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Method for repairing soil containing novel organic pollutant by using sludge biological carbon

A technology for organic pollutants and polluted soil, which is applied in the field of using sludge biocarbon to remediate soil containing emerging organic pollutants. It can solve the problem of slow effect of plant and microbial remediation methods, unfavorable large-scale promotion and application, and large disturbance of the surrounding ecological environment. and other problems, to achieve long-lasting repair and improvement effects, stable and reliable repair efficiency, and the realization of solid waste recycling

Inactive Publication Date: 2014-05-21
GUANGZHOU INST OF ADVANCED TECH CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] (1) Physical restoration and chemical restoration are traditional restoration methods. Although the goal is direct and some results have been achieved in practical applications, there are problems such as complex implementation, high cost, large disturbance to the surrounding ecological environment, and serious ecological impact during construction. The remediation efficiency of low-concentration contaminated soil is often low;
[0011] (2) Phyto and microbial remediation methods are slow to take effect and are not suitable for highly polluted land. The restoration of agricultural land will bring about a reduction in economic benefits, and phyto and microbial remediation usually requires local appropriate species and inoculation methods to be formulated according to local conditions, Not conducive to large-scale promotion and application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Dry the remaining sludge from urban sewage treatment plants at 60°C, crush and sieve through 200 mesh, put the powder into a vacuum tube furnace, and pass N at a flow rate of 0.5L / min. 2 0.5h, 5°C / min heating to 350°C, carbonization for 3h, and cooling to room temperature to obtain black biochar with a yield of 50%. Mix evenly with the polluted (bisphenol A content 10mg / kg) soil sample at 2% mass percentage. Under laboratory conditions, the leachable concentration of bisphenol A in soil was not detected after 6 months of aging.

Embodiment 2

[0037] After mixing urban sludge and discarded rice straw (mass ratio 1:2), after drying at 60°C, crush and sieve 50 mesh, put the powder into a vacuum tube furnace, and pass N at a flow rate of 0.75L / min. 2 0.35h, 5°C / min heating to 300°C, carbonization for 5h, and cooling to room temperature to obtain black biochar with a yield of 45%. Apply 3.5% mass percentage to the soil (red soil) heavily polluted by antibiotics (20.37mg / kg), and plow and mix the top 0-10cm of soil. After natural aging for 12 months, it is found that antibiotics can The leaching concentration is gradually reduced to undetectable, and the contaminated soil can be cultivated. After 6 months, it was found that the yield of the bean crop increased significantly by 5%, and the heavy metals Cr, Pb, and Mn in the product did not exceed the standard.

Embodiment 3

[0039] Use harmless treated urban sludge and rice straw (mass ratio 2:1), dry at 60°C, crush and sieve to 100 mesh, put the powder into a vacuum tube furnace, and pass it through at a flow rate of 0.5L / min. N 2 0.5h, 7°C / min heating to 400°C, carbonization for 2h, cooling to room temperature, to obtain black biochar with a yield of 70%. Apply 1% mass percentage to the tea field soil compounded by antibiotics and heavy metals (tetracycline 0.91mg / kg, copper 150mg / kg), and plow and mix the top 0-25cm of soil for 6 months After natural aging, it was found that the leachable concentration of pollutants gradually decreased to below the safe level of environmental standards.

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PUM

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Abstract

The invention discloses a method for repairing soil containing novel organic pollutants by using sludge biological carbon. The method comprises the steps of (1), drying a biomass raw material containing sludge at a temperature of 40-60 DEG C, sieving the biomass raw material containing the sludge via a sieve with 10-200 meshes, and carbonizing the biomass raw material for 0.5-6 hours at a temperature of 300-650 DEG C under an anaerobic condition to prepare biomass carbon; (2), applying the prepared biomass carbon to the surface of the polluted soil according to a mass ratio of 0.5-5%, plowing the surface layer of the polluted soil in a distance of 0-30cm, and enabling the surface layer of polluted soil to be fully and evenly mixed with the biomass carbon; and (3), aging for 6-12 months. The biomass carbon is low in cost of preparation raw material and environmentalally-friendly; the preparation process is simple and feasible and totally conforms to the principle of turning waste into wealth and forming the stereoscopic agriculture. In addition, the biomass carbon contains a large quantity of carbon elements and nutritional ingredients; the biomass carbon has the effect of fertilizing the soil.

Description

technical field [0001] The invention relates to a method for repairing emerging organic polluted soil, in particular to a method for using sludge biochar to restore soil containing emerging organic pollutants. Background technique [0002] Soil is a natural adsorbent and carrier because of its electronegativity and high specific surface area, and it is the most important sink for emerging organic pollutants. Emerging Organic Contaminants (EOCs) include Endocrine Disrupting Chemicals (EDCs), Pharmaceuticals and Personal Care Products (PPCPs) and Perfluorinated Compounds (PFCs). Emerging organic pollutants are chemically very different from traditional persistent organic pollutants. Persistent organic pollutants tend to have low water solubility, so their mobility in soil is poor; while emerging pollutants have high water solubility and are mostly hydrophilic substances, so their mobility and bioavailability in soil are poor. High, more harmful to soil, especially agricultur...

Claims

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Application Information

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IPC IPC(8): B09C1/00
Inventor 费颖恒赵丹陈顺权
Owner GUANGZHOU INST OF ADVANCED TECH CHINESE ACAD OF SCI
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