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Luminescent glass for LED and preparation method thereof

A technology of luminescent glass and glass, applied in the field of luminescent materials and their preparation, can solve the problems of high color temperature, impossible to break through the inherent defects of powder materials, low color rendering index, etc., and achieve the effect of solving the technical bottleneck

Active Publication Date: 2016-09-28
QILU UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This combination method has the following disadvantages: a) poor uniformity of luminous chromaticity; b) low color rendering index; c) high color temperature; d) epoxy resin is easy to age; e) easy to produce temperature quenching effect, Resulting in a decrease in the luminous efficiency of semiconductor chips and phosphors; f) higher costs
Although great progress has been made in the research of phosphors for LEDs, it is impossible to break through the inherent defects of powder materials, whether it is to modify the traditional phosphor system or to develop a new compound system.

Method used

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  • Luminescent glass for LED and preparation method thereof
  • Luminescent glass for LED and preparation method thereof
  • Luminescent glass for LED and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] (1) Design the glass molar composition to be 45SiO 2 −15Al 2 o 3 −10ZnO −20CaF 2 −10CaO: 0.075Eu 2 o 3 , 0.025 Tb 4 o 7 , 0.125Dy 2 o 3 ;

[0025] (2) According to the glass composition designed in step (1), accurately weigh 10.5609 g of silica, 5.9742 g of alumina, 3.1793 g of zinc oxide, 6.0992 g of calcium fluoride, 3.9098 g of calcium carbonate, 0.1031 g of europium oxide, 0.0730 g of terbium and 0.1821 g of dysprosium oxide, these raw materials were fully ground in an agate mortar for 25 min, and the glass batch was obtained after mixing evenly;

[0026] (3) Pour the glass batch material into a corundum crucible, put it into a high temperature furnace for melting, and the melting temperature is 1450 o C, heat preservation for 1 h to obtain glass liquid;

[0027] (4) Pour the glass liquid into 450 o C preheated for 30 min in a stainless steel mold, then placed in a muffle furnace at 450 o C annealed for 2 h, then cooled to room temperature with the f...

Embodiment 2

[0032] (1) Design the glass molar composition to be 45SiO 2 −15Al 2 o 3 −20CaF 2 −10CaO −10Na 2 O: 0.075Eu 2 o 3 , 0.025Tb 4 o 7 , 0.125Dy 2 o 3 ;

[0033] (2) According to the glass composition designed in step (1), accurately weigh 10.2216 g of silica, 5.7822 g of alumina, 5.9032 g of calcium fluoride, 3.7841 g of calcium carbonate, 4.0072 g of sodium carbonate, 0.0998 g of europium oxide, Terbium 0.0707g and Dysprosium oxide 0.1763g, these raw materials are fully ground in an agate mortar for 25 minutes, after mixing evenly, a glass batch is obtained;

[0034] (3) Pour the glass batch material into a corundum crucible, put it into a high temperature furnace for melting, and the melting temperature is 1450 o C, keep warm for 1 h to obtain a uniform glass liquid;

[0035] (4) Pour the glass liquid into 450 o C preheated for 30 min in a stainless steel mold, then placed in a muffle furnace at 450 o C annealed for 2 h, then cooled to room temperature with the fu...

Embodiment 3

[0038] (1) Design the glass molar composition to be 45SiO 2 −15Al 2 o 3 −20B 2 o 3 −10ZnO −10CaO: 0.075Ce 2 o 3 , 0.025Tb 4 o 7 , 0.125Sm 2 o 3 ;

[0039] (2) According to the glass composition designed in step (1), accurately weigh 9.3875 g of silica, 5.3104 g of alumina, 8.5875 g of boric acid, 2.8260 g of zinc oxide, 3.4753 g of calcium carbonate, 0.2262 g of cerium nitrate, and 0.0649 g of terbium oxide. g and 0.1514 g of samarium oxide, fully grind these raw materials in an agate mortar for 25 min, and mix them uniformly to obtain a glass batch;

[0040] (3) Pour the glass batch material into a corundum crucible, put it into a high-temperature furnace for melting, and the melting temperature is 1480 o C, keep warm for 1 h to obtain a uniform glass liquid;

[0041] (4) Pour the glass liquid into 470 o C preheated for 30 min in a stainless steel mold, then placed in a muffle furnace at 470 o C annealed for 2 h, then cooled to room temperature with the furna...

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Abstract

The invention discloses luminescent glass for an LED (Light-Emitting Diode), and a preparation method of the luminescent glass. The glass matrixes of the luminescent glass for the LED include main ingredients: SiO2, Al2O3, B2O3, CaF2, CaO, ZnO AND Na2O, the preparation method comprises the steps of: by taking rare earth ions Tb<3+>, Eu<3+>, Dy<3+>, Ce<3+> and Sm<3+> as a luminescence center, codoping or tridoping the rare earth ions into the glass matrixes, and emitting white light by matching with an ultraviolet LED chip; preparing the luminescent glass by adopting a high-temperature melting method. According to the luminescent glass, the emission spectrum, chromaticity coordinates, chromaticity temperature and the like of the luminescent glass can be regulated by changing the ingredients of the glass matrixes, the concentration of the rare earth ions and excitation wavelength, thus realizing the intelligent luminescence of the material, so as to meet the requirement of different usage environments on the luminescence performance of LED devices. The luminescent glass has excellent luminescence performance and stable physical and chemical properties, and is a novel white light emission material. The luminescent glass can be used for the LED devices, so as to solve the problems that the current LED is poor in chromaticity stability, the packaging resin is easy to age, and the like.

Description

technical field [0001] The invention relates to a luminescent material and a preparation method thereof in the fields of luminescent display, optoelectronics, and lighting engineering science and technology, and in particular to a luminescent glass for LED and a preparation method thereof. Background technique [0002] Light emitting diode (LED) is a semiconductor light emitting device that converts electrical energy into light energy. The successful development of high-brightness white LEDs has enabled better promotion and application of LEDs in the field of lighting, and at the same time brought a new revolution to lighting technology. Compared with incandescent lamps and fluorescent lamps, LED, as a new type of light source, has the characteristics of energy saving, long life, short start-up time, environmental protection, low-voltage safety, etc., and has now become a high-tech product with great development prospects and influence. White light-emitting diodes (W-LEDs) ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C3/112C03C3/095C03C4/12
Inventor 朱超峰王佳
Owner QILU UNIV OF TECH
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