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Stone treatment agent

A treatment agent and stone technology, applied in the field of building materials, can solve the problems of increasing the difficulty of treatment, difficult to clean and remove, and the stone can not keep the color well, and achieve the effect of easy cleaning and removal and reducing difficulty.

Active Publication Date: 2015-03-25
ZHONGHAO CHENGUANG RES INST OF CHEMICALINDUSTRY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The current chemical treatment method for stone is still the traditional nitric acid and concentrated sulfuric acid treatment. After this method, there is a layer of colored oxides attached to the surface of the stone, so that the original color of the stone cannot be well maintained, and it is difficult to clean and remove. , increasing the difficulty of subsequent processing
[0004] Patent CN 102180702A discloses a stone surface treatment agent, which uses alkali metal silicate, polymer emulsion, etc., resulting in an increase in the cost of the stone treatment agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] HEDP is used as a corrosion inhibitor, high polyferric chloride and high polyaluminum chloride 1:1 (mass ratio) are compound decolorizers, and distilled water, hydrogen peroxide, hydrochloric acid, sulfuric acid, hydrofluoric acid, and stone treatment agents are configured.

[0024] Prepare a solution with a mass concentration as shown in Table 1, and treat it with a decolorizing agent:

[0025] Table 1 Example 1 stone treatment agent ratio

[0026]

[0027] The specific method of treating limestone is: configure the above proportioning solution in a 100L glass fiber reinforced plastic container, after cooling, add a decolorizing agent for treatment, after standing for clarification, take 100ml of clear treatment agent, spray evenly on the surface of 10×10cm stone, and leave it at room temperature Under treatment for 45min.

[0028] The variegated treatment agent for this stone has a good treatment effect on sandstone, slate, shale, and limestone. There is no colore...

Embodiment 2

[0030] HEDP and TH-501 (purchased from Shandong Taihe Water Treatment Company) mixed agent (1:1) are used as corrosion inhibitor, high polyferric chloride and high polyaluminum chloride are composite decolorizers (1:1), and distilled water, Hydrogen peroxide, hydrochloric acid, and hydrofluoric acid are configured as stone treatment agents.

[0031] Prepare a solution with a mass concentration as shown in Table 2 and treat it with a decolorizing agent

[0032] Table 2 Example 2 stone treatment agent ratio

[0033]

[0034] The specific method of sandstone treatment is: configure the above proportioned solution in a glass fiber reinforced plastic container, after cooling, add a decolorizing agent for treatment, after standing for clarification, take a clear treatment agent, according to the ratio of 4L treatment agent / m 2 Sandstone is evenly sprayed on the surface of the stone and treated at room temperature for 50 minutes.

[0035] The variegated treatment agent for this ...

Embodiment 3

[0037] POCA and polyacrylic acid (2:1) are used as corrosion inhibitors, cationic polyacrylamide and high polyaluminum chloride composite decolorizer (2:1), and distilled water, hydrogen peroxide, hydrochloric acid, and hydrofluoric acid are used as stone treatment agents.

[0038] The mass concentration of preparation stone material treatment agent is as follows the solution of table 3, and handles with decolorizing agent:

[0039] Table 3 Example 3 stone treatment agent ratio

[0040]

[0041] The specific method for treating granite is: configure the above proportioned solution in a glass fiber reinforced plastic container, add a decolorizer after cooling, and after standing for clarification, take a clear treatment agent, according to the ratio of 3L treatment agent / m 2 Granite is evenly sprayed on the surface of the stone and treated at room temperature for 50 minutes.

[0042] The variegated treatment agent for this stone has a good treatment effect on granite and ma...

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Abstract

The invention provides a stone treatment agent which consists of hydrogen chloride, hydrogen fluoride, hydrogen peroxide, sulfuric acid, water, a corrosion inhibitor and water. The preparation method comprises the following steps: treating the liquid containing the components by using a decolorizing agent, thereby obtaining the stone treatment agent product, wherein the hydrogen chloride accounts for 5-20 mass percent, the hydrogen fluoride accounts for 10-20 mass percent, the hydrogen peroxide accounts for 10-30 mass percent, the corrosion inhibitor accounts for 5-15 mass percent, the sulfuric acid accounts for 1-10 mass percent, and the rest is water; and the use amount of the decolorizing agent is 10-30Kg / ton of the liquid. According to the stone treatment agent provided by the invention, the treatment operations in aspects of removing impurities on the stone surface, removing stains and impurities on the cutting surface and the polishing surface, flattening the surface, engraving the stones can be effectively realized, a phenomenon that a layer of colored oxides is attached to the surface of the stone is avoided, the oxides are easy to clean and remove, and the subsequent treatment difficulty is reduced.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to a natural stone treatment agent. Background technique [0002] At present, with the development of the construction industry, the application of stone in decoration and sculpture has also increased rapidly. Common surface processing methods for natural stone include mechanical polishing, matte treatment, rough grinding, and machine cutting. Pickling is a chemical treatment method, which uses strong acid to corrode the surface of the stone to make it have small corrosion marks, and the appearance is more rustic than the polished surface. Most stones can be pickled, but the most common are marble and limestone. Acid washing is also a way to soften the luster of granite. [0003] The current chemical treatment method for stone is still the traditional nitric acid and concentrated sulfuric acid treatment. After this method, there is a layer of colored oxides attached ...

Claims

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Application Information

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IPC IPC(8): C04B41/53
Inventor 田勇张德波郭澎湃叶泉曾祥秋
Owner ZHONGHAO CHENGUANG RES INST OF CHEMICALINDUSTRY CO LTD
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