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Concrete curing agent and preparation method thereof

A technology of concrete curing agent and mixture, which is applied in the field of building materials, can solve the problems of poor compatibility, strong hydrophobicity of organofluorine and organosilicon polymers, and no synergistic effect, etc., and achieves simple preparation methods, improved curing effects, The effect of enhancing binding force

Active Publication Date: 2014-02-26
JIANGSU SOBUTE NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional styrene-acrylic emulsion has poor bonding force with the wet surface of freshly poured concrete, resulting in unsatisfactory water retention effect, and its maintenance effect is difficult to meet actual needs
[0004] Patent CN102010230 discloses a preparation method of concrete curing agent, but the organofluorine unsaturated monomer and organosilicon unsaturated monomer used in this method are expensive and costly; and the formed organofluorine and organosilicon polymer have strong hydrophobicity , which is not conducive to the wetting of the curing agent on the newly poured concrete surface and the uniform coating of the curing agent on the concrete surface
[0005] Patent CN102976652 discloses a method for preparing a concrete curing agent with a high water retention rate. However, this method is a traditional styrene-acrylic emulsion. The introduction of a core-shell structure can only reduce the minimum film-forming temperature of the emulsion, and cannot fundamentally improve the formed Inhibitory Effect of Curing Film on Surface Moisture of Fresh Concrete
[0006] Patent ZL02111497.8 discloses a water-based liquid film type concrete curing agent. However, this method is a curing agent formed by compounding acrylate polymer emulsion and wax emulsion. The compounding of physical effects does not have a positive synergistic effect, and the two poor compatibility
[0007] The inventions of the above-mentioned curing agents are all considered only from the curing agent itself, without considering the bonding effect of the curing agent and the concrete surface, so it is difficult to meet the actual needs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Concrete curing agent, mixed according to the following ingredients and proportions: 93.9 parts of core-shell structure polymer emulsion with a solid content of 15wt%, 5 parts of film-forming aid alcohol ester twelve, 0.5 part of fluorocarbon leveling agent, 0.5 part Defoamer n-octanol, 0.1 parts of hydroxyethyl cellulose.

[0035] Wherein, the preparation method of core-shell structure polymer emulsion is as follows:

[0036] (1) Raw material ratio:

[0037] Nucleomonomer: 5 parts styrene and 5 parts methyl methacrylate;

[0038] Shell monomer: 40 parts styrene, 45 parts methyl methacrylate and 5 parts hydroxypropyl methacrylate;

[0039] 0.5 parts of ammonium persulfate, 0.5 parts of emulsifier sodium lauryl sulfate, 1.5 parts of emulsifier alkylphenol ethoxylate and 567 parts of water.

[0040] (2) Preparation:

[0041] Prepare core emulsion, shell emulsion and ammonium persulfate aqueous solution according to raw material ratio.

[0042] Under stirring conditio...

Embodiment 2

[0045] Concrete curing agent, mixed according to the following ingredients and proportions: 94 parts of core-shell structure polymer emulsion with a solid content of 35wt%, 4 parts of film-forming aid alcohol ester twelve, 1 part of fluorocarbon leveling agent, 0.5 parts Defoamer n-octanol and 0.5 parts of alkali swelling thickener.

[0046] Wherein, the preparation method of core-shell structure polymer emulsion is as follows:

[0047] (1) Raw material ratio:

[0048] Nucleomonomer: 40 parts styrene and 10 parts methyl acrylate;

[0049] Shell monomer: 5 parts styrene, 35 parts methyl methacrylate and 10 parts hydroxypropyl acrylate;

[0050] 0.5 parts of ammonium persulfate, 0.3 parts of ferrous sulfate, 0.5 parts of emulsifier sodium dodecylbenzene sulfonate, 1.5 parts of emulsifier alkylphenol polyoxyethylene ether and 186 parts of water.

[0051] (2) Preparation:

[0052] Prepare core emulsion, shell emulsion and ammonium persulfate aqueous solution according to raw m...

Embodiment 3

[0056] Concrete curing agent, mixed according to the following ingredients and proportions: 98.2 parts of core-shell structure polymer emulsion with a solid content of 20wt%, 1 part of fluorocarbon leveling agent, 0.3 part of defoamer n-octanol and 0.5 part of hydroxyethyl base cellulose.

[0057] Wherein, the preparation method of core-shell structure polymer emulsion is as follows:

[0058] (1) Raw material ratio:

[0059] Nucleomonomer: 15 parts lauryl acrylate and 20 parts methyl methacrylate;

[0060] Shell monomer: 25 parts butyl acrylate, 20 parts ethyl acrylate and 20 parts hydroxyethyl methacrylate;

[0061] 1 part of ammonium persulfate, 0.5 parts of emulsifier sodium lauryl sulfate, 2 parts of emulsifier alkylphenol ethoxylate and 400 parts of water.

[0062] (2) Preparation:

[0063] Prepare core emulsion, shell emulsion and ammonium persulfate aqueous solution according to raw material ratio.

[0064] Under stirring conditions, the temperature is 70-75 °C, ad...

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PUM

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Abstract

The invention provides a concrete curing agent which is prepared from the following components in parts by weight: 90-99 parts of core-shell structure macromolecule emulsion, 0-5 parts of film-forming aid, 0.1-2 parts of defoaming agent, 0-5 parts of leveling agent and 0-1 part of thickening agent. The concrete curing agent is simple in preparation method, the emulsion of a core-shell structure is prepared by using an emulsion polymerization method, hydroxyl groups are introduced into the shell layer, and the hydroxyl groups can have chemical bonding action with silicon atoms on the surface of the concrete, so that the binding force of the curing agent with the surface of the concrete is improved, and the water retention effect of the concrete curing agent is ensured.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a concrete curing agent with an emulsion type core-shell structure, and also relates to a preparation method of the concrete curing agent. Background technique [0002] Concrete curing is an important part of concrete construction. After the concrete is poured, it must be cured during the initial setting process, that is, to maintain the necessary humidity and temperature so that it has enough water to ensure the hydration reaction. Improper early maintenance can easily lead to concrete drying shrinkage cracking and insufficient hydration reaction, the latter can easily lead to the compactness of the concrete structure not meeting the design requirements; proper maintenance can greatly improve the durability, strength, wear resistance and volume stability of concrete sexual performance. [0003] The traditional maintenance methods include grass bag maintenance, plas...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/28
Inventor 王瑞李磊刘加平田倩王洪松王文彬
Owner JIANGSU SOBUTE NEW MATERIALS
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