Method for repairing soil containing novel organic pollutant by using sludge biological carbon
A technology for organic pollutants and polluted soil, which is applied in the field of using sludge biocarbon to remediate soil containing emerging organic pollutants. It can solve the problem of slow effect of plant and microbial remediation methods, unfavorable large-scale promotion and application, and large disturbance of the surrounding ecological environment. and other problems, to achieve long-lasting repair and improvement effects, stable and reliable repair efficiency, and the realization of solid waste recycling
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Embodiment 1
[0035] Dry the remaining sludge from urban sewage treatment plants at 60°C, crush and sieve through 200 mesh, put the powder into a vacuum tube furnace, and pass N at a flow rate of 0.5L / min. 2 0.5h, 5°C / min heating to 350°C, carbonization for 3h, and cooling to room temperature to obtain black biochar with a yield of 50%. Mix evenly with the polluted (bisphenol A content 10mg / kg) soil sample at 2% mass percentage. Under laboratory conditions, the leachable concentration of bisphenol A in soil was not detected after 6 months of aging.
Embodiment 2
[0037] After mixing urban sludge and discarded rice straw (mass ratio 1:2), after drying at 60°C, crush and sieve 50 mesh, put the powder into a vacuum tube furnace, and pass N at a flow rate of 0.75L / min. 2 0.35h, 5°C / min heating to 300°C, carbonization for 5h, and cooling to room temperature to obtain black biochar with a yield of 45%. Apply 3.5% mass percentage to the soil (red soil) heavily polluted by antibiotics (20.37mg / kg), and plow and mix the top 0-10cm of soil. After natural aging for 12 months, it is found that antibiotics can The leaching concentration is gradually reduced to undetectable, and the contaminated soil can be cultivated. After 6 months, it was found that the yield of the bean crop increased significantly by 5%, and the heavy metals Cr, Pb, and Mn in the product did not exceed the standard.
Embodiment 3
[0039] Use harmless treated urban sludge and rice straw (mass ratio 2:1), dry at 60°C, crush and sieve to 100 mesh, put the powder into a vacuum tube furnace, and pass it through at a flow rate of 0.5L / min. N 2 0.5h, 7°C / min heating to 400°C, carbonization for 2h, cooling to room temperature, to obtain black biochar with a yield of 70%. Apply 1% mass percentage to the tea field soil compounded by antibiotics and heavy metals (tetracycline 0.91mg / kg, copper 150mg / kg), and plow and mix the top 0-25cm of soil for 6 months After natural aging, it was found that the leachable concentration of pollutants gradually decreased to below the safe level of environmental standards.
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