Self-crosslinked water-based acrylic air-drying paint and preparation method thereof

A water-based acrylic and self-drying paint technology, applied in the coating and other directions, can solve the problems of difficult adjustment of construction, high volatile organic content, water-based acrylic self-drying paint can not meet the electrostatic spraying construction and other problems, to achieve the effect of maintaining mirror gloss

Inactive Publication Date: 2015-02-25
GUANGZHOU FUCHENGMEI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Most of the existing acrylic self-drying paints are oily acrylic self-drying paints. These oily acrylic self-drying paints contain high volatile organic compounds (VOC), which are easy to pollute the environment and cause damage to human health.
[0004] In response to the above situation, some water-based acrylic self-drying coatings have appeared on the market. However, the paint film formed by these water-based acrylic self-drying coatings on the surface of hardware electroplating products has poor sealability, low brightness and low hardness, and cannot provide good protection for the electroplating layer. , poor oxidation resistance, poor hand sweat resistance, poor salt spray resistance, short service life
In addition, the water-based acrylic self-drying paint cannot meet the needs of electrostatic spraying construction, and its application range is narrow; its viscosity is high, its water dilutability is poor, and it is not easy to adjust the construction

Method used

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  • Self-crosslinked water-based acrylic air-drying paint and preparation method thereof
  • Self-crosslinked water-based acrylic air-drying paint and preparation method thereof
  • Self-crosslinked water-based acrylic air-drying paint and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0066] A kind of self-crosslinking waterborne acrylic acid self-drying paint of the present invention comprises the raw material of following mass percentage:

[0067]

[0068] The alcohol in this embodiment is a monohydric alcohol.

[0069] The monohydric alcohol in this embodiment is n-butanol.

[0070] The initiator of this embodiment is BPO.

[0071] The auxiliary agent in this embodiment is a silane coupling agent.

[0072] The neutralizing agent of the present embodiment is ammonia water.

[0073] A preparation method for self-crosslinking water-based acrylic acid self-drying coating, comprising the following processing steps:

[0074] Step A, weighing the materials of the formula amount, respectively placing them in different containers for use;

[0075] Step B, add methyl methacrylate, butyl methacrylate, hydroxyethyl methacrylate, methacrylic acid, diacetone acrylamide and 80% initiator into a mixing tank and mix evenly to form a mixed solution, ready to use ; ...

Embodiment 2

[0081] A kind of self-crosslinking waterborne acrylic acid self-drying paint of the present invention comprises the raw material of following mass percentage:

[0082]

[0083]

[0084] The alcohol in this embodiment is dihydric alcohol.

[0085] The dihydric alcohol of this embodiment is propylene glycol.

[0086] The initiator of the present embodiment is potassium persulfate.

[0087] The auxiliary agent in this embodiment is a titanate coupling agent.

[0088] The neutralizing agent of the present embodiment is triethylamine.

[0089] A preparation method for self-crosslinking water-based acrylic acid self-drying coating, comprising the following processing steps:

[0090] Step A, weighing the materials of the formula amount, respectively placing them in different containers for use;

[0091] Step B, add methyl methacrylate, butyl methacrylate, hydroxyethyl methacrylate, methacrylic acid, diacetone acrylamide and 75% initiator into a mixing tank and mix evenly to...

Embodiment 3

[0098] A kind of self-crosslinking waterborne acrylic acid self-drying paint of the present invention comprises the raw material of following mass percentage:

[0099]

[0100] The alcohol in this embodiment is a polyhydric alcohol.

[0101] The polyhydric alcohol of this embodiment is glycerin.

[0102] The initiator of this embodiment is azobisisobutyronitrile.

[0103] The auxiliary agent in this embodiment is a silane coupling agent.

[0104] The neutralizing agent of the present embodiment is sodium bicarbonate.

[0105] A preparation method for self-crosslinking water-based acrylic acid self-drying coating, comprising the following processing steps:

[0106] Step A, weighing the materials of the formula amount, respectively placing them in different containers for use;

[0107] Step B, add methyl methacrylate, butyl methacrylate, hydroxyethyl methacrylate, methacrylic acid, diacetone acrylamide and 85% initiator into the mixing tank and mix evenly to form a mixed ...

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Abstract

The invention relates to a self-crosslinked water-based acrylic air-drying paint which comprises the following raw materials in percentage by mass: 10-20% of methyl methacrylate, 5-15% of butyl methacrylate, 1-3% of hydroxyethyl methacrylate, 3-8% of methacrylic acid, 1-3% of diacetone acrylamide, 10-20% of alcohol, 1-2% of initiator, 2-5% of neutralizer, 40-50% of pure water and 0.5-1% of assistant. The paint film formed by the paint has the advantages of favorable closeness, favorable oxidation resistance, favorable hand perspiration resistance and favorable salt spray resistance. The preparation method of the paint comprises the following steps: weighing the raw materials; mixing the methyl methacrylate, butyl methacrylate, hydroxyethyl methacrylate, methacrylic acid, diacetone acrylamide and 75-85% of initiator to obtain a mixed solution; adding the alcohol into a reaction kettle, introducing nitrogen and heating; adding the mixed solution into the reaction kettle, adding the rest of initiator into the reaction kettle, removing the solvent, and cooling; adding the neutralizer into the reaction kettle; and adding the pure water into the reaction kettle, and adding the assistant into the reaction kettle to obtain the finished product. The method has the advantages of simple technique and high production efficiency.

Description

technical field [0001] The invention relates to the technical field of chemical products, in particular to a self-crosslinking water-based acrylic self-drying paint and a preparation method thereof. Background technique [0002] Acrylic self-drying paint is a material that can be naturally air-dried to form a film after being applied to the surface of an object. It is mainly used for surface sealing of hardware electroplating products and can provide protection for the electroplating layer. [0003] Most of the existing acrylic self-drying paints are oily acrylic self-drying paints. These oily acrylic self-drying paints have a high content of volatile organic compounds (VOC), which are easy to pollute the environment and cause damage to human health. [0004] In response to the above situation, some water-based acrylic self-drying coatings have appeared on the market. However, the paint film formed by these water-based acrylic self-drying coatings on the surface of hardware ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/12C09D133/10C08F220/14C08F220/18C08F220/28C08F220/06C08F220/58
CPCC08F220/14C09D133/12C08F220/1804C08F220/281C08F220/06C08F220/58
Inventor 胡大明
Owner GUANGZHOU FUCHENGMEI CHEM
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