mass or more, and still more preferab...

no. 2 Embodiment approach

[0067] Next, a second embodiment of the present invention will be described.

[0068] The polishing composition of the second embodiment differs from the polishing composition of the first embodiment in that it contains zirconia particles having an average secondary particle size of 1.0 μm or less. The average secondary particle size of the zirconia particles contained in the polishing composition according to the second embodiment is preferably 0.7 μm or less, more preferably 0.5 μm or less, even more preferably 0.4 μm or less.

[0069] In addition, the value obtained by dividing the average secondary particle diameter of the zirconia particles contained in the polishing composition of the second embodiment by the average primary particle diameter of the same zirconia particles is 1.5 or less.

[0070] Therefore, it is considered that the average primary particle size of the zirconia particles contained in the polishing composition of the second embodiment is relatively large...

Embodiment 1~6、 comparative example 1、2

[0073] Embodiment 1~6, comparative example 1, 2 and reference example 1

[0074] The polishing compositions of Examples 1 to 6 and Comparative Examples 1 and 2 were prepared by mixing monoclinic zirconia particles into water and adjusting pH with phosphorous acid or potassium hydroxide. The polishing composition of Reference Example 1 was prepared by mixing a commercially available cerium oxide abrasive material, CEPOL132 manufactured by Fujimi Incorporated, with water and adjusting the pH with potassium hydroxide. Table 1 shows details of each polishing composition.

[0075] The production method of the zirconia particles used in each polishing composition of Examples 1 to 6 and Comparative Examples 1 and 2 is shown in the column of "Manufacturing method" of Table 1. "ZW" indicates the use of zirconia particles produced by a wet process, "ZD" indicates the use of zirconia particles produced by a dry process using zircon sand as a raw material, and "BD" indicates the use of z...

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Abstract

A polishing composition which comprises an abrasive and water is provided. The abrasive comprises zirconium oxide particles. In one embodiment, the crystallite size of the zirconium oxide particles as calculated on the basis of the diffracted X-ray intensity measured in the vicinity of 2? of 28.0° in the powder X-ray diffractometry and that as calculated on the basis of the diffracted X-ray intensity measured in the vicinity of 2? of 31.0° therein are 330 Å or more, while the mean primary particle diameter of the zirconium oxide particles is 0.2µm or more. In another embodiment, the mean secondary particle diameter of the zirconium oxide particles is 1.0µm or less, while the value obtained by dividing the mean secondary particle diameter of the zirconium oxide particles by the mean primary particle diameter thereof is 1.5 or less. The polishing composition is usable in polishing a hard and brittle material such as sapphire.

Description

technical field [0001] The present invention relates to abrasive materials and abrasive compositions used for grinding sapphire, silicon nitride, silicon carbide, silicon oxide, glass, gallium nitride, gallium arsenide, indium arsenide, indium phosphide and other hard and brittle materials . The invention also relates to a grinding method for hard and brittle materials and a manufacturing method for hard and brittle material substrates. Background technique [0002] For polishing compositions used for polishing substrates such as glass substrates for hard disks, glass substrates for liquid crystal display panels, and synthetic quartz substrates for photomasks, in order to improve the quality of the polished substrates, the quality of the polished substrates is strongly required. The surface roughness is small and there are few surface defects such as scratches on the polished substrate. In addition, in order to shorten the time required for the polishing operation, the pol...

Claims

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Application Information

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IPC IPC(8): B24B37/00C09K3/14H01L21/304
CPCC09K3/1409C09K3/1463B24B37/00B24D3/00C09K3/14H01L21/304
Inventor 三轮直也森永均大矢曜三岩国真弓杉山博保森智雄
Owner FUJIMI INCORPORATED