A method for recycling agricultural waste straw

A waste straw recycling technology, applied in chemical instruments and methods, inorganic chemistry, waste fuels, etc., can solve the problems of polluting irrigation water, polluting the atmospheric environment, and high content, and achieves high methane production efficiency and high adsorption efficiency.

Active Publication Date: 2016-08-24
南通汉森农业科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First, crop straws and rice husks after processing are burned in large quantities. Although the relevant state departments have banned the burning of straws and chaffs many times, due to the limited use of straws and chaffs in rural areas, there are still a lot of bans. There are still a large number of Straw and chaff are burned, which seriously pollutes the air environment
The second is that untreated poultry manure is discharged into rivers and lakes randomly, causing water pollution and increasing the load of biochemical oxygen demand (BOD), threatening the survival of fish, shellfish and algae; at the same time, agricultural waste pollutes irrigation water, using The ammonia nitrogen and protein nitrogen content in the water are too high, and excessive nitrate is produced in the underground aquifer, which endangers the growth of crops and breeds a large number of flies and other pests, seriously endangering human health
The third is that the excessive use of chemical fertilizers and pesticides in my country's planting industry has caused soil compaction, soil fertility decline, rampant pests and diseases, and agricultural environment pollution.
Usually, wood chips and charcoal are used as the main raw materials, and each ton of activated carbon needs to consume about 4 cubic meters of wood. With the increasing shortage of wood resources, the manufacturing cost of activated carbon continues to increase. In addition, manufacturers in my country use dried potatoes to ferment citric acid every year About 100,000 to 125,000 tons of waste residue is produced, and there is no ideal treatment method at present, causing environmental pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] (1), the crushing of stalks, the stalks are cut into lengths of 3 cm, and subjected to steam explosion under the conditions of 2.0 MPa and pressure maintenance time of 1 min;

[0022] (2), ferment, carry out solid-state fermentation bar after steam explosion treatment, fermented parts are: add ammonia water, peptone, bran, peanut powder, adjust C / N to be 30 (molar ratio), then insert the active sludge in the digester , the inoculum amount is 20% of the straw weight; the fermentation temperature is 55°C, the fermentation period is 10 days, and the solid-liquid ratio is 1:3-1:6; combustible gas is produced;

[0023] (3) Squeeze the fermented waste residue to remove part of the moisture, mix it with unfermented crushed straw, phosphoric acid and potassium chloride; dry to 4% moisture, then extrude, carbonize, steam activate, cool and pulverize to obtain Activated carbon;

[0024] Among the raw materials for extrusion molding: 90% of fermented waste residue; 5% of unfermen...

Embodiment 2

[0027] (1), the crushing of stalks, the stalks are cut into lengths of 15cm, and subjected to steam explosion treatment under the conditions of 2.0MPa and pressure maintenance time of 1min;

[0028] (2), fermentation, solid-state fermentation bar after steam explosion treatment, the fermentation parts are: add ammonia water, peptone, bran, peanut powder, adjust C / N to 20 (molar ratio), and then access the activated sludge in the biogas tank , the inoculum amount is 30% of the straw weight; the fermentation temperature is 20°C, the fermentation period is 20 days, and combustible gas is produced;

[0029] (3) Squeeze the fermented waste residue to remove part of the moisture, mix it with unfermented crushed straw, phosphoric acid and potassium chloride; dry to 5% moisture, then extrude, carbonize, steam activate, and pulverize after cooling to obtain Activated carbon; raw materials for extrusion molding: 90% of fermented waste residue; 5% of unfermented crushed straw; 1% of phos...

Embodiment 3

[0031] (1), the pulverization of stalks, the stalks are cut into lengths of 10cm, and steam explosion is carried out under the conditions of 2.0MPa and pressure maintenance time of 1min;

[0032] (2), ferment, carry out solid-state fermentation bar after steam explosion treatment, fermentation part is: add ammonia water, peptone, bran, peanut powder, adjust C / N to be 25 (molar ratio), then insert the active sludge in the digester ; The fermentation temperature is 37°C, and the fermentation period is 15 days; combustible gas is produced;

[0033] (3) Squeeze the fermented waste residue to remove part of the moisture, mix it with unfermented crushed straw, phosphoric acid and potassium chloride; dry to 1% moisture, then extrude, carbonize, steam activate, cool and pulverize to obtain Activated carbon; raw materials for extrusion molding: 90% of fermented waste residue; 6% of unfermented crushed straw; 4% of phosphoric acid or potassium chloride; the balance is water; the straw i...

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PUM

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Abstract

The invention discloses a method for recycling waste crop straw. The method comprises the following steps: (1) smashing crop straw, namely cutting the crop straw into sections, and blasting at the pressure of 0.2-2.0MPa for 0.5-1 minute with steam, wherein each section of the crop straw has a length of 3-15cm; (2) fermenting, namely adding ammonia, peptone, bran and chopped peanut shells into the blasted crop straw sections, regulating the molar ratio of carbon to nitrogen (C to N) to 20:30, adding activated sludge from a methane-generating pit, and carrying out solid state fermentation at a temperature of 20-55 DEG C for 10-20 days until combustible gases are generated; and (3) squeezing fermented waste residue to remove part of water, mixing with unfermented smashed crop straw, phosphoric acid or potassium chloride, drying a mixture until water left therein is not more than 10%, molding by extruding, carbonizing, activating with steam, cooling, and smashing to obtain activated carbon, wherein the raw materials molded by extruding contain 90-95% of fermented waste residue, 5-10% of unfermented smashed crop straw, 1-5% of phosphoric acid or potassium chloride and the balance of water, and the crop straw is wheat straw, rice straw, corn straw or soybean straw.

Description

technical field [0001] The invention relates to a method for recycling waste crop stalks. Background technique [0002] my country is a large agricultural country, and the vast rural areas will produce a large amount of plant straw every harvest season. Since most of the young people in rural areas have all moved to the cities to work, there is a shortage of labor, and the workload of plant straw recycling is heavy, and the recycled straw has low reuse value, so they have to be directly burned in the field. Due to the smog caused by burning straw, planes cannot land, highway accidents occur frequently, and air pollution is severe, causing a sharp increase in respiratory diseases. In order to ban the burning of straw, governments at all levels spend a lot of energy every year to strictly investigate the burning of straw. The state invests a lot of money every year to promote straw gasification and straw biogas technology. [0003] There are many existing technologies for p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B31/10C12P5/02C02F11/04C01B32/336
CPCY02E50/30
Inventor 华文蔚
Owner 南通汉森农业科技有限公司
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