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Environment-friendly heat-resistant flame-retardant aging-resistant modified natural rubber material

A natural rubber, aging-resistant technology, applied in the field of rubber materials, can solve the problems of life safety threat, deterioration of mechanical properties, loss of performance, etc., to achieve good flame retardant performance, enhanced mechanical strength, enhanced tensile strength and tear strength Effect

Inactive Publication Date: 2015-03-25
QIAOJIAN NEW ENERGY TECH SUZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, rubber materials and their products are developing vigorously. They are rapidly replacing natural polymers such as steel, metal, cement, wood, and cotton, and are widely used in various sectors of the national economy such as industry, agriculture, and military affairs. Natural rubber materials are used in long-term storage and use. In the process, it is affected by heat energy, mechanical energy, light energy and radiation energy, plus the chemical reaction of oxygen, ozone, moisture and variable price metals and metal ions, the rubber sheath material gradually becomes soft and sticky, hard and brittle or turtle The aging phenomenon of cracking will make its mechanical properties deteriorate or even lose its original properties, resulting in failure during use, and synthetic materials need to be added during the preparation process, and synthetic materials often contain high halogens, which can be burned during combustion. A large amount of toxic gas is produced, causing harm to the environment and posing a huge threat to people's life safety. How to modify natural rubber to prepare an environmentally friendly, aging-resistant, heat-resistant and flame-resistant rubber material has become a current problem. technical issues

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] An environmentally friendly, heat-resistant, flame-retardant, and aging-resistant modified natural rubber material, the raw materials of which include by weight: 48 parts of modified natural rubber, 32 parts of nitrile rubber, 1.5 parts of tetrabenzylthiuram disulfide, fluorine-containing surface active 3.2 parts of agent, 1.4 parts of 1,1-di-tert-butylperoxy-3,3,5-trimethylsiloxane, 2.6 parts of accelerator M, 2 parts of accelerator TMTD, 33 parts of white carbon black, talc 37 parts of powder, 32 parts of nano kaolin, 35 parts of superfine magnesium hydroxide, 5.5 parts of manganese phosphate, 7 parts of dimethyl methyl phosphate, 9 parts of calcium hydrogen phosphate, 4.2 parts of magnesium borate, 1.8 parts of anti-aging agent MB, anti-aging agent 2.1 parts of RD, 2.7 parts of aromatic oil, 2.4 parts of stearic acid;

[0014] Wherein the modified natural rubber is prepared by the following process: by weight, 0.6 parts of rare earth elements and 7 parts of sulfuric ...

Embodiment 2

[0016] An environmentally friendly, heat-resistant, flame-retardant, and aging-resistant modified natural rubber material, the raw materials of which include by weight: 40 parts of modified natural rubber, 35 parts of nitrile rubber, 1 part of tetrabenzylthiuram disulfide, fluorine-containing surface active 4 parts of agent, 1 part of 1,1-di-tert-butylperoxy-3,3,5-trimethylsiloxane, 4 parts of accelerator M, 1 part of accelerator TMTD, 35 parts of white carbon black, talc 30 parts of powder, 35 parts of nano-kaolin, 30 parts of superfine magnesium hydroxide, 8 parts of manganese phosphate, 6 parts of dimethyl methyl phosphate, 11 parts of calcium hydrogen phosphate, 4 parts of magnesium borate, 3 parts of anti-aging agent MB, anti-aging agent 2 parts of RD, 4 parts of aromatic oil, 2 parts of stearic acid;

[0017] Wherein the modified natural rubber is prepared by the following process: by weight, 0.8 parts of rare earth elements and 5 parts of sulfuric acid with a concentrat...

Embodiment 3

[0019] An environmentally friendly, heat-resistant, flame-retardant, and aging-resistant modified natural rubber material, the raw materials of which include by weight: 50 parts of modified natural rubber, 15 parts of nitrile rubber, 3 parts of tetrabenzylthiuram disulfide, fluorine-containing surface active 2 parts of agent, 2 parts of 1,1-di-tert-butylperoxy-3,3,5-trimethylsiloxane, 2 parts of accelerator M, 3 parts of accelerator TMTD, 25 parts of white carbon black, talc 40 parts of powder, 25 parts of nano-kaolin, 40 parts of superfine magnesium hydroxide, 5 parts of manganese phosphate, 9 parts of dimethyl methyl phosphate, 5 parts of calcium hydrogen phosphate, 6 parts of magnesium borate, 1 part of anti-aging agent MB, anti-aging agent 3 parts of RD, 2 parts of aromatic oil, 3.5 parts of stearic acid;

[0020] Among them, the modified natural rubber is prepared by the following process: 0.2 parts of rare earth elements and 8 parts of sulfuric acid with a concentration ...

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PUM

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Abstract

The invention discloses an environment-friendly heat-resistant flame-retardant aging-resistant modified natural rubber material. The environment-friendly heat-resistant flame-retardant aging-resistant modified natural rubber material comprises the following raw materials in parts by weight: 40-50 parts of modified natural rubber, 15-35 parts of butyronitrile rubber, 1-3 parts of tetrabenzylthiuram disulfide, 2-4 parts of a fluorine-containing surfactant, 1-2 parts of 1,1-di-t-butylperoxy-3,3,5-trimethyl siloxane, 2-4 parts of an accelerator M, 1-3 parts of an accelerator TMTD, 25-35 parts of white carbon black, 30-40 parts of talc powder, 25-35 parts of nano kaolin, 30-40 parts of ultrafine magnesium hydroxide, 5-8 parts of manganese phosphate, 6-9 parts of dimethyl methylphosphate, 5-11 parts of calcium hydrogen phosphate, 4-6 parts of magnesium borate, 1-3 parts of an anti-aging agent MB, 2-3 parts of an anti-aging agent RD, 2-4 parts of aromatic oil and 2-3.5 parts of stearic acid. The environment-friendly heat-resistant flame-retardant aging-resistant modified natural rubber material disclosed by the invention has the advantages of environmental friendliness, good heat resistance, flame-retardant property and aging resistance.

Description

technical field [0001] The invention relates to the technical field of rubber materials, in particular to an environmentally friendly, heat-resistant, flame-resistant, aging-resistant and modified natural rubber material. Background technique [0002] At present, rubber materials and their products are developing vigorously. They are rapidly replacing natural polymers such as steel, metal, cement, wood, and cotton, and are widely used in various sectors of the national economy such as industry, agriculture, and military affairs. Natural rubber materials are used in long-term storage and use. In the process, it is affected by heat energy, mechanical energy, light energy and radiation energy, plus the chemical reaction of oxygen, ozone, moisture and variable price metals and metal ions, the rubber sheath material gradually becomes soft and sticky, hard and brittle or turtle The aging phenomenon of cracking will make its mechanical properties deteriorate or even lose its origin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08L9/02C08K13/02C08K5/5419C08K3/36C08K3/34C08K3/22C08K3/32C08K5/521C08K3/38C08K5/09C08C1/14
CPCC08L7/00C08C1/14C08K2201/011C08K2201/014C08L2201/02C08L2201/08C08L2205/03C08L9/02C08L91/00C08K13/02C08K3/36C08K3/34C08K3/346C08K2003/2224C08K2003/321
Inventor 马从勇
Owner QIAOJIAN NEW ENERGY TECH SUZHOU
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