Method for separating lignin and holocellulose from wood fiber raw materials and application thereof

A technology of lignocellulosic raw materials and comprehensive cellulose, which is applied in the field of utilization of agricultural and forestry biological materials, can solve the problems of insufficient biomass-based substitute products and the inability to use lignocellulosic raw materials, etc., and achieve simple and easy process, high saccharification efficiency, and extraction yield high effect

Inactive Publication Date: 2015-03-04
INT CENT FOR BAMBOO & RATTAN
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  • Summary
  • Abstract
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Problems solved by technology

[0006] At present, my country's polymer materials and chemicals mainly rely on petroleum resources. Among them, the plastic market alone consumes more than 70 million tons per year, equivalent to about 80 million tons of petroleum resources. However, the biomass-based substitute products are less than 1%, so research and development are urgently needed. Petroleum-based products Biomass-based products, such as energy-saving insulation materials, thermosetting resin materials, functional polymer materials and other products, reduce oil dependence and make positive contributions to addressing climate change and energy crises
This method is only applicable to shrub red willow, and cannot be applied to most lignocellulosic raw materials, which has great limitations, and acidic substances such as sulfuric acid or hydrochloric acid need to be added

Method used

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  • Method for separating lignin and holocellulose from wood fiber raw materials and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0035] Embodiment 1: separate lignin from bamboo powder

[0036] This embodiment has the following steps:

[0037] (1) Grind the bamboo until the particle size is less than 2mm, add 100g of bamboo powder to 500mL of 10% sodium hydroxide solution, stir evenly at room temperature, heat at 120°C for 60min, cool naturally to room temperature, and soak to moisten rising bamboo powder;

[0038] (2) Add the bamboo powder soaked and moistened into the homogenizer feed hopper, stir to keep the material in suspension, then pass through the homogenizer, while circulating the material and gradually increase the pressure, when the pressure reaches 80MPa, start to collect the material, and the material Vacuum filtration to separate solid and liquid to obtain solid filter residue, which is washed with water;

[0039] (3) the solid filter residue that step (2) obtains is joined in 40% sodium cumene sulfonate aqueous solution, the mass volume ratio of residue and sodium cumene sulfonate solu...

Embodiment 2

[0046] The difference between this embodiment and embodiment 1 is that in step (1), 100g of bamboo powder is added to 1000mL of 1% potassium hydroxide aqueous solution in parts by mass.

Embodiment 3

[0048] The difference between this embodiment and embodiment 1 is that in step (2) when the pressure reaches 100MPa, the material starts to be collected.

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Abstract

The invention relates to utilization and technology of agriculture and forestry biological data, in particular to a method for separating lignin and holocellulose from wood fiber raw materials. The method comprises the following steps: a, wood fiber raw materials are mixed with an alkali liquor and then soaked and moistened; b, the soaked and moistened wood fiber raw materials are homogenized and then filtered and separated to obtain solid residues and a filtrate I; c, the solid residues which are washed with water are added into a benzene sulfonate water solution for digestion, and the digested solid residues are filtered and separated to obtain residues containing holocellulose and a filtrate containing lignin; d, the residues containing holocellulose are washed to obtain holocellulose; e, water is added into the filtrate containing lignin to separate lignin, filtering is performed to obtain lignin residues and a filtrate II, and the lignin residues are washed and dried to obtain lignin. The method provided by the invention is simple and feasible in process, environment-friendly, and low in toxicity, the lignin extraction yield is high, and the saccharification efficiency of holocellulose obtained through separation is also high.

Description

technical field [0001] The invention relates to the utilization and technology of agricultural and forestry biological data, in particular to a method and application for separating lignin and cellulose from lignocellulosic raw materials. Background technique [0002] With the increasing tension of global fossil fuels and increasingly serious environmental pollution, the energy and environmental crisis has become a major obstacle to the sustainable development of human society in the 21st century. The use of renewable biomass as an alternative to fossil fuels has become increasingly urgent and important. Biomass fuels and bio-based products are one of the important research directions. [0003] Lignocellulosic raw materials are the most abundant and cheapest renewable resources on earth. Lignocellulosic biomass produced through photosynthesis in the world is as high as 100 billion tons every year, but 89% of it has not been utilized by humans. my country is very rich in l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21C5/00C08H7/00
CPCC08H6/00D21C5/00
Inventor 李志强江泽慧费本华刘杏娥
Owner INT CENT FOR BAMBOO & RATTAN
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